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प्रश्न
Define the term Co-ordination isomer.
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उत्तर
Isomers which show interchange of ligands between cationic and anionic spheres of different metal ions are called co-ordination isomers.
संबंधित प्रश्न
List various types of isomerism possible for coordination compounds, giving an example of each.
Choose the most correct option.
Which of the following complexes exist as cis and trans isomers?
1. [Cr(NH3)2Cl4]-
2. [Co(NH3)5Br]2⊕
3. [PtCl2Br2]2- (square planar)
4. [FeCl2(NCS)2]2- (tetrahedral)
Answer the following in one or two sentences.
Predict whether the [Cr(en)2(H2O)2]3+ complex is chiral. Write the structure of its enantiomer.
Answer the following in one or two sentences.
Consider the complexes \[\ce{[Cu(NH3)4][PtCl4] and [Pt(NH3)4] [CuCl4]}\]. What type of isomerism these two complexes exhibit?
Answer the following question.
Draw geometric isomers and enantiomers of the following complex.
[Pt(en)2ClBr]2⊕
The pair [Co(NH3)5(SO4)]Br and [Co(NH3)5Br]SO4 exhibits ____________ isomerism
How many geometrical isomers are possible for \[\ce{[Pt(Py)(NH3)(Br)(Cl)]}\]?
Explain optical isomerism in coordination compounds with an example.
The compound(s) that exhibit(s) geometrical isomerism is (are):
(I) [Pt(en)Cl2]
(II) [Pt(en)2]Cl2
(III) [Pt(en)2Cl2]
(IV) [Pt(NH3)2Cl2]
Identify the CORRECT statement about the following complex of platinum.
[PtCl2(en)2]2+
The number of geometrical isomers of [CrCl2(en)2]+ is ____________.
Consider the two complexes given below:
\[\ce{\underset{(I)}{[Co(NH3)5SO4]Br}}\] and \[\ce{\underset{(II)}{[Co(NH3)5Br]SO4}}\]
I and II are ____________ isomers.
Which of the following does NOT show optical isomerism?
The complex ions [Co(H2O)5(ONO)]2+ and [Co(H2O)5NO2]2+ are ____________.
Which of the following has zero dipole moment?
What is the number of moles of silver chloride precipitated when excess of aqueous silver nitrate is treated with [Co(NH3)4Cl2]Cl?
What type of isomerism is present between (I) [Cr(H2O)6]Cl3 and (II) [Cr(H2O)5Cl]Cl2.H2O?
\[\ce{IUPAC}\] name of \[\ce{[Pt(NH3)2 Cl(NO2)]}\] is ______.
The correct structure of Fe(CO)5 is
Complex [COCl2(en)2]+ can
Which of the following has an optical isomer?
Which of the following shows maximum number of isomers?
Write the name of isomerism in the following complexes:
[Cu(NH3)4] [PtCl4] and [Pt(NH3)4] [ CuCl4]
The number of geometrical isomers of \[\ce{[Co(NH3)3 (NO3)3]}\] are ______.
White precipitate of AgCl dissolves in aqueous ammonia solution due to formation of ______.
Which among the following solid is a non-polar solid?
The compounds [PtCl2(NH3)4]Br2 and [PtBr2(NH3)4]Cl2 constitutes a pair of ______.
Name the type of isomerism exhibited by the following pair of compounds:
[Co(NH3)5(ONO)]Cl2 and [Co(NH3)5(NO2)]Cl2
Three organic compounds A, B and C are non cyclic functional isomers of carbonyl compounds with molecular formula C4H8O. Isomers A and C give positive Tollen’s test while compound B does not give positive Tollen’s test but gives positive iodoform test. Compounds A and B on reduction with Zn amalgam and conc. HCl give the same product.
- Write the structures of the compounds A, B and C.
- Out of the compounds A, B and C, which one will be the least reactive towards addition of HCN.
