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प्रश्न
Draw the geometrical isomers of the following complexes [Pt(NH3)(H2O)Cl2].
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उत्तर
Geometrical isomers of [Pt(NH3)(H2O)Cl2]:
Cis isomer Trans isomer
संबंधित प्रश्न
List various types of isomerism possible for coordination compounds, giving an example of each.
Why dextro and laevo rotatory isomers of Butan-2-ol are difficult to separate by fractional distillation?
Choose the most correct option.
Which of the following complexes exist as cis and trans isomers?
1. [Cr(NH3)2Cl4]-
2. [Co(NH3)5Br]2⊕
3. [PtCl2Br2]2- (square planar)
4. [FeCl2(NCS)2]2- (tetrahedral)
Answer in brief.
What are ionization isomers ? Give an example.
Draw isomers of the following.
\[\ce{Pt(NH3)2ClNO2}\]
Answer the following question.
Draw isomers of the following
Ru(NH3)4Cl2
Write the type of isomerism exhibited by [Co(NH3)5(NO2)]2+ and [Co(NH3)5ONO]2+ pair of complex ion.
Fac-mer isomerism is shown by
What is linkage isomerism? Explain with an example.
____________ isomers are formed when the ligand has two different donor atoms.
The complex ions [Co(H2O)5(ONO)]2+ and [Co(H2O)5NO2]2+ are ____________.
Complex [COCl2(en)2]+ can
Which of the following shows maximum number of isomers?
Which compound would exhibit optical isomers?
Which among the following solid is a non-polar solid?
Define Distereoisomers.
Give cis isomer of [Co(NH3)4Cl2]⊕.
Indicate the type of isomerism exhibited by the following complex and draw the structures for this isomer:
\[\ce{[Pt(NH3)(H2O)Cl2]}\]
Indicate the types of isomerism exhibited by the following complexes and draw the structures for these isomers: [Pt(NH3)(H2O)Cl2]
Explain the geometrical isomerism of the octahedral complex of the type [M(AA)2B2]n± with a suitable example.
What are structural isomers?
Draw the structure of cis isomers of Pt(NH3)2Cl2.
Three organic compounds A, B and C are non cyclic functional isomers of carbonyl compounds with molecular formula C4H8O. Isomers A and C give positive Tollen’s test while compound B does not give positive Tollen’s test but gives positive iodoform test. Compounds A and B on reduction with Zn amalgam and conc. HCl give the same product.
- Write the structures of the compounds A, B and C.
- Out of the compounds A, B and C, which one will be the least reactive towards addition of HCN.
Match List-I with List-II:
| List-I (Complex) |
List-II (Type of isomerism) |
| A. [Co(NH3)5(NO2)]Cl2 | I. Solvate isomerism |
| B. [Co(NH3)5(SO4)]Br | II. Linkage isomerism |
| C. [Co(NH3)6][Cr(CN)6] | III. Ionisation isomerism |
| D. [Co(H2O)6]Cl3 | IV. Coordination isomerism |
Choose the correct answer from the options given below:
