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प्रश्न
What is linkage isomerism? Explain with an example.
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उत्तर
Linkage isomers
Linkage isomerism arises when an ambidentate ligand is bonded to the central metal atom/ion through either of its two different donor atoms.
e.g. - [Co(NH3)5NO2]2+ Pentaammine nitrito-κN Cobalt (III) ion – N attached
[Co(NH3)5ONO2]2+ Pentaammine nitrito-κO Cobalt (III) ion – O attached
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संबंधित प्रश्न
Answer in brief.
What are ionization isomers ? Give an example.
Which one of the following complexes is not expected to exhibit isomerism?
The formula of two complexes X and Y of chromium are given below:
\[\ce{\underset{(X)}{[Cr(H2O)6]Cl3}}\] and \[\ce{\underset{(Y)}{[Cr(H2O)5Cl]Cl2.H2O}}\]
X and Y are examples of ____________ isomers.
Which of the following shows maximum number of isomers?
\[\ce{CH3CH2COO- Na+ ->[NaOH, + ?][Heat] CH3CH3 + Na2CO3}\]
Consider the above reaction and identify the missing reagent/chemical.
Write the name of isomerism in the following complexes:
[Cu(NH3)4] [PtCl4] and [Pt(NH3)4] [ CuCl4]
Give cis isomer of [Co(NH3)4Cl2]⊕.
Give trans isomer of [Co(NH3)4Cl2]⊕.
Draw the structure of trans isomers of Pt(NH3)2Cl2.
Name the type of isomerism exhibited by the following pair of compounds:
[Co(NH3)5(ONO)]Cl2 and [Co(NH3)5(NO2)]Cl2
