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Derive an expression to calculate molar mass of non-volatile solute by osmotic pressure measurement.

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प्रश्न

Derive an expression to calculate molar mass of non-volatile solute by osmotic pressure measurement.

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उत्तर

For very dilute solution

Where π = `(n_2RT)/V`

π = Osmotic Pressure

n2 = Number of moles of solute

R = Gas constant

T = Absolute temperature

V = Volume of solution

n2 = `(W_2 ("Mass of solute"))/(M_2 ("Molar mass of solution"))`

M2 = `(W_2RT)/(πV)`

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2021-2022 (March) Set 1

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