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महाराष्ट्र राज्य शिक्षण मंडळएचएससी विज्ञान (सामान्य) इयत्ता १२ वी

Write the name of isomerism in the following complexes: [Cu(NH3)4] [PtCl4] and [Pt(NH3)4] [ CuCl4] - Chemistry

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प्रश्न

Write the name of isomerism in the following complexes:

[Cu(NH3)4] [PtCl4] and [Pt(NH3)4] [ CuCl4]

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उत्तर

Both complexes exhibit coordination isomerism due to ligand exchange between cationic and anionic entities of distinct metal ions present in the complex.

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2021-2022 (March) Set 1

संबंधित प्रश्‍न

List various types of isomerism possible for coordination compounds, giving an example of each.


 Out of    and  , which one is optically active and why ?


Answer the following in one or two sentences.

Predict whether the [Cr(en)2(H2O)2]3+ complex is chiral. Write the structure of its enantiomer.


Answer in brief.

What are ionization isomers ? Give an example.


Answer the following question.

Draw isomers of the following

Ru(NH3)4Cl2


Draw structure of cis isomer of [Co(NH3)4Cl2]+


Which one of the following pairs represents linkage isomers?


Which one of the following complexes is not expected to exhibit isomerism?


Fac-mer isomerism is shown by


What is linkage isomerism? Explain with an example.


Explain optical isomerism in coordination compounds with an example.


What are hydrate isomers? Explain with an example.


Which of the following is NOT a pair of structural isomers?


How many isomers are possible for an alkane having molecular formula C5H12?


____________ isomers are formed when the ligand has two different donor atoms.


The formula of two complexes X and Y of chromium are given below:

\[\ce{\underset{(X)}{[Cr(H2O)6]Cl3}}\] and \[\ce{\underset{(Y)}{[Cr(H2O)5Cl]Cl2.H2O}}\]

X and Y are examples of ____________ isomers.


What type of isomerism is present between (I) [Cr(H2O)6]Cl3 and (II) [Cr(H2O)5Cl]Cl2.H2O?


Geometrical isomerism is not shown by


The correct structure of Fe(CO)5 is


Complex [COCl2(en)2]+ can 


Draw geometric isomers of the following complex.

Geometrical isomers of Pt(NH3)2Cl2


Which of the following are isostructural pairs?

(A) \[\ce{SO^{2-}4}\] and \[\ce{CrO^{2-}4}\]

(B) SiCl4 and TiCl4

(C) NH3 and \[\ce{NO^-3}\]

(D) BCl3 and BrCl3


The compounds [PtCl2(NH3)4]Br2 and [PtBr2(NH3)4]Cl2 constitutes a pair of ______.


Give cis isomer of [Co(NH3)4Cl2].


Match the pairs in column I (pairs of isomers) and column II (types of isomers)

Column I
(Pairs of isomers)
Column II
(Types of isomers)
(A) [Cr(H2O)5Cl]Cl2.H2O and [Cr(H2O)4Cl2]Cl.2H2O (i) Ionization isomers
(B) [Co(en)2(NO2)2]+ and [Co(en)2(ONO2)]+ (ii) Hydrate isomers
(C) [Co(NH3)6] [Cr(CN)6] and [Cr(NH3)6] [Co(CN)6] (iii) Linkage isomers
(D) [Pt(NH3)4Cl2] Br2 and [Pt(NH3)4Br2]Cl2 (iv) Coordination isomers

Draw the structure of trans isomers of Pt(NH3)2Cl2.


Name the type of isomerism exhibited by the following pair of compounds:

[Co(NH3)5(ONO)]Cl2 and [Co(NH3)5(NO2)]Cl2


Name the type of isomerism exhibited by the following pair of compounds:

[Cr(H2O)5Cl]Cl2.H2O and [Cr(H2O)4Cl2]Cl.2H2O


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