Advertisements
Advertisements
प्रश्न
What kind of isomerism exists between \[\ce{[Cr(H2O)6]Cl3}\] (violet) and \[\ce{[Cr(H2O)5Cl]Cl2 . H2O}\] (greyish-green)?
पर्याय
Linkage isomerism
Solvate isomerism
Ionisation isomerism
Coordination isomerism
Advertisements
उत्तर
Solvate isomerism
Explanation:
This form of isomerism is known as 'hydrate isomerism' in case where water is involved as a solvent. This is similar to ionisation isomerism. Solvate isomers differ by whether or not a solvent molecule is directly bonded to the metal ion or merely present as free solvent molecules in the crystal lattice.
APPEARS IN
संबंधित प्रश्न
The complex ion `[Co(H_2O)_5 (ONO)]^(2+) `
(A) linkage isomer
(B) ionisation isomer
(C) co-ordination isomer
(D) geometrical isomer
Give evidence that [Co(NH3)5Cl]SO4 and [Co(NH3)5SO4]Cl are ionization isomers.
What type of isomerism is shown by the complex [Co(en)3]Cl3
What type of isomerism is shown by the complex [Co(NH3)6] [Cr(CN)6]?
What type of isomerism is exhibited by the complex [Co(NH3)5Cl]SO4?
Write IUPAC name of the complex [Pt(en)2Cl2]. Draw structures of geometrical isomers for this complex.
Which of the following pair contains a complex salt and double salt respectively?
Which of the following isomer has the highest melting point?
Due to the presence of ambidentate ligands coordination compounds show isomerism. Palladium complexes of the type \[\ce{Pd(C6H5)2 (SCN)2]}\] and \[\ce{[Pd(C6H5)2 (NCS)2]}\] are ______.
Which of the following complexes show linkage isomerism?
(i) \[\ce{[Co(NH3)5 (NO2)]^{2+}}\]
(ii) \[\ce{Co(H2O)5 CO]^{3+}}\]
(iii) \[\ce{[Cr(NH3)5 SCN]^{2+}}\]
(iv) \[\ce{Fe(en)2 Cl2]^+}\]
Name the type of isomerism when ambidentate ligands are attached to central metal ion. Give two examples of ambidentate ligands.
Assertion: Linkage isomerism arises in coordination compounds containing ambidentate ligand.
Reason: Ambidentate ligand has two different donor atoms
A functional isomer of 1-butyne is
The complex [Co(NH3)5(NO2)]Cl2 is red in colour. Give IUPAC the name of its linkage isomer.
Indicate the types of isomerism exhibited by the following complexes and draw the structures for this isomer:
Pt(NH3)(H2O)Cl2
