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प्रश्न
What is linkage isomerism? Explain with an example.
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उत्तर
Linkage isomers
Linkage isomerism arises when an ambidentate ligand is bonded to the central metal atom/ion through either of its two different donor atoms.
e.g. - [Co(NH3)5NO2]2+ Pentaammine nitrito-κN Cobalt (III) ion – N attached
[Co(NH3)5ONO2]2+ Pentaammine nitrito-κO Cobalt (III) ion – O attached
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संबंधित प्रश्न
Answer the following in one or two sentences.
Predict whether the [Cr(en)2(H2O)2]3+ complex is chiral. Write the structure of its enantiomer.
Draw optical isomers of [Co(en)3]3+.
The complex ions [Co(H2O)5(ONO)]2+ and [Co(H2O)5NO2]2+ are ____________.
The relationship between compound (i) and (ii) is
 |
 |
| (i) | (ii) |
Complex [COCl2(en)2]+ can
Write the name of isomerism in the following complexes:
[Cu(NH3)4] [PtCl4] and [Pt(NH3)4] [ CuCl4]
Which among the following solid is a non-polar solid?
Indicate the type of isomerism exhibited by the following complex and draw the structures for this isomer:
\[\ce{[Pt(NH3)(H2O)Cl2]}\]
Name the type of isomerism exhibited by the following pair of compounds:
[Co(NH3)5(ONO)]Cl2 and [Co(NH3)5(NO2)]Cl2
Match List-I with List-II:
| List-I (Complex) |
List-II (Type of isomerism) |
| A. [Co(NH3)5(NO2)]Cl2 | I. Solvate isomerism |
| B. [Co(NH3)5(SO4)]Br | II. Linkage isomerism |
| C. [Co(NH3)6][Cr(CN)6] | III. Ionisation isomerism |
| D. [Co(H2O)6]Cl3 | IV. Coordination isomerism |
Choose the correct answer from the options given below:
