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Give the oxidation state, d-orbital occupation and coordination number of the central metal ion in the following complex: cis-[CrCl2(en)2]Cl

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प्रश्न

Give the oxidation state, d-orbital occupation and coordination number of the central metal ion in the following complex:

cis-[CrCl2(en)2]Cl

Give the oxidation state, d-orbital occupation and coordination number of the central metal ion in the following complex:

cis-[Cr(en)2Cl2]Cl

अति संक्षिप्त उत्तर
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उत्तर

Oxidation state = +3

Coordination number = 6

3d3 configuration = \[\ce{t^3_{2g}e^0_g}\]

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पाठ 5: Coordinate Compounds - Exercises [पृष्ठ १३९]

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एनसीईआरटी Chemistry Part 1 and 2 [English] Class 12
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संबंधित प्रश्‍न

Classify the following ligands into monodentate and polydentate —

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  2. Carbon monoxide
  3. Ethylene diamine
  4. Ethylene diamine tetra acetate ion

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Give the oxidation state, d-orbital occupation and coordination number of the central metal ion in the following complex:

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(NH4)2[CoF4]


Which of the following compounds is used as a semipermeable membrane?

(a) Potassium ferrocyanide

(b) Potassium argentocyanide

(c) Sodium meta aluminate

(d) Copper ferrocyanide


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Which of the following complexes are heteroleptic?

(i) \[\ce{[Cr(NH3)6]^{3+}}\]

(ii) \[\ce{[Fe(NH3)4]Cl2]^+}\]

(iii) \[\ce{[Mn(CN)6]^{4-}}\]

(iv) \[\ce{[Co(NH3)4]Cl2]}\]


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Match the complex ions given in Column I with the colours given in Column II and assign the correct code:

Column I (Complex ion) Column II (Colour)
A. \[\ce{[Co(NH3)6]^{3+}}\] 1. Violet
B. \[\ce{[Ti(H2O)6]^{3+}}\] 2. Green
C. \[\ce{[Ni(H2O)6]^{2+}}\] 3. Pale blue
D. \[\ce{(Ni(H2O)4 (en)]^{2+} (aq)}\] 4. Yellowish orange
  5. Blue

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Reason: Unpaired electrons are present in their d-orbitals.


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The complex which has no d electrons in the central atom is:-


The following ligand is:


The one that will show optical activity is: (en = ethane 1, 2-diamine)


What is a chelate complex?


What is meant by ambidentate ligand?


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