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प्रश्न
Define the term Co-ordination isomer.
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उत्तर
Isomers which show interchange of ligands between cationic and anionic spheres of different metal ions are called co-ordination isomers.
संबंधित प्रश्न
Define the term Hydrated isomers.
Draw structure of cis isomer of [Co(NH3)4Cl2]+
Draw the geometrical isomers of the following complexes [Pt(NH3)(H2O)Cl2].
Which one of the following will give a pair of enantiomorphs?
Which one of the following complexes is not expected to exhibit isomerism?
Draw all possible geometrical isomers of the complex \[\ce{[Co(en)2Cl2]^+}\] and identify the optically active isomer.
Identify the CORRECT statement about the following complex of platinum.
[PtCl2(en)2]2+
Which of the following is NOT an isomer of n-hexane?
Which of the following does NOT show optical isomerism?
The complex ions [Co(H2O)5(ONO)]2+ and [Co(H2O)5NO2]2+ are ____________.
The formula of two complexes X and Y of chromium are given below:
\[\ce{\underset{(X)}{[Cr(H2O)6]Cl3}}\] and \[\ce{\underset{(Y)}{[Cr(H2O)5Cl]Cl2.H2O}}\]
X and Y are examples of ____________ isomers.
What is the number of moles of silver chloride precipitated when excess of aqueous silver nitrate is treated with [Co(NH3)4Cl2]Cl?
Which of the following does not show optical isomerism?
Draw geometric isomers of the following complex.
Geometrical isomers of Pt(NH3)2Cl2
Which of the following are isostructural pairs?
(A) \[\ce{SO^{2-}4}\] and \[\ce{CrO^{2-}4}\]
(B) SiCl4 and TiCl4
(C) NH3 and \[\ce{NO^-3}\]
(D) BCl3 and BrCl3
Which compound would exhibit optical isomers?
The number of geometrical isomers of \[\ce{[Co(NH3)3 (NO3)3]}\] are ______.
The compounds [PtCl2(NH3)4]Br2 and [PtBr2(NH3)4]Cl2 constitutes a pair of ______.
Give trans isomer of [Co(NH3)4Cl2]⊕.
Indicate the types of isomerism exhibited by the following complexes and draw the structures for these isomers: [Pt(NH3)(H2O)Cl2]
Write structures for geometrical isomers of diamminebromochloroplatinum (II).
Draw the structure of cis isomers of Pt(NH3)2Cl2.
The co-ordination number of Co3+ ion in the complex [Co(NH3)4Cl2]⊕ is ______.
Name the type of isomerism exhibited by the following pair of compounds:
[Co(NH3)5(ONO)]Cl2 and [Co(NH3)5(NO2)]Cl2
Three organic compounds A, B and C are non cyclic functional isomers of carbonyl compounds with molecular formula C4H8O. Isomers A and C give positive Tollen’s test while compound B does not give positive Tollen’s test but gives positive iodoform test. Compounds A and B on reduction with Zn amalgam and conc. HCl give the same product.
- Write the structures of the compounds A, B and C.
- Out of the compounds A, B and C, which one will be the least reactive towards addition of HCN.
Match List-I with List-II:
| List-I (Complex) |
List-II (Type of isomerism) |
| A. [Co(NH3)5(NO2)]Cl2 | I. Solvate isomerism |
| B. [Co(NH3)5(SO4)]Br | II. Linkage isomerism |
| C. [Co(NH3)6][Cr(CN)6] | III. Ionisation isomerism |
| D. [Co(H2O)6]Cl3 | IV. Coordination isomerism |
Choose the correct answer from the options given below:
