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प्रश्न
Define the term Co-ordination isomer.
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उत्तर
Isomers which show interchange of ligands between cationic and anionic spheres of different metal ions are called co-ordination isomers.
संबंधित प्रश्न
Out of 
and 
, which one is optically active and why ?
Choose the most correct option.
Which of the following complexes exist as cis and trans isomers?
1. [Cr(NH3)2Cl4]-
2. [Co(NH3)5Br]2⊕
3. [PtCl2Br2]2- (square planar)
4. [FeCl2(NCS)2]2- (tetrahedral)
Draw isomers of the following.
\[\ce{Pt(NH3)2ClNO2}\]
Define the term Hydrated isomers.
Draw structure of cis isomer of [Co(NH3)4Cl2]+
Which one of the following will give a pair of enantiomorphs?
Draw all possible geometrical isomers of the complex \[\ce{[Co(en)2Cl2]^+}\] and identify the optically active isomer.
Identify the CORRECT statement about the following complex of platinum.
[PtCl2(en)2]2+
____________ isomers are formed when the ligand has two different donor atoms.
What is the number of moles of silver chloride precipitated when excess of aqueous silver nitrate is treated with [Co(NH3)4Cl2]Cl?
What type of isomerism is present between (I) [Cr(H2O)6]Cl3 and (II) [Cr(H2O)5Cl]Cl2.H2O?
Indicate the complex ion which shows geometrical isomerism.
Assertion: Complexes of MX6 and MX5L type (X and L are unidentate) do not show geometrical isomerism.
Reason: Geometrical isomerism is not shown by complexes of coordination number 6.
Which of the following has an optical isomer?
Which compound would exhibit optical isomers?
The number of geometrical isomers of \[\ce{[Co(NH3)3 (NO3)3]}\] are ______.
White precipitate of AgCl dissolves in aqueous ammonia solution due to formation of ______.
The compounds [PtCl2(NH3)4]Br2 and [PtBr2(NH3)4]Cl2 constitutes a pair of ______.
Give cis isomer of [Co(NH3)4Cl2]⊕.
Indicate the type of isomerism exhibited by the following complex and draw the structures for this isomer:
\[\ce{[Pt(NH3)(H2O)Cl2]}\]
Explain the ionisation isomers.
Match the pairs in column I (pairs of isomers) and column II (types of isomers)
| Column I (Pairs of isomers) |
Column II (Types of isomers) |
| (A) [Cr(H2O)5Cl]Cl2.H2O and [Cr(H2O)4Cl2]Cl.2H2O | (i) Ionization isomers |
| (B) [Co(en)2(NO2)2]+ and [Co(en)2(ONO2)]+ | (ii) Hydrate isomers |
| (C) [Co(NH3)6] [Cr(CN)6] and [Cr(NH3)6] [Co(CN)6] | (iii) Linkage isomers |
| (D) [Pt(NH3)4Cl2] Br2 and [Pt(NH3)4Br2]Cl2 | (iv) Coordination isomers |
Draw the geometrical isomers of the following complexes [Co(NH3)4Cl2]+
Draw the structure of trans isomers of Pt(NH3)2Cl2.
Name the type of isomerism exhibited by the following pair of compounds:
[Cr(H2O)5Cl]Cl2.H2O and [Cr(H2O)4Cl2]Cl.2H2O
Give a chemical test to show that \[\ce{[Co(NH3)5Cl]SO4}\] and \[\ce{[Co(NH3)5SO4]CI}\] are ionisation isomers.
Which one of the following complex ions has geometrical isomers?
Three organic compounds A, B and C are non cyclic functional isomers of carbonyl compounds with molecular formula C4H8O. Isomers A and C give positive Tollen’s test while compound B does not give positive Tollen’s test but gives positive iodoform test. Compounds A and B on reduction with Zn amalgam and conc. HCl give the same product.
- Write the structures of the compounds A, B and C.
- Out of the compounds A, B and C, which one will be the least reactive towards addition of HCN.
