हिंदी

Write the name of isomerism in the following complexes: [Cu(NH3)4] [PtCl4] and [Pt(NH3)4] [ CuCl4]

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प्रश्न

Write the name of isomerism in the following complexes:

[Cu(NH3)4] [PtCl4] and [Pt(NH3)4] [ CuCl4]

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उत्तर

Both complexes exhibit coordination isomerism due to ligand exchange between cationic and anionic entities of distinct metal ions present in the complex.

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2021-2022 (March) Set 1

संबंधित प्रश्न

List various types of isomerism possible for coordination compounds, giving an example of each.


Give one chemical test as an evidence to show that [Co (NH3)5Cl]  are ionisation isomers. 


Answer the following in one or two sentences.

Predict whether the [Cr(en)2(H2O)2]3+ complex is chiral. Write the structure of its enantiomer.


Answer the following question.

Draw isomers of the following

Ru(NH3)4Cl2


Answer the following question.

Draw isomers of the following

[Cr(en2)Br2]⊕


Answer the following question.

Draw geometric isomers and enantiomers of the following complex.

[Pt(en)3]4⊕


The pair [Co(NH3)5(SO4)]Br and [Co(NH3)5Br]SO4 exhibits ____________ isomerism


Draw structure of cis isomer of [Co(NH3)4Cl2]+


Fac-mer isomerism is shown by


What is linkage isomerism? Explain with an example.


The term anomers of glucose refer to ____________.


The number of geometrical isomers of [CrCl2(en)2]+ is ____________.


Consider the two complexes given below:

\[\ce{\underset{(I)}{[Co(NH3)5SO4]Br}}\] and \[\ce{\underset{(II)}{[Co(NH3)5Br]SO4}}\]

I and II are ____________ isomers.


____________ isomers are formed when the ligand has two different donor atoms.


The formula of two complexes X and Y of chromium are given below:

\[\ce{\underset{(X)}{[Cr(H2O)6]Cl3}}\] and \[\ce{\underset{(Y)}{[Cr(H2O)5Cl]Cl2.H2O}}\]

X and Y are examples of ____________ isomers.


Which of the following has zero dipole moment?


What is the number of moles of silver chloride precipitated when excess of aqueous silver nitrate is treated with [Co(NH3)4Cl2]Cl?


Which of the following does not show optical isomerism?


Which of the following compounds show optical isomerism?


Which of the following compound is optically active?


Define Distereoisomers.


Give trans isomer of [Co(NH3)4Cl2]⊕.


Indicate the type of isomerism exhibited by the following complex and draw the structures for this isomer:

\[\ce{[Pt(NH3)(H2O)Cl2]}\]


The co-ordination number of Co3+ ion in the complex [Co(NH3)4Cl2]⊕ is ______.


Three organic compounds A, B and C are non cyclic functional isomers of carbonyl compounds with molecular formula C4H8O. Isomers A and C give positive Tollen’s test while compound B does not give positive Tollen’s test but gives positive iodoform test. Compounds A and B on reduction with Zn amalgam and conc. HCl give the same product.

  1. Write the structures of the compounds A, B and C.
  2. Out of the compounds A, B and C, which one will be the least reactive towards addition of HCN.

Match List-I with List-II:

List-I
(Complex)
List-II
(Type of isomerism)
A. [Co(NH3)5(NO2)]Cl2 I. Solvate isomerism
B. [Co(NH3)5(SO4)]Br II. Linkage isomerism
C. [Co(NH3)6][Cr(CN)6] III. Ionisation isomerism
D. [Co(H2O)6]Cl3 IV. Coordination isomerism

Choose the correct answer from the options given below:


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