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कर्नाटक बोर्ड पी.यू.सी.पीयूसी विज्ञान 2nd PUC Class 12

The compounds [CO(SOX4)(NHX3)X5]Br and [Co(SOX4)(NHX3)X5]Cl represent - Chemistry

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प्रश्न

The compounds \[\ce{[CO(SO4)(NH3)5]Br}\] and \[\ce{[Co(SO4)(NH3)5]Cl}\] represent

विकल्प

  • linkage isomerism

  • ionisation isomerism

  • coordination isomerism

  • no isomerism

MCQ
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उत्तर

no isomerism

Explanation:

\[\ce{[Co(SO4)(NH3)5]Br}\] and \[\ce{[CO(SO4)(NH3)5]Cl}\] represent no isomerism because they are different compounds.

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अध्याय 9: Coordination Compounds - Exercises [पृष्ठ १२१]

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एनसीईआरटी एक्झांप्लर Chemistry [English] Class 12
अध्याय 9 Coordination Compounds
Exercises | Q I. 10. | पृष्ठ १२१

संबंधित प्रश्न

 

The complex ion `[Co(H_2O)_5 (ONO)]^(2+) `

(A) linkage isomer

(B) ionisation isomer

(C) co-ordination isomer

(D) geometrical isomer

 

What type of isomerism is shown by the complex [Co(en)3]Cl3


What type of isomerism is shown by the complex [Co(NH3)6] [Cr(CN)6]?


Write IUPAC name of the complex [Pt(en)2Cl2]. Draw structures of geometrical isomers for this complex. 


Which among the following is an ambidentate ligand?


Which of the following isomer has the highest melting point?


Due to the presence of ambidentate ligands coordination compounds show isomerism. Palladium complexes of the type \[\ce{Pd(C6H5)2 (SCN)2]}\] and \[\ce{[Pd(C6H5)2 (NCS)2]}\] are ______.


What kind of isomerism exists between \[\ce{[Cr(H2O)6]Cl3}\] (violet) and \[\ce{[Cr(H2O)5Cl]Cl2 . H2O}\] (greyish-green)?


Which of the following complexes show linkage isomerism?

(i) \[\ce{[Co(NH3)5 (NO2)]^{2+}}\]

(ii) \[\ce{Co(H2O)5 CO]^{3+}}\]

(iii) \[\ce{[Cr(NH3)5 SCN]^{2+}}\]

(iv) \[\ce{Fe(en)2 Cl2]^+}\]


Name the type of isomerism when ambidentate ligands are attached to central metal ion. Give two examples of ambidentate ligands.


Assertion: Linkage isomerism arises in coordination compounds containing ambidentate ligand.

Reason: Ambidentate ligand has two different donor atoms


CoSO4Cl.5NH3 exists in two isomeric forms ‘A’ and ‘B’. Isomer ‘A’ reacts with AgNO3 to give white precipitate, but does not react with BaCl2. Isomer ‘B’ gives white precipitate with BaCl2 but does not react with AgNO3. Answer the following questions.

  1. Identify ‘A’ and ‘B’ and write their structural formulas.
  2. Name the type of isomerism involved.
  3. Give the IUPAC name of ‘A’ and ‘B’.

A functional isomer of 1-butyne is


The diamagnetic species is:-


Which of the following compounds exhibits linkage isomerism?


Which isomer of C5H10 gives a single monochloro compound C5H9Cl in bright sunlight?


The complex [Co(NH3)5(NO2)]Cl2 is red in colour. Give IUPAC the name of its linkage isomer.


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