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प्रश्न
Answer the following.
What are isotonic and hypertonic solutions?
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उत्तर
- Isotonic solutions: Two or more solutions having the same osmotic pressure are said to be isotonic solutions.
e.g. For example, 0.1 M urea solution and 0.1 M sucrose solution are isotonic because their osmotic pressures are equal. Such solutions have the same molar concentrations but different concentrations in g/L. If these solutions are separated by a semipermeable membrane, there is no flow of solvent in either direction. - Hypertonic solution: If two solutions have unequal osmotic pressures, the more concentrated solution with higher osmotic pressure is said to be the hypertonic solution.
e.g. For example, if osmotic pressure of sucrose solution is higher than that of urea solution, the sucrose solution is hypertonic to urea solution.
संबंधित प्रश्न
Which of the following is not a colligative property?
What happens when the external pressure applied becomes more than the osmotic pressure of solution?
A solution containing 15 g urea (molar mass = 60 g mol–1) per litre of solution in water has the same osmotic pressure (isotonic) as a solution of glucose (molar mass = 180 g mol–1) in water. Calculate the mass of glucose present in one litre of its solution.
Calculate the osmotic pressure in pascals exerted by a solution prepared by dissolving 1.0 g of polymer of molar mass 185,000 in 450 mL of water at 37°C.
Determine the amount of CaCl2 (i = 2.47) dissolved in 2.5 litre of water such that its osmotic pressure is 0.75 atm at 27°C.
Determine the osmotic pressure of a solution prepared by dissolving 25 mg of K2SO4 in 2 liter of water at 25°C, assuming that it is completely dissociated.
Which of the following 0.1 M aqueous solutions will exert the highest osmotic pressure?
Calculate the mass of a compound (molar mass = 256 g mol−1) to be dissolved in 75 g of benzene to lower its freezing point by 0.48 K (Kf = 5.12 K kg mol−1).
Define the following term:
isotonic solution
Define the following term:
Hypotonic solution
Choose the most correct option.
In calculating osmotic pressure the concentration of solute is expressed in _______.
Choose the most correct option.
A living cell contains a solution which is isotonic with 0.3 M sugar solution. What osmotic pressure develops when the cell is placed in 0.1 M KCl solution at body temperature?
Answer the following in one or two sentences.
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Answer the following.
A solvent and its solution containing a nonvolatile solute are separated by a semipermeable membrane. Does the flow of solvent occur in both directions? Comment giving a reason.
Answer the following.
The osmotic pressure of CaCl2 and urea solutions of the same concentration at the same temperature are respectively 0.605 atm and 0.245 atm, calculate van’t Hoff factor for CaCl2.
Answer the following.
How molar mass of a solute is determined by osmotic pressure measurement?
What are hypertonic solutions?
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Explain the phenomenon of osmosis.
Define Osmosis.
Which of the following is a colligative property?
Two solutions have different osmotic pressures. The solution of higher osmotic pressure is called ____________.
At constant temperature the osmotic pressure of a solution is ____________.
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Osmotic pressure of a solution is 0.0821 atm at a temperature of 300 K. The concentration in moles/litre will be:
Which of the following statements is false?
In isotonic solutions:
(i) Solute and solvent both are same.
(ii) Osmotic pressure is same.
(iii) Solute and solvent may or may not be same.
(iv) Solute is always same solvent may be different.
Match the items given in Column I and Column II.
| Column I | Column II |
| (i) Saturated solution | (a) Solution having same osmotic pressure at a given temperature as that of given solution. |
| (ii) Binary solution | (b) A solution whose osmotic pressure is less than that of another. |
| (iii) Isotonic solution | (c) Solution with two components. |
| (iv) Hypotonic solution | (d) A solution which contains maximum amount of solute that can be dissolved in a given amount of solvent at a given temperature. |
| (v) Solid solution | (e) A solution whose osmotic pressure is more than that of another. |
| (vi) Hypertonic solution | (f) A solution in solid phase. |
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Osmotic pressure of a solution increases if
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Assertion (A) : Osmotic pressure is a colligative property.
Reason (R) : Osmotic pressure is proportional to the molality.
Determine the osmotic pressure of a solution prepared by dissolving 2.32 × 10−2 g of K2SO4 in 2L of solution at 25°C assuming that K2SO4 is completely dissociated.
(R = 0.082 L atm K−1 mol, Molar mass K2SO4 = 174 g mol−1)
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Define reverse osmosis.
How will you determine molar mass of solute from osmotic pressure?
Write the condition of reverse osmosis.
The 'X' g nonvolatile solute having molar mass 196 g mol-1 is dissolved in 3 dm³ water. Calculate the value of 'X' if resulting solution has osmotic pressure 0.8 atm at 300 К.
(R = 0.0821dm³ atm K-1 mol-1)
The plot of osmotic pressure (π) vs concentration (mol L−1) for a solution gives a straight line with slope 25.73 L bar mol−1. The temperature at which the osmotic pressure measurement is done is ______.
(Use R = 0.083 L bar mol−1 K−1)
