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प्रश्न
Write the name of isomerism in the following complexes:
[Cu(NH3)4] [PtCl4] and [Pt(NH3)4] [ CuCl4]
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उत्तर
Both complexes exhibit coordination isomerism due to ligand exchange between cationic and anionic entities of distinct metal ions present in the complex.
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संबंधित प्रश्न
List various types of isomerism possible for coordination compounds, giving an example of each.
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| Column I (Pairs of isomers) |
Column II (Types of isomers) |
| (A) [Cr(H2O)5Cl]Cl2.H2O and [Cr(H2O)4Cl2]Cl.2H2O | (i) Ionization isomers |
| (B) [Co(en)2(NO2)2]+ and [Co(en)2(ONO2)]+ | (ii) Hydrate isomers |
| (C) [Co(NH3)6] [Cr(CN)6] and [Cr(NH3)6] [Co(CN)6] | (iii) Linkage isomers |
| (D) [Pt(NH3)4Cl2] Br2 and [Pt(NH3)4Br2]Cl2 | (iv) Coordination isomers |
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[Co(NH3)5(ONO)]Cl2 and [Co(NH3)5(NO2)]Cl2
Name the type of isomerism exhibited by the following pair of compounds:
[Cr(H2O)5Cl]Cl2.H2O and [Cr(H2O)4Cl2]Cl.2H2O
