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Answer in brief. What are ionization isomers ? Give an example. - Chemistry

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प्रश्न

Answer in brief.

What are ionization isomers ? Give an example.

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उत्तर

Isomers that involve the exchange of ligands between coordination and ionization spheres are called ionization isomers.

e.g. [Co(NH3)5SO4]Br and [Co(NH3)5Br]SO4

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पाठ 9: Coordination Compounds - Exercises [पृष्ठ २०८]

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बालभारती Chemistry [English] Standard 12 Maharashtra State Board
पाठ 9 Coordination Compounds
Exercises | Q 3.06 | पृष्ठ २०८

संबंधित प्रश्‍न

Give one chemical test as an evidence to show that [Co (NH3)5Cl]  are ionisation isomers. 


Choose the most correct option.

Which of the following complexes exist as cis and trans isomers?

1. [Cr(NH3)2Cl4]-

2. [Co(NH3)5Br]2⊕

3. [PtCl2Br2]2- (square planar)

4. [FeCl2(NCS)2]2- (tetrahedral)


Answer the following question.

Draw isomers of the following

Ru(NH3)4Cl2


Answer the following question.

Draw geometric isomers and enantiomers of the following complex.

[Pt(en)3]4⊕


The pair [Co(NH3)5(SO4)]Br and [Co(NH3)5Br]SO4 exhibits ____________ isomerism


Define the term Hydrated isomers.


Draw structure of cis isomer of [Co(NH3)4Cl2]+


Draw the geometrical isomers of the following complexes [Pt(NH3)(H2O)Cl2].


Fac-mer isomerism is shown by


Draw all possible geometrical isomers of the complex \[\ce{[Co(en)2Cl2]^+}\] and identify the optically active isomer.


Explain optical isomerism in coordination compounds with an example.


The term anomers of glucose refer to ____________.


Which of the following does NOT show optical isomerism?


Which of the following has zero dipole moment?


Indicate the complex ion which shows geometrical isomerism.


Assertion: Complexes of MX6 and MX5L type (X and L are unidentate) do not show geometrical isomerism.

Reason: Geometrical isomerism is not shown by complexes of coordination number 6.


The relationship between compound (i) and (ii) is

(i) (ii)

Geometrical isomerism is not shown by


Which of the following shows maximum number of isomers?


Which of the following compound is optically active?


White precipitate of AgCl dissolves in aqueous ammonia solution due to formation of ______.


The one that is not expected to show isomerism is ______.


Write structures for geometrical isomers of diamminebromochloroplatinum (II).


Explain the geometrical isomerism of the octahedral complex of the type [M(AA)2B2]with a suitable example.


Match the pairs in column I (pairs of isomers) and column II (types of isomers)

Column I
(Pairs of isomers)
Column II
(Types of isomers)
(A) [Cr(H2O)5Cl]Cl2.H2O and [Cr(H2O)4Cl2]Cl.2H2O (i) Ionization isomers
(B) [Co(en)2(NO2)2]+ and [Co(en)2(ONO2)]+ (ii) Hydrate isomers
(C) [Co(NH3)6] [Cr(CN)6] and [Cr(NH3)6] [Co(CN)6] (iii) Linkage isomers
(D) [Pt(NH3)4Cl2] Br2 and [Pt(NH3)4Br2]Cl2 (iv) Coordination isomers

Name the type of isomerism exhibited by the following pair of compounds:

[Co(NH3)5(ONO)]Cl2 and [Co(NH3)5(NO2)]Cl2


Which one of the following complex ions has geometrical isomers?


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