Advertisements
Advertisements
प्रश्न
How will you determine molar mass of solute from osmotic pressure?
Advertisements
उत्तर
For very dilute solution, osmotic pressure is given by
πV = n2RT
where,
π = Osmotic pressure in atm.
V = Volume of a solution in dm3
n2 = Moles of non-volatile solute
R = Gas constant = 0.082L dm3 atm K−1mol−1
T = temperature in Kelvin
∴ `pi = (n_2RT)/V`
`pi = (W_2RT)/(M_2V) ...[because n_2 = W_2/M_2]`
∴ `M_2 = (W_2 R T)/(pi V)`
APPEARS IN
संबंधित प्रश्न
Determine the osmotic pressure of a solution prepared by dissolving 2.5 × 10−2 g of K2SO4 in 2L of water at 25°C, assuming that it is completely dissociated.
(R = 0.0821 L atm K−1 mol−1, Molar mass of K2SO4 = 174 g mol−1)
Which of the following is not a colligative property?
Blood cells are isotonic with 0.9% sodium chloride solution. What happens if we place blood cells in a solution containing
(i) 1.2% sodium chloride solution?
(ii) 0.4% sodium chloride solution?
A solution containing 15 g urea (molar mass = 60 g mol–1) per litre of solution in water has the same osmotic pressure (isotonic) as a solution of glucose (molar mass = 180 g mol–1) in water. Calculate the mass of glucose present in one litre of its solution.
At 300 K, 36 g of glucose present in a litre of its solution has an osmotic pressure of 4.98 bar. If the osmotic pressure of the solution is 1.52 bars at the same temperature, what would be its concentration?
Determine the amount of CaCl2 (i = 2.47) dissolved in 2.5 litre of water such that its osmotic pressure is 0.75 atm at 27°C.
Determine the osmotic pressure of a solution prepared by dissolving 25 mg of K2SO4 in 2 liter of water at 25°C, assuming that it is completely dissociated.
Define osmotic pressure.
Which of the following 0.1 M aqueous solutions will exert the highest osmotic pressure?
Define Semipermeable membrane
Calculate the mass of a compound (molar mass = 256 g mol−1) to be dissolved in 75 g of benzene to lower its freezing point by 0.48 K (Kf = 5.12 K kg mol−1).
Define the following term:
isotonic solution
Choose the most correct option.
A living cell contains a solution which is isotonic with 0.3 M sugar solution. What osmotic pressure develops when the cell is placed in 0.1 M KCl solution at body temperature?
Answer the following in one or two sentences.
What is osmotic pressure?
Answer the following in one or two sentences.
A solution concentration is expressed in molarity and not in molality while considering osmotic pressure. Why?
Answer the following.
The osmotic pressure of CaCl2 and urea solutions of the same concentration at the same temperature are respectively 0.605 atm and 0.245 atm, calculate van’t Hoff factor for CaCl2.
Answer the following.
Explain reverse osmosis.
An aqueous solution of a certain organic compound has a density of 1.063 g mL-1 , osmotic pressure of 12.16 atm at 25 °C and a freezing point of 1.03 °C. What is the molar mass of the compound?
Explain the osmotic pressure of a solution with the help of a thistle tube.
Explain the phenomenon of osmosis.
Define Osmosis.
Which of the following is a colligative property?
Two solutions have different osmotic pressures. The solution of higher osmotic pressure is called ____________.
At constant temperature the osmotic pressure of a solution is ____________.
The average osmotic pressure of human blood is 7.8 bar at 37°C. What is the concentration of an aqueous NaCl solution that could be used in the blood stream?
The temperature at which 10% aqueous solution of (W/V) of glucose will show the osmotic pressure of 16.4 atoms is: (R = 0.082 L atom K−1 mol−1)
At a given temperature, osmotic pressure of a concentrated solution of a substance ______.
Which of the following colligative property can provide molar mass of proteins (or polymers or colloids) with greatest precision?
Which one of the following is a colligative property?
In Isotonic solution
Osmotic pressure of a solution containing 2 g dissolved protein per 300 cm3 of solution is 20 mm of Hg at 27°C. The molecular mass of protein is ______.
Assertion (A) : Osmotic pressure is a colligative property.
Reason (R) : Osmotic pressure is proportional to the molality.
Determine the osmotic pressure of a solution prepared by dissolving 2.32 × 10−2 g of K2SO4 in 2L of solution at 25°C assuming that K2SO4 is completely dissociated.
(R = 0.082 L atm K−1 mol, Molar mass K2SO4 = 174 g mol−1)
Isotonic solutions are the solutions having the same ______.
Prove that: M2 = `(W_2RT)/(πV)`.
Arrange the following solutions in the order of increasing osmotic pressure (π) assuming complete ionization.
- 0.5M Li2 SO4
- 0.5M KCl
- 0.5M Al2 (SO4)3
- 0.1 M BaCl2
Define reverse osmosis.
Write the condition of reverse osmosis.
Calculate the osmotic pressure of 0.03 mole of non electrolyte solute dissolved in 0.1 dm3 of water at 300 K. [R = 0.082 dm3 atm mol-1 K-1]
The 'X' g nonvolatile solute having molar mass 196 g mol-1 is dissolved in 3 dm³ water. Calculate the value of 'X' if resulting solution has osmotic pressure 0.8 atm at 300 К.
(R = 0.0821dm³ atm K-1 mol-1)
