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प्रश्न
Give the oxidation state, d-orbital occupation and coordination number of the central metal ion in the following complex:
cis-[CrCl2(en)2]Cl
Give the oxidation state, d-orbital occupation and coordination number of the central metal ion in the following complex:
cis-[Cr(en)2Cl2]Cl
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उत्तर
Oxidation state = +3,
Coordination number = 6,
3d3 configuration = \[\ce{t^3_{2g}e^0_g}\]
संबंधित प्रश्न
Give the oxidation state, d-orbital occupation and coordination number of the central metal ion in the following complex:
(NH4)2[CoF4]
IUPAC name of the following compound is
(a) 3 - Bromo- 3, 4- dimethylheptane
(b) 3, 4- dimethyl - 3- bromoheptane
(c) 5- Bromo- 4, 5- dimethylheptane
(d) 4, 5- dimethyl- 5- bromoheptane
Write IUPAC names of the following compounds:
Write the IUPAC name of the following complex:
[Co(NH3)5(CO3)]Cl
Write the IUPAC name of the following coordination compound:
[PtCl2(NH3)4][PtCl4]
Write structures of compounds A and B of the following reaction :
A group of atoms can function as a ligand only when:
The oxidation number of Fe in K4[Fe(CN)6] is ____________.
Which of the following is non-ionizable?
A coordination compound \[\ce{CrCl3.4H2O}\] precipitates silver chloride when treated with silver nitrate. The molar conductance of its solution corresponds to a total of two ions. Write structural formula of the compound and name it.
Match the coordination compounds given in Column I with the central metal atoms given in Column II and assign the correct code:
| Column I (Coordination Compound) | Column II (Central metal atom) |
| A. Chlorophyll | 1. rhodium |
| B. Blood pigment | 2. cobalt |
| C. Wilkinson catalyst | 3. calcium |
| D. Vitamin B12 | 4. iron |
| 5. magnesium |
Match the compounds given in Column I with the oxidation state of cobalt present in it (given in Column II) and assign the correct code:
| Column I (Compound) | Column II (Oxidation state of Co) |
| A. \[\ce{[Co(NCS)(NH3)5](SO3)}\] | 1. + 4 |
| B. \[\ce{[Co(NH3)4 CL2]SO4}\] | 2. 0 |
| C. \[\ce{Na4[Co(S2O3)3]}\] | 3. + 1 |
| D. \[\ce{[Co2(CO)8]}\] | 4. + 2 |
| 5. + 3 |
The oxidation number d-arbitral occupation and co-ordination number of Cr in the complex cis [Cr(en)2Cl2]Cl are respectively.
Which of the following ligands can exhibit linkage isomerism?
Given below are two statements.
Statement I: In CuSO4·5H2O, Cu-O bonds are present.
Statement II: In CuSO4·5H2O, ligands coordinating with Cu(II) ion are O- and S-based ligands.
In light of the above statement, choose the correct answer from the options given below.
The correct order of the spin-only magnetic moment of metal ions in the following low spin complexes,
\[\ce{[V(CN)6]^{4-}, [Fe(CN)6]^{4-}, [Ru(NH3)6]^{3+} and [Cr(NH3)6]^2}\] is:
What is meant by the chelate effect? Give an example.
Explain the following, giving two examples:
Homoleptic
Explain the following, giving two examples:
Heteroleptic
