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महाराष्ट्र राज्य शिक्षण मंडळएचएससी विज्ञान (सामान्य) इयत्ता १२ वी

Answer the following question. Draw geometric isomers and enantiomers of the following complex.

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प्रश्न

Answer the following question.

Draw geometric isomers and enantiomers of the following complex.

[Pt(en)3]4⊕

थोडक्यात उत्तर
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उत्तर

[Pt(en)3]4+ shows only enantiomers as follows:

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पाठ 9: Coordination Compounds - Exercises [पृष्ठ २०८]

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बालभारती Chemistry [English] Standard 12 Maharashtra State Board
पाठ 9 Coordination Compounds
Exercises | Q 4.4 a. | पृष्ठ २०८

संबंधित प्रश्‍न

Why dextro and laevo rotatory isomers of Butan-2-ol are difficult to separate by fractional distillation?


Answer the following question.

Draw isomers of the following

[Cr(en2)Br2]


Answer the following question.

Draw geometric isomers and enantiomers of the following complex.

[Pt(en)2ClBr]2⊕


Draw optical isomers of [Co(en)3]3+.


Which one of the following will give a pair of enantiomorphs?


Explain optical isomerism in coordination compounds with an example.


The term anomers of glucose refer to ____________.


The compound(s) that exhibit(s) geometrical isomerism is (are):

(I) [Pt(en)Cl2]

(II) [Pt(en)2]Cl2

(III) [Pt(en)2Cl2]

(IV) [Pt(NH3)2Cl2]


Identify the CORRECT statement about the following complex of platinum.

[PtCl2(en)2]2+


Which of the following is NOT an isomer of n-hexane?


Which of the following does NOT show optical isomerism?


The formula of two complexes X and Y of chromium are given below:

\[\ce{\underset{(X)}{[Cr(H2O)6]Cl3}}\] and \[\ce{\underset{(Y)}{[Cr(H2O)5Cl]Cl2.H2O}}\]

X and Y are examples of ____________ isomers.


What type of isomerism is present between (I) [Cr(H2O)6]Cl3 and (II) [Cr(H2O)5Cl]Cl2.H2O?


Indicate the complex ion which shows geometrical isomerism.


Assertion: Complexes of MX6 and MX5L type (X and L are unidentate) do not show geometrical isomerism.

Reason: Geometrical isomerism is not shown by complexes of coordination number 6.


Complex [COCl2(en)2]+ can 


\[\ce{CH3CH2COO- Na+ ->[NaOH, + ?][Heat] CH3CH3 + Na2CO3}\]

Consider the above reaction and identify the missing reagent/chemical.


The number of geometrical isomers of \[\ce{[Co(NH3)3 (NO3)3]}\] are ______.


White precipitate of AgCl dissolves in aqueous ammonia solution due to formation of ______.


Indicate the types of isomerism exhibited by the following complexes and draw the structures for these isomers: [Pt(NH3)(H2O)Cl2]


Write structures for geometrical isomers of diamminebromochloroplatinum (II).


What are structural isomers?


Draw the structure of trans isomers of Pt(NH3)2Cl2.


The co-ordination number of Co3+ ion in the complex [Co(NH3)4Cl2] is ______.


Three organic compounds A, B and C are non cyclic functional isomers of carbonyl compounds with molecular formula C4H8O. Isomers A and C give positive Tollen’s test while compound B does not give positive Tollen’s test but gives positive iodoform test. Compounds A and B on reduction with Zn amalgam and conc. HCl give the same product.

  1. Write the structures of the compounds A, B and C.
  2. Out of the compounds A, B and C, which one will be the least reactive towards addition of HCN.

Match List-I with List-II:

List-I
(Complex)
List-II
(Type of isomerism)
A. [Co(NH3)5(NO2)]Cl2 I. Solvate isomerism
B. [Co(NH3)5(SO4)]Br II. Linkage isomerism
C. [Co(NH3)6][Cr(CN)6] III. Ionisation isomerism
D. [Co(H2O)6]Cl3 IV. Coordination isomerism

Choose the correct answer from the options given below:


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