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प्रश्न
The complex [Co(NH3)5(NO2)]Cl2 is red in colour. Give IUPAC the name of its linkage isomer.
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उत्तर
Linkage isomer of [Co(NH3)5(NO2)]Cl2 is [Co(NH3)5(ONO)] Pentaamine nitrito-O-cobalt(III).
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संबंधित प्रश्न
The complex ion `[Co(H_2O)_5 (ONO)]^(2+) `
(A) linkage isomer
(B) ionisation isomer
(C) co-ordination isomer
(D) geometrical isomer
What type of isomerism is shown by the complex [Co(NH3)5(SCN)]2+?
What type of isomerism is exhibited by the complex [Co(NH3)5Cl]SO4?
Write the IUPAC name of the complex [Cr(NH3)4Cl2]+. What type of isomerism does it exhibit?
Write IUPAC name of the complex [Pt(en)2Cl2]. Draw structures of geometrical isomers for this complex.
Which among the following is an ambidentate ligand?
Which of the following complexes show linkage isomerism?
(i) \[\ce{[Co(NH3)5 (NO2)]^{2+}}\]
(ii) \[\ce{Co(H2O)5 CO]^{3+}}\]
(iii) \[\ce{[Cr(NH3)5 SCN]^{2+}}\]
(iv) \[\ce{Fe(en)2 Cl2]^+}\]
Match the complex species given in Column I with the possible isomerism given in Column II and assign the correct code:
| Column I (Complex species) | Column II (Isomerism) |
| A. \[\ce{[Co(NH3)4 Cl2]^+}\] | 1. optical |
| B. \[\ce{cis-[Co(en)2 Cl2]^+}\] | 2. ionisation |
| C. \[\ce{[Co(NH3)5 (NO2)]Cl2}\] | 3. coordination |
| D. \[\ce{[Co(NH3)6][Cr(CN)6]}\] | 4. geometrical |
| 5. linkage |
Which isomer of C5H10 gives a single monochloro compound C5H9Cl in bright sunlight?
Indicate the types of isomerism exhibited by the following complexes and draw the structures for this isomer:
Pt(NH3)(H2O)Cl2
