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Draw the geometrical isomers of the following complexes [Co(NH3)4Cl2]+ - Chemistry

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प्रश्न

Draw the geometrical isomers of the following complexes [Co(NH3)4Cl2]+

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पाठ 9: Coordination Compounds - Short Answer Questions (Type-II)

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एससीईआरटी महाराष्ट्र Chemistry [English] 12 Standard HSC
पाठ 9 Coordination Compounds
Short Answer Questions (Type-II) | Q 4.2

संबंधित प्रश्‍न

List various types of isomerism possible for coordination compounds, giving an example of each.


Give one chemical test as an evidence to show that [Co (NH3)5Cl]  are ionisation isomers. 


Answer the following in one or two sentences.

Predict whether the [Cr(en)2(H2O)2]3+ complex is chiral. Write the structure of its enantiomer.


Answer the following question.

Draw isomers of the following

[Cr(en2)Br2]


Answer the following question.

Draw geometric isomers and enantiomers of the following complex.

[Pt(en)2ClBr]2⊕


Define the term Co-ordination isomer.


Which one of the following will give a pair of enantiomorphs?


How many geometrical isomers are possible for \[\ce{[Pt(Py)(NH3)(Br)(Cl)]}\]?


Which kind of isomerism is possible for a complex [Co(NH3)4Br2]Cl?


Which one of the following complexes is not expected to exhibit isomerism?


Fac-mer isomerism is shown by


Draw all possible geometrical isomers of the complex \[\ce{[Co(en)2Cl2]^+}\] and identify the optically active isomer.


Explain optical isomerism in coordination compounds with an example.


Identify the CORRECT statement about the following complex of platinum.

[PtCl2(en)2]2+


Consider the two complexes given below:

\[\ce{\underset{(I)}{[Co(NH3)5SO4]Br}}\] and \[\ce{\underset{(II)}{[Co(NH3)5Br]SO4}}\]

I and II are ____________ isomers.


The formula of two complexes X and Y of chromium are given below:

\[\ce{\underset{(X)}{[Cr(H2O)6]Cl3}}\] and \[\ce{\underset{(Y)}{[Cr(H2O)5Cl]Cl2.H2O}}\]

X and Y are examples of ____________ isomers.


Indicate the complex ion which shows geometrical isomerism.


The relationship between compound (i) and (ii) is

(i) (ii)

Which of the following are isostructural pairs?

(A) \[\ce{SO^{2-}4}\] and \[\ce{CrO^{2-}4}\]

(B) SiCl4 and TiCl4

(C) NH3 and \[\ce{NO^-3}\]

(D) BCl3 and BrCl3


Which of the following compound is optically active?


Indicate the type of isomerism exhibited by the following complex and draw the structures for this isomer:

\[\ce{[Pt(NH3)(H2O)Cl2]}\]


Indicate the types of isomerism exhibited by the following complexes and draw the structures for these isomers: [Pt(NH3)(H2O)Cl2]


Draw the structure of trans isomers of Pt(NH3)2Cl2.


Name the type of isomerism exhibited by the following pair of compound:

\[\ce{[Pt(NH3)4Cl2]Br2  and  [Pt(NH3)4 Br2]Cl2}\]


Three organic compounds A, B and C are non cyclic functional isomers of carbonyl compounds with molecular formula C4H8O. Isomers A and C give positive Tollen’s test while compound B does not give positive Tollen’s test but gives positive iodoform test. Compounds A and B on reduction with Zn amalgam and conc. HCl give the same product.

  1. Write the structures of the compounds A, B and C.
  2. Out of the compounds A, B and C, which one will be the least reactive towards addition of HCN.

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