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प्रश्न
Define the term Hydrated isomers.
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उत्तर
Isomers in which there is exchange of solvent (water) ligands between coordination and ionization spheres are called hydrate isomers.
संबंधित प्रश्न
Give one chemical test as an evidence to show that [Co (NH3)5Cl] are ionisation isomers.
Choose the most correct option.
Which of the following complexes exist as cis and trans isomers?
1. [Cr(NH3)2Cl4]-
2. [Co(NH3)5Br]2⊕
3. [PtCl2Br2]2- (square planar)
4. [FeCl2(NCS)2]2- (tetrahedral)
Answer the following in one or two sentences.
Consider the complexes \[\ce{[Cu(NH3)4][PtCl4] and [Pt(NH3)4] [CuCl4]}\]. What type of isomerism these two complexes exhibit?
Draw optical isomers of [Co(en)3]3+.
Which kind of isomerism is possible for a complex [Co(NH3)4Br2]Cl?
What are hydrate isomers? Explain with an example.
The term anomers of glucose refer to ____________.
Which of the following is NOT a pair of structural isomers?
Which of the following does NOT show optical isomerism?
The complex ions [Co(H2O)5(ONO)]2+ and [Co(H2O)5NO2]2+ are ____________.
Which of the following has zero dipole moment?
How many donor groups are present in diethylene triamine?
What type of isomerism is present between (I) [Cr(H2O)6]Cl3 and (II) [Cr(H2O)5Cl]Cl2.H2O?
The relationship between compound (i) and (ii) is
 |
 |
| (i) | (ii) |
The correct structure of Fe(CO)5 is
Which of the following does not show optical isomerism?
\[\ce{CH3CH2COO- Na+ ->[NaOH, + ?][Heat] CH3CH3 + Na2CO3}\]
Consider the above reaction and identify the missing reagent/chemical.
Write the name of isomerism in the following complexes:
[Cu(NH3)4] [PtCl4] and [Pt(NH3)4] [ CuCl4]
Which of the following are isostructural pairs?
(A) \[\ce{SO^{2-}4}\] and \[\ce{CrO^{2-}4}\]
(B) SiCl4 and TiCl4
(C) NH3 and \[\ce{NO^-3}\]
(D) BCl3 and BrCl3
White precipitate of AgCl dissolves in aqueous ammonia solution due to formation of ______.
The compounds [PtCl2(NH3)4]Br2 and [PtBr2(NH3)4]Cl2 constitutes a pair of ______.
What are structural isomers?
Match the pairs in column I (pairs of isomers) and column II (types of isomers)
| Column I (Pairs of isomers) |
Column II (Types of isomers) |
| (A) [Cr(H2O)5Cl]Cl2.H2O and [Cr(H2O)4Cl2]Cl.2H2O | (i) Ionization isomers |
| (B) [Co(en)2(NO2)2]+ and [Co(en)2(ONO2)]+ | (ii) Hydrate isomers |
| (C) [Co(NH3)6] [Cr(CN)6] and [Cr(NH3)6] [Co(CN)6] | (iii) Linkage isomers |
| (D) [Pt(NH3)4Cl2] Br2 and [Pt(NH3)4Br2]Cl2 | (iv) Coordination isomers |
Name the type of isomerism exhibited by the following pair of compounds:
[Co(NH3)5(ONO)]Cl2 and [Co(NH3)5(NO2)]Cl2
Name the type of isomerism exhibited by the following pair of compounds:
[Cr(H2O)5Cl]Cl2.H2O and [Cr(H2O)4Cl2]Cl.2H2O
Name the type of isomerism exhibited by the following pair of compound:
\[\ce{[Pt(NH3)4Cl2]Br2 and [Pt(NH3)4 Br2]Cl2}\]
Three organic compounds A, B and C are non cyclic functional isomers of carbonyl compounds with molecular formula C4H8O. Isomers A and C give positive Tollen’s test while compound B does not give positive Tollen’s test but gives positive iodoform test. Compounds A and B on reduction with Zn amalgam and conc. HCl give the same product.
- Write the structures of the compounds A, B and C.
- Out of the compounds A, B and C, which one will be the least reactive towards addition of HCN.
