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Define the term Co-ordination isomer. - Chemistry

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प्रश्न

Define the term Co-ordination isomer.

परिभाषा
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उत्तर

Isomers which show interchange of ligands between cationic and anionic spheres of different metal ions are called co-ordination isomers.

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अध्याय 9: Coordination Compounds - Short Answer Questions (Type-Ⅰ)

APPEARS IN

एससीईआरटी महाराष्ट्र Chemistry [English] 12 Standard HSC
अध्याय 9 Coordination Compounds
Short Answer Questions (Type-Ⅰ) | Q 5.1
एससीईआरटी महाराष्ट्र Chemistry [English] 12 Standard HSC
अध्याय 9 Coordination Compounds
Short Answer Questions (Type-II) | Q 2.1

संबंधित प्रश्न

Give one chemical test as an evidence to show that [Co (NH3)5Cl]  are ionisation isomers. 


Answer the following in one or two sentences.

Consider the complexes \[\ce{[Cu(NH3)4][PtCl4] and [Pt(NH3)4] [CuCl4]}\]. What type of isomerism these two complexes exhibit?


The pair [Co(NH3)5(SO4)]Br and [Co(NH3)5Br]SO4 exhibits ____________ isomerism


Draw structure of cis isomer of [Co(NH3)4Cl2]+


Draw the geometrical isomers of the following complexes [Pt(NH3)(H2O)Cl2].


Draw optical isomers of [Co(en)3]3+.


Draw all possible geometrical isomers of the complex \[\ce{[Co(en)2Cl2]^+}\] and identify the optically active isomer.


The number of geometrical isomers of [CrCl2(en)2]+ is ____________.


Consider the two complexes given below:

\[\ce{\underset{(I)}{[Co(NH3)5SO4]Br}}\] and \[\ce{\underset{(II)}{[Co(NH3)5Br]SO4}}\]

I and II are ____________ isomers.


Indicate the complex ion which shows geometrical isomerism.


\[\ce{IUPAC}\] name of \[\ce{[Pt(NH3)2 Cl(NO2)]}\] is ______.


Assertion: Complexes of MX6 and MX5L type (X and L are unidentate) do not show geometrical isomerism.

Reason: Geometrical isomerism is not shown by complexes of coordination number 6.


Geometrical isomerism is not shown by


\[\ce{CH3CH2COO- Na+ ->[NaOH, + ?][Heat] CH3CH3 + Na2CO3}\]

Consider the above reaction and identify the missing reagent/chemical.


Write the name of isomerism in the following complexes:

[Cu(NH3)4] [PtCl4] and [Pt(NH3)4] [ CuCl4]


Draw geometric isomers of the following complex.

Geometrical isomers of Pt(NH3)2Cl2


Which of the following are isostructural pairs?

(A) \[\ce{SO^{2-}4}\] and \[\ce{CrO^{2-}4}\]

(B) SiCl4 and TiCl4

(C) NH3 and \[\ce{NO^-3}\]

(D) BCl3 and BrCl3


Which compound would exhibit optical isomers?


The number of geometrical isomers of \[\ce{[Co(NH3)3 (NO3)3]}\] are ______.


White precipitate of AgCl dissolves in aqueous ammonia solution due to formation of ______.


The compounds [PtCl2(NH3)4]Br2 and [PtBr2(NH3)4]Cl2 constitutes a pair of ______.


Define Distereoisomers.


Indicate the type of isomerism exhibited by the following complex and draw the structures for this isomer:

\[\ce{[Pt(NH3)(H2O)Cl2]}\]


What are structural isomers?


Draw the structure of trans isomers of Pt(NH3)2Cl2.


The co-ordination number of Co3+ ion in the complex [Co(NH3)4Cl2] is ______.


Name the type of isomerism exhibited by the following pair of compounds:

[Co(NH3)5(ONO)]Cl2 and [Co(NH3)5(NO2)]Cl2


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