Advertisements
Advertisements
प्रश्न
What is linkage isomerism? Explain with an example.
Advertisements
उत्तर
Linkage isomers
Linkage isomerism arises when an ambidentate ligand is bonded to the central metal atom/ion through either of its two different donor atoms.
e.g. - [Co(NH3)5NO2]2+ Pentaammine nitrito-κN Cobalt (III) ion – N attached
[Co(NH3)5ONO2]2+ Pentaammine nitrito-κO Cobalt (III) ion – O attached
APPEARS IN
संबंधित प्रश्न
List various types of isomerism possible for coordination compounds, giving an example of each.
Choose the most correct option.
Which of the following complexes exist as cis and trans isomers?
1. [Cr(NH3)2Cl4]-
2. [Co(NH3)5Br]2⊕
3. [PtCl2Br2]2- (square planar)
4. [FeCl2(NCS)2]2- (tetrahedral)
Answer the following question.
Draw geometric isomers and enantiomers of the following complex.
[Pt(en)3]4⊕
Write the type of isomerism exhibited by [Co(NH3)5(NO2)]2+ and [Co(NH3)5ONO]2+ pair of complex ion.
Which type of isomerism is exhibited by [Pt(NH3)2Cl2]?
How many geometrical isomers are possible for \[\ce{[Pt(Py)(NH3)(Br)(Cl)]}\]?
The complex ions [Co(H2O)5(ONO)]2+ and [Co(H2O)5NO2]2+ are ____________.
The formula of two complexes X and Y of chromium are given below:
\[\ce{\underset{(X)}{[Cr(H2O)6]Cl3}}\] and \[\ce{\underset{(Y)}{[Cr(H2O)5Cl]Cl2.H2O}}\]
X and Y are examples of ____________ isomers.
Complex [COCl2(en)2]+ can
Name the type of isomerism exhibited by the following pair of compounds:
[Co(NH3)5(ONO)]Cl2 and [Co(NH3)5(NO2)]Cl2
