Advertisements
Advertisements
प्रश्न
What is linkage isomerism? Explain with an example.
Advertisements
उत्तर
Linkage isomers
Linkage isomerism arises when an ambidentate ligand is bonded to the central metal atom/ion through either of its two different donor atoms.
e.g. - [Co(NH3)5NO2]2+ Pentaammine nitrito-κN Cobalt (III) ion – N attached
[Co(NH3)5ONO2]2+ Pentaammine nitrito-κO Cobalt (III) ion – O attached
APPEARS IN
संबंधित प्रश्न
Choose the most correct option.
Which of the following complexes exist as cis and trans isomers?
1. [Cr(NH3)2Cl4]-
2. [Co(NH3)5Br]2⊕
3. [PtCl2Br2]2- (square planar)
4. [FeCl2(NCS)2]2- (tetrahedral)
Draw isomers of the following.
\[\ce{Pt(NH3)2ClNO2}\]
Draw the geometrical isomers of the following complexes [Pt(NH3)(H2O)Cl2].
Which would exhibit coordination isomerism?
Identify the CORRECT statement about the following complex of platinum.
[PtCl2(en)2]2+
Which of the following does NOT show optical isomerism?
Which of the following has an optical isomer?
Give trans isomer of [Co(NH3)4Cl2]⊕.
Name the type of isomerism exhibited by the following pair of compound:
\[\ce{[Pt(NH3)4Cl2]Br2 and [Pt(NH3)4 Br2]Cl2}\]
Give a chemical test to show that \[\ce{[Co(NH3)5Cl]SO4}\] and \[\ce{[Co(NH3)5SO4]CI}\] are ionisation isomers.
