Advertisements
Advertisements
प्रश्न
Explain the osmotic pressure of a solution with the help of a thistle tube.
Advertisements
उत्तर
- Osmosis can be demonstrated with the following experimental set up in which a semipermeable membrane is firmly fastened across the mouth of thistle tube. The solution of interest is placed inside an inverted thistle tube. This part of the tube and the membrane are then immersed in a container of pure water.
Osmosis and osmotic pressure - As a result of osmosis, some of the solvent passes through the membrane into the solution. It causes the liquid level in the tube to rise. The liquid column in the tube creates hydrostatic pressure that pushes the solvent back through the membrane into the container. The column of liquid in the tube continues to rise and eventually stops rising. At this stage hydrostatic pressure developed is sufficient to force solvent molecules back through the membrane into the container at the same rate they enter the solution.
- Thus, an equilibrium is established where rates of forward and reverse passages are equal. The height of liquid column in the tube remains constant. This implies that the hydrostatic pressure has stopped osmosis.
- The hydrostatic pressure that stops osmosis is an osmotic pressure (π) of the solution. The hydrostatic pressure is equal to hρg, where, h is the height of the liquid column in the tube, ρ is density of solution and g is acceleration due to gravity.
APPEARS IN
संबंधित प्रश्न
Which of the following is not a colligative property?
Blood cells are isotonic with 0.9% sodium chloride solution. What happens if we place blood cells in a solution containing
(i) 1.2% sodium chloride solution?
(ii) 0.4% sodium chloride solution?
Calculate the osmotic pressure in pascals exerted by a solution prepared by dissolving 1.0 g of polymer of molar mass 185,000 in 450 mL of water at 37°C.
Determine the osmotic pressure of a solution prepared by dissolving 25 mg of K2SO4 in 2 liter of water at 25°C, assuming that it is completely dissociated.
Define osmotic pressure.
Calculate the mass of a compound (molar mass = 256 g mol−1) to be dissolved in 75 g of benzene to lower its freezing point by 0.48 K (Kf = 5.12 K kg mol−1).
Define the following term:
isotonic solution
Define the following term:
Hypotonic solution
Choose the most correct option.
In calculating osmotic pressure the concentration of solute is expressed in _______.
Choose the most correct option.
A living cell contains a solution which is isotonic with 0.3 M sugar solution. What osmotic pressure develops when the cell is placed in 0.1 M KCl solution at body temperature?
Choose the most correct option.
The osmotic pressure of blood is 7.65 atm at 310 K. An aqueous solution of glucose isotonic with blood has the percentage (by volume)________.
Answer the following.
What are isotonic and hypertonic solutions?
Answer the following.
A solvent and its solution containing a nonvolatile solute are separated by a semipermeable membrane. Does the flow of solvent occur in both directions? Comment giving a reason.
Answer the following.
Explain reverse osmosis.
Answer the following.
How molar mass of a solute is determined by osmotic pressure measurement?
An aqueous solution of a certain organic compound has a density of 1.063 g mL-1 , osmotic pressure of 12.16 atm at 25 °C and a freezing point of 1.03 °C. What is the molar mass of the compound?
What are hypertonic solutions?
Two solutions have different osmotic pressures. The solution of higher osmotic pressure is called ____________.
At constant temperature the osmotic pressure of a solution is ____________.
20 g of a substance were dissolved in 500 mL of water and the osmotic pressure of the solution was found to be 600 mm of mercury at 15°C. The molecular weight of the substance is ______.
Osmotic pressure of a solution is 0.0821 atm at a temperature of 300 K. The concentration in moles/litre will be:
Which of the following statements is false?
Give an example of a material used for making semipermeable membrane for carrying out reverse osmosis.
Discuss biological and industrial importance of osmosis.
How can you remove the hard calcium carbonate layer of the egg without damaging its semiprermiable membrane? Can this egg be inserted into a bottle with a narrow neck without distorting its shape? Explain the process involved.
Osmotic pressure of a solution increases if
Blood cells retain their normal shape in solution which are
In Isotonic solution
The vapour pressure of water is 12.3 k pa at 300 k. Calculated the vapour pressure of molal solution in it.
The following solutions were prepared by dissolving 10 g of glucose (C6H12O6) in 250 ml of water (P1), 10 g of urea (CH4N2O) in 250 ml of water (P2) and 10 g of sucrose (C12H22O11) in 250 ml of water (P3). The right option for the decreasing order of osmotic pressure of these solutions is
Derive an expression to calculate molar mass of non-volatile solute by osmotic pressure measurement.
Assertion (A) : Osmotic pressure is a colligative property.
Reason (R) : Osmotic pressure is proportional to the molality.
Determine the osmotic pressure of a solution prepared by dissolving 2.32 × 10−2 g of K2SO4 in 2L of solution at 25°C assuming that K2SO4 is completely dissociated.
(R = 0.082 L atm K−1 mol, Molar mass K2SO4 = 174 g mol−1)
A solution containing 10 g glucose has osmotic pressure 3.84 atm. If 10 g more glucose is added to the same solution, what will be its osmotic pressure? (Temperature remains constant)
Prove that: M2 = `(W_2RT)/(πV)`.
Define reverse osmosis.
Name the four colligative properties that are oftently used for determination of molecular mass.
Write the condition of reverse osmosis.
Calculate the osmotic pressure of 0.03 mole of non electrolyte solute dissolved in 0.1 dm3 of water at 300 K. [R = 0.082 dm3 atm mol-1 K-1]
The 'X' g nonvolatile solute having molar mass 196 g mol-1 is dissolved in 3 dm³ water. Calculate the value of 'X' if resulting solution has osmotic pressure 0.8 atm at 300 К.
(R = 0.0821dm³ atm K-1 mol-1)
The plot of osmotic pressure (π) vs concentration (mol L−1) for a solution gives a straight line with slope 25.73 L bar mol−1. The temperature at which the osmotic pressure measurement is done is ______.
(Use R = 0.083 L bar mol−1 K−1)
