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प्रश्न
What is linkage isomerism? Explain with an example.
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उत्तर
Linkage isomers
Linkage isomerism arises when an ambidentate ligand is bonded to the central metal atom/ion through either of its two different donor atoms.
e.g. - [Co(NH3)5NO2]2+ Pentaammine nitrito-κN Cobalt (III) ion – N attached
[Co(NH3)5ONO2]2+ Pentaammine nitrito-κO Cobalt (III) ion – O attached
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संबंधित प्रश्न
List various types of isomerism possible for coordination compounds, giving an example of each.
Answer the following question.
Draw isomers of the following
Ru(NH3)4Cl2
Which type of isomerism is exhibited by [Pt(NH3)2Cl2]?
The compound(s) that exhibit(s) geometrical isomerism is (are):
(I) [Pt(en)Cl2]
(II) [Pt(en)2]Cl2
(III) [Pt(en)2Cl2]
(IV) [Pt(NH3)2Cl2]
The number of geometrical isomers of [CrCl2(en)2]+ is ____________.
The relationship between compound (i) and (ii) is
 |
 |
| (i) | (ii) |
Which of the following compounds show optical isomerism?
Write the name of isomerism in the following complexes:
[Cu(NH3)4] [PtCl4] and [Pt(NH3)4] [ CuCl4]
Which of the following are isostructural pairs?
(A) \[\ce{SO^{2-}4}\] and \[\ce{CrO^{2-}4}\]
(B) SiCl4 and TiCl4
(C) NH3 and \[\ce{NO^-3}\]
(D) BCl3 and BrCl3
Indicate the types of isomerism exhibited by the following complexes and draw the structures for these isomers: [Pt(NH3)(H2O)Cl2]
