हिंदी

Choose the most correct option. Which of the following complexes exist as cis and trans isomers? 1. [Cr(NH3)2Cl4]- 2. [Co(NH3)5Br]2⊕ 3. [PtCl2Br2]2- (square planar) 4. [FeCl2(NCS)2]2- (tetrahedral)

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प्रश्न

Choose the most correct option.

Which of the following complexes exist as cis and trans isomers?

1. [Cr(NH3)2Cl4]-

2. [Co(NH3)5Br]2⊕

3. [PtCl2Br2]2- (square planar)

4. [FeCl2(NCS)2]2- (tetrahedral)

विकल्प

  • 1 and 3

  • 2 and 3

  • 1 and 3

  • 4 only

MCQ
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उत्तर

1 and 3

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अध्याय 9: Coordination Compounds - Exercises [पृष्ठ २०७]

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बालभारती Chemistry [English] Standard 12 Maharashtra State Board
अध्याय 9 Coordination Compounds
Exercises | Q 1.4 | पृष्ठ २०७

संबंधित प्रश्न

Answer the following in one or two sentences.

Predict whether the [Cr(en)2(H2O)2]3+ complex is chiral. Write the structure of its enantiomer.


Answer the following in one or two sentences.

Consider the complexes \[\ce{[Cu(NH3)4][PtCl4] and [Pt(NH3)4] [CuCl4]}\]. What type of isomerism these two complexes exhibit?


Answer in brief.

What are ionization isomers ? Give an example.


Answer the following question.

Draw isomers of the following

[Cr(en2)Br2]


Draw structure of cis isomer of [Co(NH3)4Cl2]+


Which one of the following complexes is not expected to exhibit isomerism?


The term anomers of glucose refer to ____________.


Identify the CORRECT statement about the following complex of platinum.

[PtCl2(en)2]2+


The number of geometrical isomers of [CrCl2(en)2]+ is ____________.


Which of the following does NOT show optical isomerism?


The formula of two complexes X and Y of chromium are given below:

\[\ce{\underset{(X)}{[Cr(H2O)6]Cl3}}\] and \[\ce{\underset{(Y)}{[Cr(H2O)5Cl]Cl2.H2O}}\]

X and Y are examples of ____________ isomers.


\[\ce{IUPAC}\] name of \[\ce{[Pt(NH3)2 Cl(NO2)]}\] is ______.


Assertion: Complexes of MX6 and MX5L type (X and L are unidentate) do not show geometrical isomerism.

Reason: Geometrical isomerism is not shown by complexes of coordination number 6.


Geometrical isomerism is not shown by


Complex [COCl2(en)2]+ can 


Which compound would exhibit optical isomers?


White precipitate of AgCl dissolves in aqueous ammonia solution due to formation of ______.


The one that is not expected to show isomerism is ______.


Which among the following solid is a non-polar solid?


The compounds [PtCl2(NH3)4]Br2 and [PtBr2(NH3)4]Cl2 constitutes a pair of ______.


Define Distereoisomers.


Give trans isomer of [Co(NH3)4Cl2].


Indicate the types of isomerism exhibited by the following complexes and draw the structures for these isomers: [Pt(NH3)(H2O)Cl2]


Draw the geometrical isomers of the following complexes [Co(NH3)4Cl2]+


Draw the structure of cis isomers of Pt(NH3)2Cl2.


Name the type of isomerism exhibited by the following pair of compounds:

[Cr(H2O)5Cl]Cl2.H2O and [Cr(H2O)4Cl2]Cl.2H2O


Which one of the following complex ions has geometrical isomers?


Three organic compounds A, B and C are non cyclic functional isomers of carbonyl compounds with molecular formula C4H8O. Isomers A and C give positive Tollen’s test while compound B does not give positive Tollen’s test but gives positive iodoform test. Compounds A and B on reduction with Zn amalgam and conc. HCl give the same product.

  1. Write the structures of the compounds A, B and C.
  2. Out of the compounds A, B and C, which one will be the least reactive towards addition of HCN.

Match List-I with List-II:

List-I
(Complex)
List-II
(Type of isomerism)
A. [Co(NH3)5(NO2)]Cl2 I. Solvate isomerism
B. [Co(NH3)5(SO4)]Br II. Linkage isomerism
C. [Co(NH3)6][Cr(CN)6] III. Ionisation isomerism
D. [Co(H2O)6]Cl3 IV. Coordination isomerism

Choose the correct answer from the options given below:


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