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प्रश्न
Write the name of isomerism in the following complexes:
[Cu(NH3)4] [PtCl4] and [Pt(NH3)4] [ CuCl4]
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उत्तर
Both complexes exhibit coordination isomerism due to ligand exchange between cationic and anionic entities of distinct metal ions present in the complex.
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संबंधित प्रश्न
Answer the following in one or two sentences.
Consider the complexes \[\ce{[Cu(NH3)4][PtCl4] and [Pt(NH3)4] [CuCl4]}\]. What type of isomerism these two complexes exhibit?
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Answer the following question.
Draw geometric isomers and enantiomers of the following complex.
[Pt(en)3]4⊕
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Explain optical isomerism in coordination compounds with an example.
The formula of two complexes X and Y of chromium are given below:
\[\ce{\underset{(X)}{[Cr(H2O)6]Cl3}}\] and \[\ce{\underset{(Y)}{[Cr(H2O)5Cl]Cl2.H2O}}\]
X and Y are examples of ____________ isomers.
Which of the following has zero dipole moment?
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Reason: Geometrical isomerism is not shown by complexes of coordination number 6.
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| (i) | (ii) |
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Which of the following compounds show optical isomerism?
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Match the pairs in column I (pairs of isomers) and column II (types of isomers)
| Column I (Pairs of isomers) |
Column II (Types of isomers) |
| (A) [Cr(H2O)5Cl]Cl2.H2O and [Cr(H2O)4Cl2]Cl.2H2O | (i) Ionization isomers |
| (B) [Co(en)2(NO2)2]+ and [Co(en)2(ONO2)]+ | (ii) Hydrate isomers |
| (C) [Co(NH3)6] [Cr(CN)6] and [Cr(NH3)6] [Co(CN)6] | (iii) Linkage isomers |
| (D) [Pt(NH3)4Cl2] Br2 and [Pt(NH3)4Br2]Cl2 | (iv) Coordination isomers |
The co-ordination number of Co3+ ion in the complex [Co(NH3)4Cl2]⊕ is ______.
Name the type of isomerism exhibited by the following pair of compounds:
[Co(NH3)5(ONO)]Cl2 and [Co(NH3)5(NO2)]Cl2
Name the type of isomerism exhibited by the following pair of compounds:
[Cr(H2O)5Cl]Cl2.H2O and [Cr(H2O)4Cl2]Cl.2H2O
Give a chemical test to show that \[\ce{[Co(NH3)5Cl]SO4}\] and \[\ce{[Co(NH3)5SO4]CI}\] are ionisation isomers.
Which one of the following complex ions has geometrical isomers?
Match List-I with List-II:
| List-I (Complex) |
List-II (Type of isomerism) |
| A. [Co(NH3)5(NO2)]Cl2 | I. Solvate isomerism |
| B. [Co(NH3)5(SO4)]Br | II. Linkage isomerism |
| C. [Co(NH3)6][Cr(CN)6] | III. Ionisation isomerism |
| D. [Co(H2O)6]Cl3 | IV. Coordination isomerism |
Choose the correct answer from the options given below:
