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महाराष्ट्र राज्य शिक्षण मंडळएचएससी विज्ञान (सामान्य) इयत्ता १२ वी

Explain the osmotic pressure of a solution with the help of thistle tube.

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प्रश्न

Explain the osmotic pressure of a solution with the help of a thistle tube.

थोडक्यात उत्तर
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उत्तर

  1. Osmosis can be demonstrated with the following experimental set up in which a semipermeable membrane is firmly fastened across the mouth of thistle tube. The solution of interest is placed inside an inverted thistle tube. This part of the tube and the membrane are then immersed in a container of pure water.

    Osmosis and osmotic pressure
  2. As a result of osmosis, some of the solvent passes through the membrane into the solution. It causes the liquid level in the tube to rise. The liquid column in the tube creates hydrostatic pressure that pushes the solvent back through the membrane into the container. The column of liquid in the tube continues to rise and eventually stops rising. At this stage hydrostatic pressure developed is sufficient to force solvent molecules back through the membrane into the container at the same rate they enter the solution.
  3. Thus, an equilibrium is established where rates of forward and reverse passages are equal. The height of liquid column in the tube remains constant. This implies that the hydrostatic pressure has stopped osmosis.
  4. The hydrostatic pressure that stops osmosis is an osmotic pressure (π) of the solution. The hydrostatic pressure is equal to hρg, where, h is the height of the liquid column in the tube, ρ is density of solution and g is acceleration due to gravity.
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पाठ 2: Solutions - Short answer questions (Type- II)

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संबंधित प्रश्‍न

Which of the following is not a colligative property?


What happens when the external pressure applied becomes more than the osmotic pressure of solution?


Which of the following 0.1 M aqueous solutions will exert the highest osmotic pressure?


Calculate the mass of NaCl (molar mass = 58.5 g mol−1) to be dissolved in 37.2 g of water to lower the freezing point by 2°C, assuming that NaCl undergoes complete dissociation. (Kf for water = 1.86 K kg mol−1)


Calculate the mass of a compound (molar mass = 256 g mol−1) to be dissolved in 75 g of benzene to lower its freezing point by 0.48 K (Kf = 5.12 K kg mol−1).


Define the following term:
isotonic solution


Define the following term:

Hypotonic solution


Answer the following.

What are isotonic and hypertonic solutions?


Answer the following.

A solvent and its solution containing a nonvolatile solute are separated by a semipermeable membrane. Does the flow of solvent occur in both directions? Comment giving a reason.


Answer the following.

The osmotic pressure of CaCl2 and urea solutions of the same concentration at the same temperature are respectively 0.605 atm and 0.245 atm, calculate van’t Hoff factor for CaCl2.


Answer the following.

Explain reverse osmosis.


Which of the following statements is applicable for 0.1 M urea solution and 0.1 M sucrose solution?


Explain the phenomenon of osmosis.


Define Osmosis.


Which of the following is a colligative property?


Two solutions have different osmotic pressures. The solution of higher osmotic pressure is called ____________.


20 g of a substance were dissolved in 500 mL of water and the osmotic pressure of the solution was found to be 600 mm of mercury at 15°C. The molecular weight of the substance is ______.


Osmotic pressure of a solution is 0.0821 atm at a temperature of 300 K. The concentration in moles/litre will be:


The temperature at which 10% aqueous solution of (W/V) of glucose will show the osmotic pressure of 16.4 atoms is: (R = 0.082 L atom K−1 mol1)


At a given temperature, osmotic pressure of a concentrated solution of a substance ______.


Which of the following statements is false?


Isotonic solutions must have the same:

(i) solute

(ii) density

(iii) elevation in boiling point

(iv) depression in freezing point


In isotonic solutions:

(i) Solute and solvent both are same.

(ii) Osmotic pressure is same.

(iii) Solute and solvent may or may not be same.

(iv) Solute is always same solvent may be different.


Give an example of a material used for making semipermeable membrane for carrying out reverse osmosis.


Discuss biological and industrial importance of osmosis.


Which of the following colligative property can provide molar mass of proteins (or polymers or colloids) with greatest precision?


Isotonic solutions have same


Which one of the following is a colligative property?


In Isotonic solution


The vapour pressure of water is 12.3 k pa at 300 k. Calculated the vapour pressure of molal solution in it.


Osmotic pressure of a solution containing 2 g dissolved protein per 300 cm3 of solution is 20 mm of Hg at 27°C. The molecular mass of protein is ______.


The following solutions were prepared by dissolving 10 g of glucose (C6H12O6) in 250 ml of water (P1), 10 g of urea (CH4N2O) in 250 ml of water (P2) and 10 g of sucrose (C12H22O11) in 250 ml of water (P3). The right option for the decreasing order of osmotic pressure of these solutions is


Assertion (A) : Osmotic pressure is a colligative property.

Reason (R) : Osmotic pressure is proportional to the molality.


Isotonic solutions are the solutions having the same ______.


A solution containing 10 g glucose has osmotic pressure 3.84 atm. If 10 g more glucose is added to the same solution, what will be its osmotic pressure? (Temperature remains constant)


Prove that: M2 = `(W_2RT)/(πV)`.


Arrange the following solutions in the order of increasing osmotic pressure (π) assuming complete ionization.

  1. 0.5M Li2 SO4
  2. 0.5M KCl
  3. 0.5M Al2 (SO4)3 
  4. 0.1 M BaCl2

Write the condition of reverse osmosis.


The plot of osmotic pressure (π) vs concentration (mol L−1) for a solution gives a straight line with slope 25.73 L bar mol−1. The temperature at which the osmotic pressure measurement is done is ______.

(Use R = 0.083 L bar mol−1 K−1)


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