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कर्नाटक बोर्ड पी.यू.सी.पीयूसी विज्ञान 2nd PUC Class 12

Assertion: Cr(HX2O)X6]ClX2 and [Fe(HX2O)X6]ClX2 are reducing in nature. Reason: Unpaired electrons are present in their d-orbitals. - Chemistry

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प्रश्न

Assertion: \[\ce{Cr(H2O)6]Cl2 and [Fe(H2O)6]Cl2}\] are reducing in nature.

Reason: Unpaired electrons are present in their d-orbitals.

पर्याय

  • Assertion and reason both are true, reason is correct explanation of assertion.

  • Assertion and reason both are true but reason is not the correct explanation of assertion.

  • Assertion is true, reason is false.

  • Assertion is false, reason is true.

MCQ
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उत्तर

Assertion and reason both are true but reason is not the correct explanation of assertion.

Explanation:

In the complexes, \[\ce{Co}\] exists as \[\ce{Co^{2+}}\] and \[\ce{Fe}\] as \[\ce{Fe^{2+}}\]. Both of the complexes becomes stable by oxidation of metal ion to \[\ce{Co^{3+}}\] and \[\ce{Fe^{3+}}\].

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पाठ 9: Coordination Compounds - Exercises [पृष्ठ १२७]

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एनसीईआरटी एक्झांप्लर Chemistry [English] Class 12
पाठ 9 Coordination Compounds
Exercises | Q V. 42. | पृष्ठ १२७

संबंधित प्रश्‍न

Classify the following ligands into monodentate and polydentate —

  1. Ammonia
  2. Carbon monoxide
  3. Ethylene diamine
  4. Ethylene diamine tetra acetate ion

Give the oxidation state, d-orbital occupation and coordination number of the central metal ion in the following complex:

cis-[CrCl2(en)2]Cl


Which of the following compounds is used as a semipermeable membrane?

(a) Potassium ferrocyanide

(b) Potassium argentocyanide

(c) Sodium meta aluminate

(d) Copper ferrocyanide


Write the IUPAC name of the following complex:

[Co(NH3)5(CO3)]Cl


Write structures of compounds A and B of the following reaction : 


What is the coordination number of chromium in \[\ce{[Cr(NH3)2(H2O2)2]Cl3}\]?


When 0.1 mol \[\ce{CoCl3 (NH3)5}\] is treated with excess of \[\ce{AgNO3}\], 0.2 mol of \[\ce{AgCl}\] are obtained. The conductivity of solution will correspond to ______.


The correct \[\ce{IUPAC}\] name of \[\ce{[Pt(NH3)2Cl2]}\] is ______.


Which of the following complexes are heteroleptic?

(i) \[\ce{[Cr(NH3)6]^{3+}}\]

(ii) \[\ce{[Fe(NH3)4]Cl2]^+}\]

(iii) \[\ce{[Mn(CN)6]^{4-}}\]

(iv) \[\ce{[Co(NH3)4]Cl2]}\]


Which one of the following does not achieve an octet of electrons in the central atom?


In which of the following compounds, the oxidation number of iodine is fractional?


The complex which has no d electrons in the central atom is:-


Which of the following ligands can exhibit linkage isomerism?


What are Heteroleptic complexes?


Glycinato ligand is ______.


The one that will show optical activity is: (en = ethane 1, 2-diamine)


What is a chelate complex?


Statement I: [Co(NH3)6]3+ is a homoleptic compleх whereas [Co(NH3)4Cl2]+ is a heteroleptic complex.

Statement II: Complex [Co(NH3)6]3+ has only one kind of ligands but [Co(NH3)4Cl2]+ has more than one kind of ligands.

In the light of the above statements, Choose the correct answer form the options given below.


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