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प्रश्न
Define the term Co-ordination isomer.
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उत्तर
Isomers which show interchange of ligands between cationic and anionic spheres of different metal ions are called co-ordination isomers.
संबंधित प्रश्न
Answer in brief.
What are ionization isomers ? Give an example.
Draw isomers of the following.
\[\ce{Pt(NH3)2ClNO2}\]
Answer the following question.
Draw geometric isomers and enantiomers of the following complex.
[Pt(en)3]4⊕
Draw optical isomers of [Co(en)3]3+.
Which one of the following will give a pair of enantiomorphs?
Which type of isomerism is exhibited by [Pt(NH3)2Cl2]?
Explain optical isomerism in coordination compounds with an example.
The term anomers of glucose refer to ____________.
The compound(s) that exhibit(s) geometrical isomerism is (are):
(I) [Pt(en)Cl2]
(II) [Pt(en)2]Cl2
(III) [Pt(en)2Cl2]
(IV) [Pt(NH3)2Cl2]
The number of geometrical isomers of [CrCl2(en)2]+ is ____________.
Consider the two complexes given below:
\[\ce{\underset{(I)}{[Co(NH3)5SO4]Br}}\] and \[\ce{\underset{(II)}{[Co(NH3)5Br]SO4}}\]
I and II are ____________ isomers.
Which of the following does NOT show optical isomerism?
____________ isomers are formed when the ligand has two different donor atoms.
The formula of two complexes X and Y of chromium are given below:
\[\ce{\underset{(X)}{[Cr(H2O)6]Cl3}}\] and \[\ce{\underset{(Y)}{[Cr(H2O)5Cl]Cl2.H2O}}\]
X and Y are examples of ____________ isomers.
The relationship between compound (i) and (ii) is
 |
 |
| (i) | (ii) |
Write the name of isomerism in the following complexes:
[Cu(NH3)4] [PtCl4] and [Pt(NH3)4] [ CuCl4]
Which of the following are isostructural pairs?
(A) \[\ce{SO^{2-}4}\] and \[\ce{CrO^{2-}4}\]
(B) SiCl4 and TiCl4
(C) NH3 and \[\ce{NO^-3}\]
(D) BCl3 and BrCl3
Which compound would exhibit optical isomers?
The number of geometrical isomers of \[\ce{[Co(NH3)3 (NO3)3]}\] are ______.
Define Distereoisomers.
Indicate the types of isomerism exhibited by the following complexes and draw the structures for these isomers: [Pt(NH3)(H2O)Cl2]
Explain the ionisation isomers.
Give a chemical test to show that \[\ce{[Co(NH3)5Cl]SO4}\] and \[\ce{[Co(NH3)5SO4]CI}\] are ionisation isomers.
Three organic compounds A, B and C are non cyclic functional isomers of carbonyl compounds with molecular formula C4H8O. Isomers A and C give positive Tollen’s test while compound B does not give positive Tollen’s test but gives positive iodoform test. Compounds A and B on reduction with Zn amalgam and conc. HCl give the same product.
- Write the structures of the compounds A, B and C.
- Out of the compounds A, B and C, which one will be the least reactive towards addition of HCN.
