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प्रश्न
Answer in brief.
What are ionization isomers ? Give an example.
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उत्तर
Isomers that involve the exchange of ligands between coordination and ionization spheres are called ionization isomers.
e.g. [Co(NH3)5SO4]Br and [Co(NH3)5Br]SO4
संबंधित प्रश्न
Answer the following in one or two sentences.
Consider the complexes \[\ce{[Cu(NH3)4][PtCl4] and [Pt(NH3)4] [CuCl4]}\]. What type of isomerism these two complexes exhibit?
The pair [Co(NH3)5(SO4)]Br and [Co(NH3)5Br]SO4 exhibits ____________ isomerism
Define the term Co-ordination isomer.
Draw the geometrical isomers of the following complexes [Pt(NH3)(H2O)Cl2].
Which one of the following will give a pair of enantiomorphs?
Which one of the following pairs represents linkage isomers?
Fac-mer isomerism is shown by
Identify the CORRECT statement about the following complex of platinum.
[PtCl2(en)2]2+
Consider the two complexes given below:
\[\ce{\underset{(I)}{[Co(NH3)5SO4]Br}}\] and \[\ce{\underset{(II)}{[Co(NH3)5Br]SO4}}\]
I and II are ____________ isomers.
Which of the following does NOT show optical isomerism?
\[\ce{IUPAC}\] name of \[\ce{[Pt(NH3)2 Cl(NO2)]}\] is ______.
Which of the following does not show optical isomerism?
Which of the following has an optical isomer?
Draw geometric isomers of the following complex.
Geometrical isomers of Pt(NH3)2Cl2
White precipitate of AgCl dissolves in aqueous ammonia solution due to formation of ______.
Which among the following solid is a non-polar solid?
The compounds [PtCl2(NH3)4]Br2 and [PtBr2(NH3)4]Cl2 constitutes a pair of ______.
Define Distereoisomers.
Give cis isomer of [Co(NH3)4Cl2]⊕.
Give trans isomer of [Co(NH3)4Cl2]⊕.
Indicate the type of isomerism exhibited by the following complex and draw the structures for this isomer:
\[\ce{[Pt(NH3)(H2O)Cl2]}\]
What are structural isomers?
Draw the geometrical isomers of the following complexes [Co(NH3)4Cl2]+
Draw the structure of cis isomers of Pt(NH3)2Cl2.
The co-ordination number of Co3+ ion in the complex [Co(NH3)4Cl2]⊕ is ______.
Name the type of isomerism exhibited by the following pair of compounds:
[Co(NH3)5(ONO)]Cl2 and [Co(NH3)5(NO2)]Cl2
Give a chemical test to show that \[\ce{[Co(NH3)5Cl]SO4}\] and \[\ce{[Co(NH3)5SO4]CI}\] are ionisation isomers.
Three organic compounds A, B and C are non cyclic functional isomers of carbonyl compounds with molecular formula C4H8O. Isomers A and C give positive Tollen’s test while compound B does not give positive Tollen’s test but gives positive iodoform test. Compounds A and B on reduction with Zn amalgam and conc. HCl give the same product.
- Write the structures of the compounds A, B and C.
- Out of the compounds A, B and C, which one will be the least reactive towards addition of HCN.
