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कर्नाटक बोर्ड पी.यू.सी.पीयूसी विज्ञान 2nd PUC Class 12

IUPAC name of [Pt(NHX3)X2 Cl(NOX2)] is ______. - Chemistry

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प्रश्न

\[\ce{IUPAC}\] name of \[\ce{[Pt(NH3)2 Cl(NO2)]}\] is ______.

पर्याय

  • Platinum diaminechloronitrite

  • Chloronitrito-N-ammineplatinum (II)

  • Diamminechloridonitrito-N-platinum (II)

  • Diamminechloronitrito-N-platinate (II)

MCQ
रिकाम्या जागा भरा
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उत्तर

\[\ce{IUPAC}\] name of \[\ce{[Pt(NH3)2 Cl(NO2)]}\] is diamminechloridonitrito-N-platinum (II).

Explanation:

In this case both the central atom as well as ligands are present in the coordination sphere. The ligands are named first in alphabetical order before the name of central atom or ion. Names of the anionic ligands end with suffix '- o'. The name of the central metal atom is written at the end along with its oxidation state in Roman numeral, which is (II) for the central metal atom "platinum". Note the "chloride" is preferred term/ name over chloro for chloride ion as a ligand as per modern trend. 

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पाठ 9: Coordination Compounds - Exercises [पृष्ठ १२२]

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एनसीईआरटी एक्झांप्लर Chemistry [English] Class 12
पाठ 9 Coordination Compounds
Exercises | Q I. 14. | पृष्ठ १२२

संबंधित प्रश्‍न

List various types of isomerism possible for coordination compounds, giving an example of each.


Why dextro and laevo rotatory isomers of Butan-2-ol are difficult to separate by fractional distillation?


Answer the following question.

Draw geometric isomers and enantiomers of the following complex.

[Pt(en)3]4⊕


Draw structure of cis isomer of [Co(NH3)4Cl2]+


Draw all possible geometrical isomers of the complex \[\ce{[Co(en)2Cl2]^+}\] and identify the optically active isomer.


Explain optical isomerism in coordination compounds with an example.


Which of the following is NOT a pair of structural isomers?


The complex ions [Co(H2O)5(ONO)]2+ and [Co(H2O)5NO2]2+ are ____________.


What is the number of moles of silver chloride precipitated when excess of aqueous silver nitrate is treated with [Co(NH3)4Cl2]Cl?


Complex [COCl2(en)2]+ can 


\[\ce{CH3CH2COO- Na+ ->[NaOH, + ?][Heat] CH3CH3 + Na2CO3}\]

Consider the above reaction and identify the missing reagent/chemical.


White precipitate of AgCl dissolves in aqueous ammonia solution due to formation of ______.


Which among the following solid is a non-polar solid?


Indicate the types of isomerism exhibited by the following complexes and draw the structures for these isomers: [Pt(NH3)(H2O)Cl2]


What are structural isomers?


Match the pairs in column I (pairs of isomers) and column II (types of isomers)

Column I
(Pairs of isomers)
Column II
(Types of isomers)
(A) [Cr(H2O)5Cl]Cl2.H2O and [Cr(H2O)4Cl2]Cl.2H2O (i) Ionization isomers
(B) [Co(en)2(NO2)2]+ and [Co(en)2(ONO2)]+ (ii) Hydrate isomers
(C) [Co(NH3)6] [Cr(CN)6] and [Cr(NH3)6] [Co(CN)6] (iii) Linkage isomers
(D) [Pt(NH3)4Cl2] Br2 and [Pt(NH3)4Br2]Cl2 (iv) Coordination isomers

Draw the structure of cis isomers of Pt(NH3)2Cl2.


Name the type of isomerism exhibited by the following pair of compounds:

[Co(NH3)5(ONO)]Cl2 and [Co(NH3)5(NO2)]Cl2


Name the type of isomerism exhibited by the following pair of compounds:

[Cr(H2O)5Cl]Cl2.H2O and [Cr(H2O)4Cl2]Cl.2H2O


Match List-I with List-II:

List-I
(Complex)
List-II
(Type of isomerism)
A. [Co(NH3)5(NO2)]Cl2 I. Solvate isomerism
B. [Co(NH3)5(SO4)]Br II. Linkage isomerism
C. [Co(NH3)6][Cr(CN)6] III. Ionisation isomerism
D. [Co(H2O)6]Cl3 IV. Coordination isomerism

Choose the correct answer from the options given below:


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