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Answer the following. A solvent and its solution containing a nonvolatile solute are separated by a semipermeable membrane. Does the flow of solvent occur in both directions? Comment giving a reason. - Chemistry

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प्रश्न

Answer the following.

A solvent and its solution containing a nonvolatile solute are separated by a semipermeable membrane. Does the flow of solvent occur in both directions? Comment giving a reason.

टीपा लिहा
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उत्तर

1. When a solution and pure solvent or two solutions of different concentrations are separated by a semipermeable membrane, the solvent molecules pass through the membrane.

2. The passage of solvent molecules through the semipermeable membrane takes place in both directions, since the solvent is on both sides of the membrane.

3. However, the rate of passage of solvent molecules into the solution or from a more dilute solution to more concentrated solution is found to be greater than the rate in the reverse direction.

4. This is favorable since the vapour pressure of solvent is greater than that of solution.

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पाठ 2: Solutions - Exercises [पृष्ठ ४६]

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बालभारती Chemistry [English] Standard 12 Maharashtra State Board
पाठ 2 Solutions
Exercises | Q 3.3 | पृष्ठ ४६

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संबंधित प्रश्‍न

Determine the osmotic pressure of a solution prepared by dissolving 2.5 × 10−2 g of K2SO4 in 2L of water at 25°C, assuming that it is completely dissociated.

(R = 0.0821 L atm K−1 mol−1, Molar mass of K2SO4 = 174 g mol−1)


Which of the following is not a colligative property?


What happens when the external pressure applied becomes more than the osmotic pressure of solution?


A solution containing 15 g urea (molar mass = 60 g mol–1) per litre of solution in water has the same osmotic pressure (isotonic) as a solution of glucose (molar mass = 180 g mol–1) in water. Calculate the mass of glucose present in one litre of its solution.


Calculate the osmotic pressure in pascals exerted by a solution prepared by dissolving 1.0 g of polymer of molar mass 185,000 in 450 mL of water at 37°C.


Determine the osmotic pressure of a solution prepared by dissolving 25 mg of K2SO4 in 2 liter of water at 25°C, assuming that it is completely dissociated.


Define osmotic pressure.


Which of the following 0.1 M aqueous solutions will exert the highest osmotic pressure?


Define Semipermeable membrane


Calculate the mass of NaCl (molar mass = 58.5 g mol−1) to be dissolved in 37.2 g of water to lower the freezing point by 2°C, assuming that NaCl undergoes complete dissociation. (Kf for water = 1.86 K kg mol−1)


Calculate the mass of a compound (molar mass = 256 g mol−1) to be dissolved in 75 g of benzene to lower its freezing point by 0.48 K (Kf = 5.12 K kg mol−1).


Choose the most correct option.

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Choose the most correct option.

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Answer the following in one or two sentences.

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Answer the following in one or two sentences.

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Answer the following.

The osmotic pressure of CaCl2 and urea solutions of the same concentration at the same temperature are respectively 0.605 atm and 0.245 atm, calculate van’t Hoff factor for CaCl2.


Answer the following.

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Answer the following.

How molar mass of a solute is determined by osmotic pressure measurement?


An aqueous solution of a certain organic compound has a density of 1.063 g mL-1 , osmotic pressure of 12.16 atm at 25 °C and a freezing point of 1.03 °C. What is the molar mass of the compound?


Which of the following is a colligative property?


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(i) solute

(ii) density

(iii) elevation in boiling point

(iv) depression in freezing point


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In Isotonic solution


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Derive an expression to calculate molar mass of non-volatile solute by osmotic pressure measurement.


Assertion (A) : Osmotic pressure is a colligative property.

Reason (R) : Osmotic pressure is proportional to the molality.


Determine the osmotic pressure of a solution prepared by dissolving 2.32 × 10−2 g of K2SO4 in 2L of solution at 25°C assuming that K2SO4 is completely dissociated.

(R = 0.082 L atm K−1 mol, Molar mass K2SO4 = 174 g mol−1)


Isotonic solutions are the solutions having the same ______.


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(R = 0.0821dm³ atm K-1 mol-1)


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