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प्रश्न
Answer in brief.
What are ionization isomers ? Give an example.
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उत्तर
Isomers that involve the exchange of ligands between coordination and ionization spheres are called ionization isomers.
e.g. [Co(NH3)5SO4]Br and [Co(NH3)5Br]SO4
संबंधित प्रश्न
List various types of isomerism possible for coordination compounds, giving an example of each.
Choose the most correct option.
Which of the following complexes exist as cis and trans isomers?
1. [Cr(NH3)2Cl4]-
2. [Co(NH3)5Br]2⊕
3. [PtCl2Br2]2- (square planar)
4. [FeCl2(NCS)2]2- (tetrahedral)
Answer the following question.
Draw geometric isomers and enantiomers of the following complex.
[Pt(en)3]4⊕
Define the term Co-ordination isomer.
Draw the geometrical isomers of the following complexes [Pt(NH3)(H2O)Cl2].
Which one of the following complexes is not expected to exhibit isomerism?
Draw all possible geometrical isomers of the complex \[\ce{[Co(en)2Cl2]^+}\] and identify the optically active isomer.
What is linkage isomerism? Explain with an example.
The term anomers of glucose refer to ____________.
Which would exhibit coordination isomerism?
Identify the CORRECT statement about the following complex of platinum.
[PtCl2(en)2]2+
Which of the following has zero dipole moment?
How many donor groups are present in diethylene triamine?
What is the number of moles of silver chloride precipitated when excess of aqueous silver nitrate is treated with [Co(NH3)4Cl2]Cl?
Indicate the complex ion which shows geometrical isomerism.
Complex [COCl2(en)2]+ can
Which of the following compounds show optical isomerism?
Which of the following has an optical isomer?
Which of the following shows maximum number of isomers?
Write the name of isomerism in the following complexes:
[Cu(NH3)4] [PtCl4] and [Pt(NH3)4] [ CuCl4]
Which compound would exhibit optical isomers?
The one that is not expected to show isomerism is ______.
Write structures for geometrical isomers of diamminebromochloroplatinum (II).
The co-ordination number of Co3+ ion in the complex [Co(NH3)4Cl2]⊕ is ______.
Name the type of isomerism exhibited by the following pair of compounds:
[Cr(H2O)5Cl]Cl2.H2O and [Cr(H2O)4Cl2]Cl.2H2O
Three organic compounds A, B and C are non cyclic functional isomers of carbonyl compounds with molecular formula C4H8O. Isomers A and C give positive Tollen’s test while compound B does not give positive Tollen’s test but gives positive iodoform test. Compounds A and B on reduction with Zn amalgam and conc. HCl give the same product.
- Write the structures of the compounds A, B and C.
- Out of the compounds A, B and C, which one will be the least reactive towards addition of HCN.
Match List-I with List-II:
| List-I (Complex) |
List-II (Type of isomerism) |
| A. [Co(NH3)5(NO2)]Cl2 | I. Solvate isomerism |
| B. [Co(NH3)5(SO4)]Br | II. Linkage isomerism |
| C. [Co(NH3)6][Cr(CN)6] | III. Ionisation isomerism |
| D. [Co(H2O)6]Cl3 | IV. Coordination isomerism |
Choose the correct answer from the options given below:
