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प्रश्न
Give evidence that [Co(NH3)5Cl]SO4 and [Co(NH3)5SO4]Cl are ionisation isomers.
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उत्तर
Ionisation isomers dissolve in water to give different ions, hence giving different reactions with different reagents.
\[\ce{[Co(NH3)5Cl]SO4 + Ba^{2+} -> BaSO4_{(s)}}\]
\[\ce{[Co(NH3)5SO4]Cl + Ba^{2+} -> {No Reaction}}\]
\[\ce{[Co(NH3)5Cl]SO4 + Ag^+ -> {No Reaction}}\]
\[\ce{[Co(NH3)5SO4]Cl + Ag^+ -> AgCl_{(s)}}\]
Since the given complexes give different reactions with different reagents, they are ionisation isomers.
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संबंधित प्रश्न
What type of isomerism is shown by the complex [Co(en)3]Cl3
What type of isomerism is shown by the complex [Co(NH3)6] [Cr(CN)6]?
What type of isomerism is shown by the complex [Co(NH3)5(SCN)]2+?
Write the IUPAC name of the complex [Cr(NH3)4Cl2]+. What type of isomerism does it exhibit?
Which among the following is an ambidentate ligand?
Which of the following isomer has the highest melting point?
The compounds \[\ce{[CO(SO4)(NH3)5]Br}\] and \[\ce{[Co(SO4)(NH3)5]Cl}\] represent
What kind of isomerism exists between \[\ce{[Cr(H2O)6]Cl3}\] (violet) and \[\ce{[Cr(H2O)5Cl]Cl2 . H2O}\] (greyish-green)?
Which of the following complexes show linkage isomerism?
(i) \[\ce{[Co(NH3)5 (NO2)]^{2+}}\]
(ii) \[\ce{Co(H2O)5 CO]^{3+}}\]
(iii) \[\ce{[Cr(NH3)5 SCN]^{2+}}\]
(iv) \[\ce{Fe(en)2 Cl2]^+}\]
Assertion: Linkage isomerism arises in coordination compounds containing ambidentate ligand.
Reason: Ambidentate ligand has two different donor atoms
CoSO4Cl.5NH3 exists in two isomeric forms ‘A’ and ‘B’. Isomer ‘A’ reacts with AgNO3 to give white precipitate, but does not react with BaCl2. Isomer ‘B’ gives white precipitate with BaCl2 but does not react with AgNO3. Answer the following questions.
- Identify ‘A’ and ‘B’ and write their structural formulas.
- Name the type of isomerism involved.
- Give the IUPAC name of ‘A’ and ‘B’.
A functional isomer of 1-butyne is
The diamagnetic species is:-
Which isomer of C5H10 gives a single monochloro compound C5H9Cl in bright sunlight?
The complex [Co(NH3)5(NO2)]Cl2 is red in colour. Give IUPAC the name of its linkage isomer.
Indicate the types of isomerism exhibited by the following complexes and draw the structures for this isomer:
Pt(NH3)(H2O)Cl2
