Advertisements
Advertisements
प्रश्न
\[\ce{IUPAC}\] name of \[\ce{[Pt(NH3)2 Cl(NO2)]}\] is ______.
विकल्प
Platinum diaminechloronitrite
Chloronitrito-N-ammineplatinum (II)
Diamminechloridonitrito-N-platinum (II)
Diamminechloronitrito-N-platinate (II)
Advertisements
उत्तर
\[\ce{IUPAC}\] name of \[\ce{[Pt(NH3)2 Cl(NO2)]}\] is diamminechloridonitrito-N-platinum (II).
Explanation:
In this case both the central atom as well as ligands are present in the coordination sphere. The ligands are named first in alphabetical order before the name of central atom or ion. Names of the anionic ligands end with suffix '- o'. The name of the central metal atom is written at the end along with its oxidation state in Roman numeral, which is (II) for the central metal atom "platinum". Note the "chloride" is preferred term/ name over chloro for chloride ion as a ligand as per modern trend.
APPEARS IN
संबंधित प्रश्न
List various types of isomerism possible for coordination compounds, giving an example of each.
Out of
and
, which one is optically active and why ?
Why dextro and laevo rotatory isomers of Butan-2-ol are difficult to separate by fractional distillation?
Choose the most correct option.
Which of the following complexes exist as cis and trans isomers?
1. [Cr(NH3)2Cl4]-
2. [Co(NH3)5Br]2⊕
3. [PtCl2Br2]2- (square planar)
4. [FeCl2(NCS)2]2- (tetrahedral)
Answer the following question.
Draw isomers of the following
Ru(NH3)4Cl2
Which one of the following pairs represents linkage isomers?
What are hydrate isomers? Explain with an example.
Identify the CORRECT statement about the following complex of platinum.
[PtCl2(en)2]2+
Geometrical isomerism is not shown by
Which of the following does not show optical isomerism?
Complex [COCl2(en)2]+ can
The one that is not expected to show isomerism is ______.
Give cis isomer of [Co(NH3)4Cl2]⊕.
Give trans isomer of [Co(NH3)4Cl2]⊕.
Draw the structure of trans isomers of Pt(NH3)2Cl2.
Which one of the following complex ions has geometrical isomers?
Three organic compounds A, B and C are non cyclic functional isomers of carbonyl compounds with molecular formula C4H8O. Isomers A and C give positive Tollen’s test while compound B does not give positive Tollen’s test but gives positive iodoform test. Compounds A and B on reduction with Zn amalgam and conc. HCl give the same product.
- Write the structures of the compounds A, B and C.
- Out of the compounds A, B and C, which one will be the least reactive towards addition of HCN.
Match List-I with List-II:
| List-I (Complex) |
List-II (Type of isomerism) |
| A. [Co(NH3)5(NO2)]Cl2 | I. Solvate isomerism |
| B. [Co(NH3)5(SO4)]Br | II. Linkage isomerism |
| C. [Co(NH3)6][Cr(CN)6] | III. Ionisation isomerism |
| D. [Co(H2O)6]Cl3 | IV. Coordination isomerism |
Choose the correct answer from the options given below:
