Advertisements
Advertisements
प्रश्न
Define the term Co-ordination isomer.
Advertisements
उत्तर
Isomers which show interchange of ligands between cationic and anionic spheres of different metal ions are called co-ordination isomers.
संबंधित प्रश्न
Write the structural formula and IUPAC names of all possible isomers of the compound with molecular formula C3H8O.
Out of 
and 
, which one is optically active and why ?
Choose the most correct option.
Which of the following complexes exist as cis and trans isomers?
1. [Cr(NH3)2Cl4]-
2. [Co(NH3)5Br]2⊕
3. [PtCl2Br2]2- (square planar)
4. [FeCl2(NCS)2]2- (tetrahedral)
Answer the following in one or two sentences.
Consider the complexes \[\ce{[Cu(NH3)4][PtCl4] and [Pt(NH3)4] [CuCl4]}\]. What type of isomerism these two complexes exhibit?
The pair [Co(NH3)5(SO4)]Br and [Co(NH3)5Br]SO4 exhibits ____________ isomerism
Draw structure of cis isomer of [Co(NH3)4Cl2]+
Draw the geometrical isomers of the following complexes [Pt(NH3)(H2O)Cl2].
Which one of the following will give a pair of enantiomorphs?
How many geometrical isomers are possible for \[\ce{[Pt(Py)(NH3)(Br)(Cl)]}\]?
Draw all possible geometrical isomers of the complex \[\ce{[Co(en)2Cl2]^+}\] and identify the optically active isomer.
The compound(s) that exhibit(s) geometrical isomerism is (are):
(I) [Pt(en)Cl2]
(II) [Pt(en)2]Cl2
(III) [Pt(en)2Cl2]
(IV) [Pt(NH3)2Cl2]
The number of geometrical isomers of [CrCl2(en)2]+ is ____________.
The formula of two complexes X and Y of chromium are given below:
\[\ce{\underset{(X)}{[Cr(H2O)6]Cl3}}\] and \[\ce{\underset{(Y)}{[Cr(H2O)5Cl]Cl2.H2O}}\]
X and Y are examples of ____________ isomers.
\[\ce{IUPAC}\] name of \[\ce{[Pt(NH3)2 Cl(NO2)]}\] is ______.
Complex [COCl2(en)2]+ can
Write the name of isomerism in the following complexes:
[Cu(NH3)4] [PtCl4] and [Pt(NH3)4] [ CuCl4]
Which of the following compound is optically active?
Which compound would exhibit optical isomers?
The number of geometrical isomers of \[\ce{[Co(NH3)3 (NO3)3]}\] are ______.
Indicate the type of isomerism exhibited by the following complex and draw the structures for this isomer:
\[\ce{[Pt(NH3)(H2O)Cl2]}\]
Write structures for geometrical isomers of diamminebromochloroplatinum (II).
Explain the geometrical isomerism of the octahedral complex of the type [M(AA)2B2]n± with a suitable example.
What are structural isomers?
Match the pairs in column I (pairs of isomers) and column II (types of isomers)
| Column I (Pairs of isomers) |
Column II (Types of isomers) |
| (A) [Cr(H2O)5Cl]Cl2.H2O and [Cr(H2O)4Cl2]Cl.2H2O | (i) Ionization isomers |
| (B) [Co(en)2(NO2)2]+ and [Co(en)2(ONO2)]+ | (ii) Hydrate isomers |
| (C) [Co(NH3)6] [Cr(CN)6] and [Cr(NH3)6] [Co(CN)6] | (iii) Linkage isomers |
| (D) [Pt(NH3)4Cl2] Br2 and [Pt(NH3)4Br2]Cl2 | (iv) Coordination isomers |
Draw the geometrical isomers of the following complexes [Co(NH3)4Cl2]+
Draw the structure of trans isomers of Pt(NH3)2Cl2.
The co-ordination number of Co3+ ion in the complex [Co(NH3)4Cl2]⊕ is ______.
Three organic compounds A, B and C are non cyclic functional isomers of carbonyl compounds with molecular formula C4H8O. Isomers A and C give positive Tollen’s test while compound B does not give positive Tollen’s test but gives positive iodoform test. Compounds A and B on reduction with Zn amalgam and conc. HCl give the same product.
- Write the structures of the compounds A, B and C.
- Out of the compounds A, B and C, which one will be the least reactive towards addition of HCN.
