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महाराष्ट्र राज्य शिक्षण मंडळएचएससी विज्ञान (सामान्य) इयत्ता १२ वी

Define the term Hydrated isomers.

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प्रश्न

Define the term Hydrated isomers.

व्याख्या
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उत्तर

Isomers in which there is exchange of solvent (water) ligands between coordination and ionization spheres are called hydrate isomers.

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पाठ 9: Coordination Compounds - Short Answer Questions (Type-Ⅰ)

APPEARS IN

एससीईआरटी महाराष्ट्र Chemistry [English] 12 Standard HSC
पाठ 9 Coordination Compounds
Short Answer Questions (Type-Ⅰ) | Q 5.2
एससीईआरटी महाराष्ट्र Chemistry [English] 12 Standard HSC
पाठ 9 Coordination Compounds
Short Answer Questions (Type-II) | Q 2.1

संबंधित प्रश्‍न

List various types of isomerism possible for coordination compounds, giving an example of each.


Choose the most correct option.

Which of the following complexes exist as cis and trans isomers?

1. [Cr(NH3)2Cl4]-

2. [Co(NH3)5Br]2⊕

3. [PtCl2Br2]2- (square planar)

4. [FeCl2(NCS)2]2- (tetrahedral)


Answer in brief.

What are ionization isomers ? Give an example.


Define the term Co-ordination isomer.


Which type of isomerism is exhibited by [Pt(NH3)2Cl2]?


How many geometrical isomers are possible for \[\ce{[Pt(Py)(NH3)(Br)(Cl)]}\]?


Which one of the following pairs represents linkage isomers?


What are hydrate isomers? Explain with an example.


Which of the following is NOT a pair of structural isomers?


Consider the two complexes given below:

\[\ce{\underset{(I)}{[Co(NH3)5SO4]Br}}\] and \[\ce{\underset{(II)}{[Co(NH3)5Br]SO4}}\]

I and II are ____________ isomers.


Which of the following does NOT show optical isomerism?


The complex ions [Co(H2O)5(ONO)]2+ and [Co(H2O)5NO2]2+ are ____________.


The formula of two complexes X and Y of chromium are given below:

\[\ce{\underset{(X)}{[Cr(H2O)6]Cl3}}\] and \[\ce{\underset{(Y)}{[Cr(H2O)5Cl]Cl2.H2O}}\]

X and Y are examples of ____________ isomers.


Which of the following has zero dipole moment?


\[\ce{IUPAC}\] name of \[\ce{[Pt(NH3)2 Cl(NO2)]}\] is ______.


Assertion: Complexes of MX6 and MX5L type (X and L are unidentate) do not show geometrical isomerism.

Reason: Geometrical isomerism is not shown by complexes of coordination number 6.


Geometrical isomerism is not shown by


Which of the following does not show optical isomerism?


Complex [COCl2(en)2]+ can 


Which of the following compounds show optical isomerism?


\[\ce{CH3CH2COO- Na+ ->[NaOH, + ?][Heat] CH3CH3 + Na2CO3}\]

Consider the above reaction and identify the missing reagent/chemical.


Write the name of isomerism in the following complexes:

[Cu(NH3)4] [PtCl4] and [Pt(NH3)4] [ CuCl4]


Draw geometric isomers of the following complex.

Geometrical isomers of Pt(NH3)2Cl2


Which of the following are isostructural pairs?

(A) \[\ce{SO^{2-}4}\] and \[\ce{CrO^{2-}4}\]

(B) SiCl4 and TiCl4

(C) NH3 and \[\ce{NO^-3}\]

(D) BCl3 and BrCl3


Which compound would exhibit optical isomers?


Give cis isomer of [Co(NH3)4Cl2].


Explain the geometrical isomerism of the octahedral complex of the type [M(AA)2B2]with a suitable example.


Name the type of isomerism exhibited by the following pair of compounds:

[Cr(H2O)5Cl]Cl2.H2O and [Cr(H2O)4Cl2]Cl.2H2O


Name the type of isomerism exhibited by the following pair of compound:

\[\ce{[Pt(NH3)4Cl2]Br2  and  [Pt(NH3)4 Br2]Cl2}\]


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