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प्रश्न
Assertion: \[\ce{Cr(H2O)6]Cl2 and [Fe(H2O)6]Cl2}\] are reducing in nature.
Reason: Unpaired electrons are present in their d-orbitals.
पर्याय
Assertion and reason both are true, reason is correct explanation of assertion.
Assertion and reason both are true but reason is not the correct explanation of assertion.
Assertion is true, reason is false.
Assertion is false, reason is true.
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उत्तर
Assertion and reason both are true but reason is not the correct explanation of assertion.
Explanation:
In the complexes, \[\ce{Co}\] exists as \[\ce{Co^{2+}}\] and \[\ce{Fe}\] as \[\ce{Fe^{2+}}\]. Both of the complexes becomes stable by oxidation of metal ion to \[\ce{Co^{3+}}\] and \[\ce{Fe^{3+}}\].
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संबंधित प्रश्न
Give the oxidation state, d-orbital occupation and coordination number of the central metal ion in the following complex:
[Mn(H2O)6]SO4
IUPAC name of the following compound is
(a) 3 - Bromo- 3, 4- dimethylheptane
(b) 3, 4- dimethyl - 3- bromoheptane
(c) 5- Bromo- 4, 5- dimethylheptane
(d) 4, 5- dimethyl- 5- bromoheptane
How is Benzonitrile converted to Benzophenone?
Write IUPAC name of the following Complex [Cr(NH3)3Cl3]
Write the IUPAC name of the following coordination compound:
[PtCl2(NH3)4][PtCl4]
Write structures of compounds A and B of the following reaction :
Ligand (en) is an example of ___________.
A complex of the type \[\ce{[M(AA)2X2]^{n+}}\] is known to be optically active. What does this indicate about the structure of the complex? Give one example of such complex.
Match the complex ions given in Column I with the colours given in Column II and assign the correct code:
| Column I (Complex ion) | Column II (Colour) |
| A. \[\ce{[Co(NH3)6]^{3+}}\] | 1. Violet |
| B. \[\ce{[Ti(H2O)6]^{3+}}\] | 2. Green |
| C. \[\ce{[Ni(H2O)6]^{2+}}\] | 3. Pale blue |
| D. \[\ce{(Ni(H2O)4 (en)]^{2+} (aq)}\] | 4. Yellowish orange |
| 5. Blue |
Oxidation number of cobalt in K[Co(CO)4] is
Which one of the following ligands forms a chelate?
Ethylene diamine tetraacetate (EDTA) ion is ______.
The correct order of the spin-only magnetic moment of metal ions in the following low spin complexes,
\[\ce{[V(CN)6]^{4-}, [Fe(CN)6]^{4-}, [Ru(NH3)6]^{3+} and [Cr(NH3)6]^2}\] is:
What is a chelate complex?
Assertion (A): EDTA is a hexadentate ligand.
Reason (R): EDTA has 2 nitrogen and 4 oxygen donor atoms.
What is meant by the chelate effect? Give an example.
Explain the following, giving two examples:
Heteroleptic
Give two examples of unidentate ligands.
Give two examples of didentate ligands.
