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कर्नाटक बोर्ड पी.यू.सी.पीयूसी विज्ञान 2nd PUC Class 12

Assertion: Linkage isomerism arises in coordination compounds containing ambidentate ligand. Reason: Ambidentate ligand has two different donor atoms

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प्रश्न

Assertion: Linkage isomerism arises in coordination compounds containing ambidentate ligand.

Reason: Ambidentate ligand has two different donor atoms

विकल्प

  • Assertion and reason both are true, reason is correct explanation of assertion.

  • Assertion and reason both are true but reason is not the correct explanation of assertion.

  • Assertion is true, reason is false.

  • Assertion is false, reason is true.

MCQ
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उत्तर

Assertion and reason both are true, reason is correct explanation of assertion.

Explanation:

Linkage isomerism arises due to two different donor atoms in ambidentate ligand.

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अध्याय 9: Coordination Compounds - Exercises [पृष्ठ १२७]

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एनसीईआरटी एक्झांप्लर Chemistry Exemplar [English] Class 12
अध्याय 9 Coordination Compounds
Exercises | Q V. 43. | पृष्ठ १२७

संबंधित प्रश्न

 

The complex ion `[Co(H_2O)_5 (ONO)]^(2+) `

(A) linkage isomer

(B) ionisation isomer

(C) co-ordination isomer

(D) geometrical isomer

 

Give evidence that [Co(NH3)5Cl]SO4 and [Co(NH3)5SO4]Cl are ionisation isomers.


What type of isomerism is shown by the complex [Co(en)3]Cl3


What type of isomerism is shown by the complex [Co(NH3)6] [Cr(CN)6]?


What type of isomerism is shown by the complex [Co(NH3)5(SCN)]2+?


What type of isomerism is exhibited by the complex [Co(NH3)5Cl]SO4?


Write the IUPAC name of the complex [Cr(NH3)4Cl2]+. What type of isomerism does it exhibit?


Which among the following is an ambidentate ligand?


Which of the following pair contains a complex salt and double salt respectively?


Due to the presence of ambidentate ligands coordination compounds show isomerism. Palladium complexes of the type \[\ce{Pd(C6H5)2 (SCN)2]}\] and \[\ce{[Pd(C6H5)2 (NCS)2]}\] are ______.


The compounds \[\ce{[CO(SO4)(NH3)5]Br}\] and \[\ce{[Co(SO4)(NH3)5]Cl}\] represent


What kind of isomerism exists between \[\ce{[Cr(H2O)6]Cl3}\] (violet) and \[\ce{[Cr(H2O)5Cl]Cl2 . H2O}\] (greyish-green)?


Name the type of isomerism when ambidentate ligands are attached to central metal ion. Give two examples of ambidentate ligands.


Match the complex species given in Column I with the possible isomerism given in Column II and assign the correct code:

Column I (Complex species) Column II (Isomerism)
A. \[\ce{[Co(NH3)4 Cl2]^+}\] 1. optical
B. \[\ce{cis-[Co(en)2 Cl2]^+}\] 2. ionisation
C. \[\ce{[Co(NH3)5 (NO2)]Cl2}\] 3. coordination
D. \[\ce{[Co(NH3)6][Cr(CN)6]}\] 4. geometrical
  5. linkage

A functional isomer of 1-butyne is


Which of the following compounds exhibits linkage isomerism?


Which isomer of C5H10 gives a single monochloro compound C5H9Cl in bright sunlight?


The complex [Co(NH3)5(NO2)]Cl2 is red in colour. Give IUPAC the name of its linkage isomer.


Indicate the types of isomerism exhibited by the following complexes and draw the structures for this isomer:

Pt(NH3)(H2O)Cl2


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