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Answer the following question. Draw geometric isomers and enantiomers of the following complex. [Pt(en)2ClBr]2⊕

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प्रश्न

Answer the following question.

Draw geometric isomers and enantiomers of the following complex.

[Pt(en)2ClBr]2⊕

आकृती
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उत्तर

Geometric isomers of [Pt(en)2ClBr]2⊕:

Enantiomers of [Pt(en)2ClBr]2⊕:

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पाठ 9: Coordination Compounds - Exercises [पृष्ठ २०९]

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बालभारती Chemistry [English] Standard 12 Maharashtra State Board
पाठ 9 Coordination Compounds
Exercises | Q 4.4 b. | पृष्ठ २०९

संबंधित प्रश्‍न

Write the structural formula and IUPAC names of all possible isomers of the compound with molecular formula C3H8O.


 Out of    and  , which one is optically active and why ?


Choose the most correct option.

Which of the following complexes exist as cis and trans isomers?

1. [Cr(NH3)2Cl4]-

2. [Co(NH3)5Br]2⊕

3. [PtCl2Br2]2- (square planar)

4. [FeCl2(NCS)2]2- (tetrahedral)


Answer the following in one or two sentences.

Consider the complexes \[\ce{[Cu(NH3)4][PtCl4] and [Pt(NH3)4] [CuCl4]}\]. What type of isomerism these two complexes exhibit?


Draw isomers of the following.

\[\ce{Pt(NH3)2ClNO2}\]


Answer the following question.

Draw geometric isomers and enantiomers of the following complex.

[Pt(en)3]4⊕


Draw structure of cis isomer of [Co(NH3)4Cl2]+


Which one of the following will give a pair of enantiomorphs?


Which kind of isomerism is possible for a complex [Co(NH3)4Br2]Cl?


Which one of the following complexes is not expected to exhibit isomerism?


Draw all possible geometrical isomers of the complex \[\ce{[Co(en)2Cl2]^+}\] and identify the optically active isomer.


How many isomers are possible for an alkane having molecular formula C5H12?


The number of geometrical isomers of [CrCl2(en)2]+ is ____________.


Consider the two complexes given below:

\[\ce{\underset{(I)}{[Co(NH3)5SO4]Br}}\] and \[\ce{\underset{(II)}{[Co(NH3)5Br]SO4}}\]

I and II are ____________ isomers.


Which of the following is NOT an isomer of n-hexane?


The formula of two complexes X and Y of chromium are given below:

\[\ce{\underset{(X)}{[Cr(H2O)6]Cl3}}\] and \[\ce{\underset{(Y)}{[Cr(H2O)5Cl]Cl2.H2O}}\]

X and Y are examples of ____________ isomers.


What type of isomerism is present between (I) [Cr(H2O)6]Cl3 and (II) [Cr(H2O)5Cl]Cl2.H2O?


\[\ce{CH3CH2COO- Na+ ->[NaOH, + ?][Heat] CH3CH3 + Na2CO3}\]

Consider the above reaction and identify the missing reagent/chemical.


Which of the following compound is optically active?


Which compound would exhibit optical isomers?


The number of geometrical isomers of \[\ce{[Co(NH3)3 (NO3)3]}\] are ______.


Give cis isomer of [Co(NH3)4Cl2]⊕.


Give trans isomer of [Co(NH3)4Cl2]⊕.


Draw the geometrical isomers of the following complexes [Co(NH3)4Cl2]+


Draw the structure of trans isomers of Pt(NH3)2Cl2.


Name the type of isomerism exhibited by the following pair of compound:

\[\ce{[Pt(NH3)4Cl2]Br2  and  [Pt(NH3)4 Br2]Cl2}\]


Three organic compounds A, B and C are non cyclic functional isomers of carbonyl compounds with molecular formula C4H8O. Isomers A and C give positive Tollen’s test while compound B does not give positive Tollen’s test but gives positive iodoform test. Compounds A and B on reduction with Zn amalgam and conc. HCl give the same product.

  1. Write the structures of the compounds A, B and C.
  2. Out of the compounds A, B and C, which one will be the least reactive towards addition of HCN.

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