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प्रश्न
Answer in brief.
What are ionization isomers ? Give an example.
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उत्तर
Isomers that involve the exchange of ligands between coordination and ionization spheres are called ionization isomers.
e.g. [Co(NH3)5SO4]Br and [Co(NH3)5Br]SO4
संबंधित प्रश्न
Write the structural formula and IUPAC names of all possible isomers of the compound with molecular formula C3H8O.
Out of 
and 
, which one is optically active and why ?
Why dextro and laevo rotatory isomers of Butan-2-ol are difficult to separate by fractional distillation?
Choose the most correct option.
Which of the following complexes exist as cis and trans isomers?
1. [Cr(NH3)2Cl4]-
2. [Co(NH3)5Br]2⊕
3. [PtCl2Br2]2- (square planar)
4. [FeCl2(NCS)2]2- (tetrahedral)
Answer the following in one or two sentences.
Predict whether the [Cr(en)2(H2O)2]3+ complex is chiral. Write the structure of its enantiomer.
Answer the following in one or two sentences.
Consider the complexes \[\ce{[Cu(NH3)4][PtCl4] and [Pt(NH3)4] [CuCl4]}\]. What type of isomerism these two complexes exhibit?
Draw isomers of the following.
\[\ce{Pt(NH3)2ClNO2}\]
How many geometrical isomers are possible for \[\ce{[Pt(Py)(NH3)(Br)(Cl)]}\]?
Which one of the following pairs represents linkage isomers?
Which kind of isomerism is possible for a complex [Co(NH3)4Br2]Cl?
Which one of the following complexes is not expected to exhibit isomerism?
The term anomers of glucose refer to ____________.
Identify the CORRECT statement about the following complex of platinum.
[PtCl2(en)2]2+
The number of geometrical isomers of [CrCl2(en)2]+ is ____________.
What is the number of moles of silver chloride precipitated when excess of aqueous silver nitrate is treated with [Co(NH3)4Cl2]Cl?
What type of isomerism is present between (I) [Cr(H2O)6]Cl3 and (II) [Cr(H2O)5Cl]Cl2.H2O?
Indicate the complex ion which shows geometrical isomerism.
Which of the following compounds show optical isomerism?
Which of the following shows maximum number of isomers?
\[\ce{CH3CH2COO- Na+ ->[NaOH, + ?][Heat] CH3CH3 + Na2CO3}\]
Consider the above reaction and identify the missing reagent/chemical.
Draw geometric isomers of the following complex.
Geometrical isomers of Pt(NH3)2Cl2
Indicate the types of isomerism exhibited by the following complexes and draw the structures for these isomers: [Pt(NH3)(H2O)Cl2]
Write structures for geometrical isomers of diamminebromochloroplatinum (II).
What are structural isomers?
Match the pairs in column I (pairs of isomers) and column II (types of isomers)
| Column I (Pairs of isomers) |
Column II (Types of isomers) |
| (A) [Cr(H2O)5Cl]Cl2.H2O and [Cr(H2O)4Cl2]Cl.2H2O | (i) Ionization isomers |
| (B) [Co(en)2(NO2)2]+ and [Co(en)2(ONO2)]+ | (ii) Hydrate isomers |
| (C) [Co(NH3)6] [Cr(CN)6] and [Cr(NH3)6] [Co(CN)6] | (iii) Linkage isomers |
| (D) [Pt(NH3)4Cl2] Br2 and [Pt(NH3)4Br2]Cl2 | (iv) Coordination isomers |
Draw the structure of trans isomers of Pt(NH3)2Cl2.
Name the type of isomerism exhibited by the following pair of compound:
\[\ce{[Pt(NH3)4Cl2]Br2 and [Pt(NH3)4 Br2]Cl2}\]
Which one of the following complex ions has geometrical isomers?
