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प्रश्न
Write the IUPAC name of the complex [Cr(NH3)4Cl2]+. What type of isomerism does it exhibit?
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उत्तर
The IUPAC name of the complex [Cr(NH3)4Cl2]+ is Tetraamminedichlorochromium(III) ion.
This complex exhibits geometrical isomerism. [Cr(NH3)4Cl2]+ is a [MA4B2] type of complex, in which the two chloride ligands may be oriented cis and trans to each other.
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संबंधित प्रश्न
The complex ion `[Co(H_2O)_5 (ONO)]^(2+) `
(A) linkage isomer
(B) ionisation isomer
(C) co-ordination isomer
(D) geometrical isomer
What type of isomerism is shown by the complex [Co(NH3)5(SCN)]2+?
What type of isomerism is exhibited by the complex [Co(NH3)5Cl]SO4?
Which of the following pair contains a complex salt and double salt respectively?
The compounds \[\ce{[CO(SO4)(NH3)5]Br}\] and \[\ce{[Co(SO4)(NH3)5]Cl}\] represent
Name the type of isomerism when ambidentate ligands are attached to central metal ion. Give two examples of ambidentate ligands.
Match the complex species given in Column I with the possible isomerism given in Column II and assign the correct code:
| Column I (Complex species) | Column II (Isomerism) |
| A. \[\ce{[Co(NH3)4 Cl2]^+}\] | 1. optical |
| B. \[\ce{cis-[Co(en)2 Cl2]^+}\] | 2. ionisation |
| C. \[\ce{[Co(NH3)5 (NO2)]Cl2}\] | 3. coordination |
| D. \[\ce{[Co(NH3)6][Cr(CN)6]}\] | 4. geometrical |
| 5. linkage |
Assertion: Linkage isomerism arises in coordination compounds containing ambidentate ligand.
Reason: Ambidentate ligand has two different donor atoms
Which of the following compounds exhibits linkage isomerism?
Which isomer of C5H10 gives a single monochloro compound C5H9Cl in bright sunlight?
