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Define osmotic pressure. - Chemistry

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प्रश्न

Define osmotic pressure.

व्याख्या
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उत्तर

Osmotic pressure may be defined as the external pressure which should be applied to the solution in order to stop the phenomenon of osmosis, i.e., to stop the flow of solvent into the solution when the two are separated by a semipermeable membrane.

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संबंधित प्रश्‍न

Determine the osmotic pressure of a solution prepared by dissolving 2.5 × 10−2 g of K2SO4 in 2L of water at 25°C, assuming that it is completely dissociated.

(R = 0.0821 L atm K−1 mol−1, Molar mass of K2SO4 = 174 g mol−1)


A solution containing 15 g urea (molar mass = 60 g mol–1) per litre of solution in water has the same osmotic pressure (isotonic) as a solution of glucose (molar mass = 180 g mol–1) in water. Calculate the mass of glucose present in one litre of its solution.


Calculate the osmotic pressure in pascals exerted by a solution prepared by dissolving 1.0 g of polymer of molar mass 185,000 in 450 mL of water at 37°C.


At 300 K, 36 g of glucose present in a litre of its solution has an osmotic pressure of 4.98 bar. If the osmotic pressure of the solution is 1.52 bars at the same temperature, what would be its concentration?


Determine the amount of CaCl2 (i = 2.47) dissolved in 2.5 litre of water such that its osmotic pressure is 0.75 atm at 27°C.


Which of the following 0.1 M aqueous solutions will exert the highest osmotic pressure?


Calculate the mass of a compound (molar mass = 256 g mol−1) to be dissolved in 75 g of benzene to lower its freezing point by 0.48 K (Kf = 5.12 K kg mol−1).


Define the following term:
isotonic solution


Define the following term:

Hypotonic solution


Choose the most correct option.

In calculating osmotic pressure the concentration of solute is expressed in _______.


Choose the most correct option.

A living cell contains a solution which is isotonic with 0.3 M sugar solution. What osmotic pressure develops when the cell is placed in 0.1 M KCl solution at body temperature?


Choose the most correct option.

The osmotic pressure of blood is 7.65 atm at 310 K. An aqueous solution of glucose isotonic with blood has the percentage (by volume)________.


Answer the following in one or two sentences.

What is osmotic pressure?


Answer the following.

What are isotonic and hypertonic solutions?


An aqueous solution of a certain organic compound has a density of 1.063 g mL-1 , osmotic pressure of 12.16 atm at 25 °C and a freezing point of 1.03 °C. What is the molar mass of the compound?


What are hypertonic solutions?


Explain the phenomenon of osmosis.


Define Osmosis.


Which of the following is a colligative property?


Two solutions have different osmotic pressures. The solution of higher osmotic pressure is called ____________.


At constant temperature the osmotic pressure of a solution is ____________.


Osmotic pressure of a solution is 0.0821 atm at a temperature of 300 K. The concentration in moles/litre will be:


A solution containing 10 g per dm3 of urea (molar mass 60 g mol−1) is isotonic with 5% solution of non-volatile solute, MB of solute is:


The temperature at which 10% aqueous solution of (W/V) of glucose will show the osmotic pressure of 16.4 atoms is: (R = 0.082 L atom K−1 mol1)


At a given temperature, osmotic pressure of a concentrated solution of a substance ______.


Which of the following statements is false?


In isotonic solutions:

(i) Solute and solvent both are same.

(ii) Osmotic pressure is same.

(iii) Solute and solvent may or may not be same.

(iv) Solute is always same solvent may be different.


Give an example of a material used for making semipermeable membrane for carrying out reverse osmosis.


Discuss biological and industrial importance of osmosis.


How can you remove the hard calcium carbonate layer of the egg without damaging its semiprermiable membrane? Can this egg be inserted into a bottle with a narrow neck without distorting its shape? Explain the process involved.


Osmotic pressure of a solution increases if


Isotonic solutions have same


Blood cells retain their normal shape in solution which are


In Isotonic solution


The vapour pressure of water is 12.3 k pa at 300 k. Calculated the vapour pressure of molal solution in it.


Osmotic pressure of a solution containing 2 g dissolved protein per 300 cm3 of solution is 20 mm of Hg at 27°C. The molecular mass of protein is ______.


The following solutions were prepared by dissolving 10 g of glucose (C6H12O6) in 250 ml of water (P1), 10 g of urea (CH4N2O) in 250 ml of water (P2) and 10 g of sucrose (C12H22O11) in 250 ml of water (P3). The right option for the decreasing order of osmotic pressure of these solutions is


Derive an expression to calculate molar mass of non-volatile solute by osmotic pressure measurement.


Determine the osmotic pressure of a solution prepared by dissolving 2.32 × 10−2 g of K2SO4 in 2L of solution at 25°C assuming that K2SO4 is completely dissociated.

(R = 0.082 L atm K−1 mol, Molar mass K2SO4 = 174 g mol−1)


Isotonic solutions are the solutions having the same ______.


Prove that: M2 = `(W_2RT)/(πV)`.


Arrange the following solutions in the order of increasing osmotic pressure (π) assuming complete ionization.

  1. 0.5M Li2 SO4
  2. 0.5M KCl
  3. 0.5M Al2 (SO4)3 
  4. 0.1 M BaCl2

How will you determine molar mass of solute from osmotic pressure?


Write the condition of reverse osmosis.


Calculate the osmotic pressure of 0.03 mole of non electrolyte solute dissolved in 0.1 dm3 of water at 300 K. [R = 0.082 dm3 atm mol-1 K-1]


The 'X' g nonvolatile solute having molar mass 196 g mol-1 is dissolved in 3 dm³ water. Calculate the value of 'X' if resulting solution has osmotic pressure 0.8 atm at 300 К.
(R = 0.0821dm³ atm K-1 mol-1)


The plot of osmotic pressure (π) vs concentration (mol L−1) for a solution gives a straight line with slope 25.73 L bar mol−1. The temperature at which the osmotic pressure measurement is done is ______.

(Use R = 0.083 L bar mol−1 K−1)


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