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महाराष्ट्र राज्य शिक्षण मंडळएचएससी विज्ञान (सामान्य) इयत्ता १२ वी

Answer the following question. Draw geometric isomers and enantiomers of the following complex.

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प्रश्न

Answer the following question.

Draw geometric isomers and enantiomers of the following complex.

[Pt(en)3]4⊕

थोडक्यात उत्तर
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उत्तर

[Pt(en)3]4+ shows only enantiomers as follows:

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पाठ 9: Coordination Compounds - Exercises [पृष्ठ २०८]

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बालभारती Chemistry [English] Standard 12 Maharashtra State Board
पाठ 9 Coordination Compounds
Exercises | Q 4.4 a. | पृष्ठ २०८

संबंधित प्रश्‍न

List various types of isomerism possible for coordination compounds, giving an example of each.


Answer the following in one or two sentences.

Consider the complexes \[\ce{[Cu(NH3)4][PtCl4] and [Pt(NH3)4] [CuCl4]}\]. What type of isomerism these two complexes exhibit?


Answer in brief.

What are ionization isomers ? Give an example.


Draw isomers of the following.

\[\ce{Pt(NH3)2ClNO2}\]


Define the term Hydrated isomers.


Draw all possible geometrical isomers of the complex \[\ce{[Co(en)2Cl2]^+}\] and identify the optically active isomer.


Explain optical isomerism in coordination compounds with an example.


Which of the following is NOT a pair of structural isomers?


Identify the CORRECT statement about the following complex of platinum.

[PtCl2(en)2]2+


The number of geometrical isomers of [CrCl2(en)2]+ is ____________.


____________ isomers are formed when the ligand has two different donor atoms.


The formula of two complexes X and Y of chromium are given below:

\[\ce{\underset{(X)}{[Cr(H2O)6]Cl3}}\] and \[\ce{\underset{(Y)}{[Cr(H2O)5Cl]Cl2.H2O}}\]

X and Y are examples of ____________ isomers.


What is the number of moles of silver chloride precipitated when excess of aqueous silver nitrate is treated with [Co(NH3)4Cl2]Cl?


Indicate the complex ion which shows geometrical isomerism.


Assertion: Complexes of MX6 and MX5L type (X and L are unidentate) do not show geometrical isomerism.

Reason: Geometrical isomerism is not shown by complexes of coordination number 6.


The correct structure of Fe(CO)5 is


Which of the following has an optical isomer?


Draw geometric isomers of the following complex.

Geometrical isomers of Pt(NH3)2Cl2


The one that is not expected to show isomerism is ______.


The compounds [PtCl2(NH3)4]Br2 and [PtBr2(NH3)4]Cl2 constitutes a pair of ______.


Give cis isomer of [Co(NH3)4Cl2]⊕.


Give trans isomer of [Co(NH3)4Cl2]⊕.


Indicate the types of isomerism exhibited by the following complexes and draw the structures for these isomers: [Pt(NH3)(H2O)Cl2]


Match the pairs in column I (pairs of isomers) and column II (types of isomers)

Column I
(Pairs of isomers)
Column II
(Types of isomers)
(A) [Cr(H2O)5Cl]Cl2.H2O and [Cr(H2O)4Cl2]Cl.2H2O (i) Ionization isomers
(B) [Co(en)2(NO2)2]+ and [Co(en)2(ONO2)]+ (ii) Hydrate isomers
(C) [Co(NH3)6] [Cr(CN)6] and [Cr(NH3)6] [Co(CN)6] (iii) Linkage isomers
(D) [Pt(NH3)4Cl2] Br2 and [Pt(NH3)4Br2]Cl2 (iv) Coordination isomers

Draw the structure of trans isomers of Pt(NH3)2Cl2.


Name the type of isomerism exhibited by the following pair of compounds:

[Cr(H2O)5Cl]Cl2.H2O and [Cr(H2O)4Cl2]Cl.2H2O


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