मराठी
कर्नाटक बोर्ड पी.यू.सी.पीयूसी विज्ञान 2nd PUC Class 12

Assertion: Linkage isomerism arises in coordination compounds containing ambidentate ligand. Reason: Ambidentate ligand has two different donor atoms - Chemistry

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प्रश्न

Assertion: Linkage isomerism arises in coordination compounds containing ambidentate ligand.

Reason: Ambidentate ligand has two different donor atoms

पर्याय

  • Assertion and reason both are true, reason is correct explanation of assertion.

  • Assertion and reason both are true but reason is not the correct explanation of assertion.

  • Assertion is true, reason is false.

  • Assertion is false, reason is true.

MCQ
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उत्तर

Assertion and reason both are true, reason is correct explanation of assertion.

Explanation:

Linkage isomerism arises due to two different donor atoms in ambidentate ligand.

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पाठ 9: Coordination Compounds - Exercises [पृष्ठ १२७]

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एनसीईआरटी एक्झांप्लर Chemistry [English] Class 12
पाठ 9 Coordination Compounds
Exercises | Q V. 43. | पृष्ठ १२७

संबंधित प्रश्‍न

 

The complex ion `[Co(H_2O)_5 (ONO)]^(2+) `

(A) linkage isomer

(B) ionisation isomer

(C) co-ordination isomer

(D) geometrical isomer

 

Give evidence that [Co(NH3)5Cl]SO4 and [Co(NH3)5SO4]Cl are ionization isomers.


What type of isomerism is shown by the complex [Co(en)3]Cl3


What type of isomerism is shown by the complex [Co(NH3)5(SCN)]2+?


What type of isomerism is exhibited by the complex [Co(NH3)5Cl]SO4?


Write the IUPAC name of the complex [Cr(NH3)4Cl2]+. What type of isomerism does it exhibit?


Which of the following pair contains a complex salt and double salt respectively?


The compounds \[\ce{[CO(SO4)(NH3)5]Br}\] and \[\ce{[Co(SO4)(NH3)5]Cl}\] represent


Which of the following complexes show linkage isomerism?

(i) \[\ce{[Co(NH3)5 (NO2)]^{2+}}\]

(ii) \[\ce{Co(H2O)5 CO]^{3+}}\]

(iii) \[\ce{[Cr(NH3)5 SCN]^{2+}}\]

(iv) \[\ce{Fe(en)2 Cl2]^+}\]


Name the type of isomerism when ambidentate ligands are attached to central metal ion. Give two examples of ambidentate ligands.


CoSO4Cl.5NH3 exists in two isomeric forms ‘A’ and ‘B’. Isomer ‘A’ reacts with AgNO3 to give white precipitate, but does not react with BaCl2. Isomer ‘B’ gives white precipitate with BaCl2 but does not react with AgNO3. Answer the following questions.

  1. Identify ‘A’ and ‘B’ and write their structural formulas.
  2. Name the type of isomerism involved.
  3. Give the IUPAC name of ‘A’ and ‘B’.

A functional isomer of 1-butyne is


The diamagnetic species is:-


Which of the following compounds exhibits linkage isomerism?


Indicate the types of isomerism exhibited by the following complexes and draw the structures for this isomer:

Pt(NH3)(H2O)Cl2


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