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Question
Define the term Hydrated isomers.
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Solution
Isomers in which there is exchange of solvent (water) ligands between coordination and ionization spheres are called hydrate isomers.
RELATED QUESTIONS
Write the structural formula and IUPAC names of all possible isomers of the compound with molecular formula C3H8O.
List various types of isomerism possible for coordination compounds, giving an example of each.
Choose the most correct option.
Which of the following complexes exist as cis and trans isomers?
1. [Cr(NH3)2Cl4]-
2. [Co(NH3)5Br]2⊕
3. [PtCl2Br2]2- (square planar)
4. [FeCl2(NCS)2]2- (tetrahedral)
Answer the following question.
Draw isomers of the following
[Cr(en2)Br2]⊕
Write the type of isomerism exhibited by [Co(NH3)5(NO2)]2+ and [Co(NH3)5ONO]2+ pair of complex ion.
Draw the geometrical isomers of the following complexes [Pt(NH3)(H2O)Cl2].
Which one of the following will give a pair of enantiomorphs?
What is linkage isomerism? Explain with an example.
The compound(s) that exhibit(s) geometrical isomerism is (are):
(I) [Pt(en)Cl2]
(II) [Pt(en)2]Cl2
(III) [Pt(en)2Cl2]
(IV) [Pt(NH3)2Cl2]
____________ isomers are formed when the ligand has two different donor atoms.
The complex ions [Co(H2O)5(ONO)]2+ and [Co(H2O)5NO2]2+ are ____________.
Which of the following has zero dipole moment?
\[\ce{IUPAC}\] name of \[\ce{[Pt(NH3)2 Cl(NO2)]}\] is ______.
Complex [COCl2(en)2]+ can
Which among the following solid is a non-polar solid?
Define Distereoisomers.
Indicate the type of isomerism exhibited by the following complex and draw the structures for this isomer:
\[\ce{[Pt(NH3)(H2O)Cl2]}\]
Write structures for geometrical isomers of diamminebromochloroplatinum (II).
Explain the ionisation isomers.
Draw the structure of cis isomers of Pt(NH3)2Cl2.
The co-ordination number of Co3+ ion in the complex [Co(NH3)4Cl2]⊕ is ______.
Name the type of isomerism exhibited by the following pair of compound:
\[\ce{[Pt(NH3)4Cl2]Br2 and [Pt(NH3)4 Br2]Cl2}\]
Which one of the following complex ions has geometrical isomers?
Three organic compounds A, B and C are non cyclic functional isomers of carbonyl compounds with molecular formula C4H8O. Isomers A and C give positive Tollen’s test while compound B does not give positive Tollen’s test but gives positive iodoform test. Compounds A and B on reduction with Zn amalgam and conc. HCl give the same product.
- Write the structures of the compounds A, B and C.
- Out of the compounds A, B and C, which one will be the least reactive towards addition of HCN.
Match List-I with List-II:
| List-I (Complex) |
List-II (Type of isomerism) |
| A. [Co(NH3)5(NO2)]Cl2 | I. Solvate isomerism |
| B. [Co(NH3)5(SO4)]Br | II. Linkage isomerism |
| C. [Co(NH3)6][Cr(CN)6] | III. Ionisation isomerism |
| D. [Co(H2O)6]Cl3 | IV. Coordination isomerism |
Choose the correct answer from the options given below:
