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प्रश्न
Answer in brief.
What are ionization isomers ? Give an example.
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उत्तर
Isomers that involve the exchange of ligands between coordination and ionization spheres are called ionization isomers.
e.g. [Co(NH3)5SO4]Br and [Co(NH3)5Br]SO4
संबंधित प्रश्न
Write the structural formula and IUPAC names of all possible isomers of the compound with molecular formula C3H8O.
Out of 
and 
, which one is optically active and why ?
Answer the following in one or two sentences.
Consider the complexes \[\ce{[Cu(NH3)4][PtCl4] and [Pt(NH3)4] [CuCl4]}\]. What type of isomerism these two complexes exhibit?
Draw isomers of the following.
\[\ce{Pt(NH3)2ClNO2}\]
Draw structure of cis isomer of [Co(NH3)4Cl2]+
Draw optical isomers of [Co(en)3]3+.
Which one of the following pairs represents linkage isomers?
Which kind of isomerism is possible for a complex [Co(NH3)4Br2]Cl?
Fac-mer isomerism is shown by
Explain optical isomerism in coordination compounds with an example.
What are hydrate isomers? Explain with an example.
Which would exhibit coordination isomerism?
Consider the two complexes given below:
\[\ce{\underset{(I)}{[Co(NH3)5SO4]Br}}\] and \[\ce{\underset{(II)}{[Co(NH3)5Br]SO4}}\]
I and II are ____________ isomers.
____________ isomers are formed when the ligand has two different donor atoms.
How many donor groups are present in diethylene triamine?
Indicate the complex ion which shows geometrical isomerism.
\[\ce{IUPAC}\] name of \[\ce{[Pt(NH3)2 Cl(NO2)]}\] is ______.
Assertion: Complexes of MX6 and MX5L type (X and L are unidentate) do not show geometrical isomerism.
Reason: Geometrical isomerism is not shown by complexes of coordination number 6.
Which of the following shows maximum number of isomers?
Write the name of isomerism in the following complexes:
[Cu(NH3)4] [PtCl4] and [Pt(NH3)4] [ CuCl4]
The one that is not expected to show isomerism is ______.
Give cis isomer of [Co(NH3)4Cl2]⊕.
Explain the geometrical isomerism of the octahedral complex of the type [M(AA)2B2]n± with a suitable example.
Explain the ionisation isomers.
Match the pairs in column I (pairs of isomers) and column II (types of isomers)
| Column I (Pairs of isomers) |
Column II (Types of isomers) |
| (A) [Cr(H2O)5Cl]Cl2.H2O and [Cr(H2O)4Cl2]Cl.2H2O | (i) Ionization isomers |
| (B) [Co(en)2(NO2)2]+ and [Co(en)2(ONO2)]+ | (ii) Hydrate isomers |
| (C) [Co(NH3)6] [Cr(CN)6] and [Cr(NH3)6] [Co(CN)6] | (iii) Linkage isomers |
| (D) [Pt(NH3)4Cl2] Br2 and [Pt(NH3)4Br2]Cl2 | (iv) Coordination isomers |
Draw the structure of cis isomers of Pt(NH3)2Cl2.
Name the type of isomerism exhibited by the following pair of compounds:
[Co(NH3)5(ONO)]Cl2 and [Co(NH3)5(NO2)]Cl2
