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प्रश्न
What type of isomerism is exhibited by the complex [Co(NH3)5Cl]SO4?
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उत्तर
The complex [Co(NH3)5Cl)]SO4 exhibits ionization isomerism. This occurs because the counterions (\[\ce{SO^{2-}_4}\] and Cl−) can switch places, resulting in different isomers like [Co(NH3)5SO4)]Cl. Despite having the same composition, these isomers differ in the ions present in solution.
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संबंधित प्रश्न
Write IUPAC name of the complex [Pt(en)2Cl2]. Draw structures of geometrical isomers for this complex.
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The compounds \[\ce{[CO(SO4)(NH3)5]Br}\] and \[\ce{[Co(SO4)(NH3)5]Cl}\] represent
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Match the complex species given in Column I with the possible isomerism given in Column II and assign the correct code:
| Column I (Complex species) | Column II (Isomerism) |
| A. \[\ce{[Co(NH3)4 Cl2]^+}\] | 1. optical |
| B. \[\ce{cis-[Co(en)2 Cl2]^+}\] | 2. ionisation |
| C. \[\ce{[Co(NH3)5 (NO2)]Cl2}\] | 3. coordination |
| D. \[\ce{[Co(NH3)6][Cr(CN)6]}\] | 4. geometrical |
| 5. linkage |
The diamagnetic species is:-
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Pt(NH3)(H2O)Cl2
