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प्रश्न
The complex [Co(NH3)5(NO2)]Cl2 is red in colour. Give IUPAC the name of its linkage isomer.
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उत्तर
Linkage isomer of [Co(NH3)5(NO2)]Cl2 is [Co(NH3)5(ONO)] Pentaamine nitrito-O-cobalt(III).
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संबंधित प्रश्न
Write the IUPAC name of the complex [Cr(NH3)4Cl2]+. What type of isomerism does it exhibit?
Which among the following is an ambidentate ligand?
The compounds \[\ce{[CO(SO4)(NH3)5]Br}\] and \[\ce{[Co(SO4)(NH3)5]Cl}\] represent
What kind of isomerism exists between \[\ce{[Cr(H2O)6]Cl3}\] (violet) and \[\ce{[Cr(H2O)5Cl]Cl2 . H2O}\] (greyish-green)?
Name the type of isomerism when ambidentate ligands are attached to central metal ion. Give two examples of ambidentate ligands.
Assertion: Linkage isomerism arises in coordination compounds containing ambidentate ligand.
Reason: Ambidentate ligand has two different donor atoms
CoSO4Cl.5NH3 exists in two isomeric forms ‘A’ and ‘B’. Isomer ‘A’ reacts with AgNO3 to give white precipitate, but does not react with BaCl2. Isomer ‘B’ gives white precipitate with BaCl2 but does not react with AgNO3. Answer the following questions.
- Identify ‘A’ and ‘B’ and write their structural formulas.
- Name the type of isomerism involved.
- Give the IUPAC name of ‘A’ and ‘B’.
The diamagnetic species is:-
Which of the following compounds exhibits linkage isomerism?
Indicate the types of isomerism exhibited by the following complexes and draw the structures for this isomer:
Pt(NH3)(H2O)Cl2
