Advertisements
Advertisements
प्रश्न
Explain the osmotic pressure of a solution with the help of a thistle tube.
Advertisements
उत्तर
- Osmosis can be demonstrated with the following experimental set up in which a semipermeable membrane is firmly fastened across the mouth of thistle tube. The solution of interest is placed inside an inverted thistle tube. This part of the tube and the membrane are then immersed in a container of pure water.
Osmosis and osmotic pressure - As a result of osmosis, some of the solvent passes through the membrane into the solution. It causes the liquid level in the tube to rise. The liquid column in the tube creates hydrostatic pressure that pushes the solvent back through the membrane into the container. The column of liquid in the tube continues to rise and eventually stops rising. At this stage hydrostatic pressure developed is sufficient to force solvent molecules back through the membrane into the container at the same rate they enter the solution.
- Thus, an equilibrium is established where rates of forward and reverse passages are equal. The height of liquid column in the tube remains constant. This implies that the hydrostatic pressure has stopped osmosis.
- The hydrostatic pressure that stops osmosis is an osmotic pressure (π) of the solution. The hydrostatic pressure is equal to hρg, where, h is the height of the liquid column in the tube, ρ is density of solution and g is acceleration due to gravity.
APPEARS IN
संबंधित प्रश्न
What happens when the external pressure applied becomes more than the osmotic pressure of solution?
Blood cells are isotonic with 0.9% sodium chloride solution. What happens if we place blood cells in a solution containing
(i) 1.2% sodium chloride solution?
(ii) 0.4% sodium chloride solution?
A solution containing 15 g urea (molar mass = 60 g mol–1) per litre of solution in water has the same osmotic pressure (isotonic) as a solution of glucose (molar mass = 180 g mol–1) in water. Calculate the mass of glucose present in one litre of its solution.
Calculate the osmotic pressure in pascals exerted by a solution prepared by dissolving 1.0 g of polymer of molar mass 185,000 in 450 mL of water at 37°C.
At 300 K, 36 g of glucose present in a litre of its solution has an osmotic pressure of 4.98 bar. If the osmotic pressure of the solution is 1.52 bars at the same temperature, what would be its concentration?
Determine the amount of CaCl2 (i = 2.47) dissolved in 2.5 litre of water such that its osmotic pressure is 0.75 atm at 27°C.
Determine the osmotic pressure of a solution prepared by dissolving 25 mg of K2SO4 in 2 liter of water at 25°C, assuming that it is completely dissociated.
Define osmotic pressure.
Which of the following 0.1 M aqueous solutions will exert the highest osmotic pressure?
Define Semipermeable membrane
Calculate the mass of NaCl (molar mass = 58.5 g mol−1) to be dissolved in 37.2 g of water to lower the freezing point by 2°C, assuming that NaCl undergoes complete dissociation. (Kf for water = 1.86 K kg mol−1)
Calculate the mass of a compound (molar mass = 256 g mol−1) to be dissolved in 75 g of benzene to lower its freezing point by 0.48 K (Kf = 5.12 K kg mol−1).
Define the following term:
isotonic solution
Choose the most correct option.
In calculating osmotic pressure the concentration of solute is expressed in _______.
Choose the most correct option.
The osmotic pressure of blood is 7.65 atm at 310 K. An aqueous solution of glucose isotonic with blood has the percentage (by volume)________.
Answer the following in one or two sentences.
What is osmotic pressure?
Answer the following in one or two sentences.
A solution concentration is expressed in molarity and not in molality while considering osmotic pressure. Why?
Answer the following.
The osmotic pressure of CaCl2 and urea solutions of the same concentration at the same temperature are respectively 0.605 atm and 0.245 atm, calculate van’t Hoff factor for CaCl2.
Answer the following.
Explain reverse osmosis.
An aqueous solution of a certain organic compound has a density of 1.063 g mL-1 , osmotic pressure of 12.16 atm at 25 °C and a freezing point of 1.03 °C. What is the molar mass of the compound?
Define Osmosis.
Which of the following is a colligative property?
Two solutions have different osmotic pressures. The solution of higher osmotic pressure is called ____________.
At constant temperature the osmotic pressure of a solution is ____________.
20 g of a substance were dissolved in 500 mL of water and the osmotic pressure of the solution was found to be 600 mm of mercury at 15°C. The molecular weight of the substance is ______.
The average osmotic pressure of human blood is 7.8 bar at 37°C. What is the concentration of an aqueous NaCl solution that could be used in the blood stream?
A solution containing 10 g per dm3 of urea (molar mass 60 g mol−1) is isotonic with 5% solution of non-volatile solute, MB of solute is:
At a given temperature, osmotic pressure of a concentrated solution of a substance ______.
In isotonic solutions:
(i) Solute and solvent both are same.
(ii) Osmotic pressure is same.
(iii) Solute and solvent may or may not be same.
(iv) Solute is always same solvent may be different.
Give an example of a material used for making semipermeable membrane for carrying out reverse osmosis.
How can you remove the hard calcium carbonate layer of the egg without damaging its semiprermiable membrane? Can this egg be inserted into a bottle with a narrow neck without distorting its shape? Explain the process involved.
Osmotic pressure of a solution increases if
Isotonic solutions have same
Which one of the following is a colligative property?
In Isotonic solution
Derive an expression to calculate molar mass of non-volatile solute by osmotic pressure measurement.
Assertion (A) : Osmotic pressure is a colligative property.
Reason (R) : Osmotic pressure is proportional to the molality.
A solution containing 10 g glucose has osmotic pressure 3.84 atm. If 10 g more glucose is added to the same solution, what will be its osmotic pressure? (Temperature remains constant)
Arrange the following solutions in the order of increasing osmotic pressure (π) assuming complete ionization.
- 0.5M Li2 SO4
- 0.5M KCl
- 0.5M Al2 (SO4)3
- 0.1 M BaCl2
Name the four colligative properties that are oftently used for determination of molecular mass.
Write the condition of reverse osmosis.
The 'X' g nonvolatile solute having molar mass 196 g mol-1 is dissolved in 3 dm³ water. Calculate the value of 'X' if resulting solution has osmotic pressure 0.8 atm at 300 К.
(R = 0.0821dm³ atm K-1 mol-1)
Calculate the osmotic pressure of 0.2 M aqueous solution of nonelectrolyte at 300 K.
[R = 0.082 atm dm3 mol−1K−1]
