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प्रश्न
What type of isomerism is exhibited by the complex [Co(NH3)5Cl]SO4?
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उत्तर
The complex [Co(NH3)5Cl)]SO4 exhibits ionization isomerism. This occurs because the counterions (\[\ce{SO^{2-}_4}\] and Cl−) can switch places, resulting in different isomers like [Co(NH3)5SO4)]Cl. Despite having the same composition, these isomers differ in the ions present in solution.
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संबंधित प्रश्न
What type of isomerism is shown by the complex [Co(en)3]Cl3
Write IUPAC name of the complex [Pt(en)2Cl2]. Draw structures of geometrical isomers for this complex.
Which of the following isomer has the highest melting point?
Due to the presence of ambidentate ligands coordination compounds show isomerism. Palladium complexes of the type \[\ce{Pd(C6H5)2 (SCN)2]}\] and \[\ce{[Pd(C6H5)2 (NCS)2]}\] are ______.
Which of the following complexes show linkage isomerism?
(i) \[\ce{[Co(NH3)5 (NO2)]^{2+}}\]
(ii) \[\ce{Co(H2O)5 CO]^{3+}}\]
(iii) \[\ce{[Cr(NH3)5 SCN]^{2+}}\]
(iv) \[\ce{Fe(en)2 Cl2]^+}\]
Match the complex species given in Column I with the possible isomerism given in Column II and assign the correct code:
| Column I (Complex species) | Column II (Isomerism) |
| A. \[\ce{[Co(NH3)4 Cl2]^+}\] | 1. optical |
| B. \[\ce{cis-[Co(en)2 Cl2]^+}\] | 2. ionisation |
| C. \[\ce{[Co(NH3)5 (NO2)]Cl2}\] | 3. coordination |
| D. \[\ce{[Co(NH3)6][Cr(CN)6]}\] | 4. geometrical |
| 5. linkage |
CoSO4Cl.5NH3 exists in two isomeric forms ‘A’ and ‘B’. Isomer ‘A’ reacts with AgNO3 to give white precipitate, but does not react with BaCl2. Isomer ‘B’ gives white precipitate with BaCl2 but does not react with AgNO3. Answer the following questions.
- Identify ‘A’ and ‘B’ and write their structural formulas.
- Name the type of isomerism involved.
- Give the IUPAC name of ‘A’ and ‘B’.
A functional isomer of 1-butyne is
Which of the following compounds exhibits linkage isomerism?
Indicate the types of isomerism exhibited by the following complexes and draw the structures for this isomer:
Pt(NH3)(H2O)Cl2
