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प्रश्न
Define the term Hydrated isomers.
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उत्तर
Isomers in which there is exchange of solvent (water) ligands between coordination and ionization spheres are called hydrate isomers.
संबंधित प्रश्न
List various types of isomerism possible for coordination compounds, giving an example of each.
Answer in brief.
What are ionization isomers ? Give an example.
Answer the following question.
Draw geometric isomers and enantiomers of the following complex.
[Pt(en)3]4⊕
Answer the following question.
Draw geometric isomers and enantiomers of the following complex.
[Pt(en)2ClBr]2⊕
Draw optical isomers of [Co(en)3]3+.
Which one of the following pairs represents linkage isomers?
What are hydrate isomers? Explain with an example.
Which would exhibit coordination isomerism?
The compound(s) that exhibit(s) geometrical isomerism is (are):
(I) [Pt(en)Cl2]
(II) [Pt(en)2]Cl2
(III) [Pt(en)2Cl2]
(IV) [Pt(NH3)2Cl2]
The number of geometrical isomers of [CrCl2(en)2]+ is ____________.
How many donor groups are present in diethylene triamine?
What type of isomerism is present between (I) [Cr(H2O)6]Cl3 and (II) [Cr(H2O)5Cl]Cl2.H2O?
Indicate the complex ion which shows geometrical isomerism.
Complex [COCl2(en)2]+ can
Which of the following has an optical isomer?
Which of the following are isostructural pairs?
(A) \[\ce{SO^{2-}4}\] and \[\ce{CrO^{2-}4}\]
(B) SiCl4 and TiCl4
(C) NH3 and \[\ce{NO^-3}\]
(D) BCl3 and BrCl3
White precipitate of AgCl dissolves in aqueous ammonia solution due to formation of ______.
Which among the following solid is a non-polar solid?
Define Distereoisomers.
Give trans isomer of [Co(NH3)4Cl2]⊕.
Indicate the type of isomerism exhibited by the following complex and draw the structures for this isomer:
\[\ce{[Pt(NH3)(H2O)Cl2]}\]
Explain the geometrical isomerism of the octahedral complex of the type [M(AA)2B2]n± with a suitable example.
Explain the ionisation isomers.
Draw the structure of trans isomers of Pt(NH3)2Cl2.
The co-ordination number of Co3+ ion in the complex [Co(NH3)4Cl2]⊕ is ______.
Three organic compounds A, B and C are non cyclic functional isomers of carbonyl compounds with molecular formula C4H8O. Isomers A and C give positive Tollen’s test while compound B does not give positive Tollen’s test but gives positive iodoform test. Compounds A and B on reduction with Zn amalgam and conc. HCl give the same product.
- Write the structures of the compounds A, B and C.
- Out of the compounds A, B and C, which one will be the least reactive towards addition of HCN.
Match List-I with List-II:
| List-I (Complex) |
List-II (Type of isomerism) |
| A. [Co(NH3)5(NO2)]Cl2 | I. Solvate isomerism |
| B. [Co(NH3)5(SO4)]Br | II. Linkage isomerism |
| C. [Co(NH3)6][Cr(CN)6] | III. Ionisation isomerism |
| D. [Co(H2O)6]Cl3 | IV. Coordination isomerism |
Choose the correct answer from the options given below:
