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Choose the most correct option. Which of the following complexes exist as cis and trans isomers? 1. [Cr(NH3)2Cl4]- 2. [Co(NH3)5Br]2⊕ 3. [PtCl2Br2]2- (square planar) 4. [FeCl2(NCS)2]2- (tetrahedral)

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प्रश्न

Choose the most correct option.

Which of the following complexes exist as cis and trans isomers?

1. [Cr(NH3)2Cl4]-

2. [Co(NH3)5Br]2⊕

3. [PtCl2Br2]2- (square planar)

4. [FeCl2(NCS)2]2- (tetrahedral)

पर्याय

  • 1 and 3

  • 2 and 3

  • 1 and 3

  • 4 only

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उत्तर

1 and 3

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पाठ 9: Coordination Compounds - Exercises [पृष्ठ २०७]

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बालभारती Chemistry [English] Standard 12 Maharashtra State Board
पाठ 9 Coordination Compounds
Exercises | Q 1.4 | पृष्ठ २०७

संबंधित प्रश्‍न

Write the structural formula and IUPAC names of all possible isomers of the compound with molecular formula C3H8O.


 Out of    and  , which one is optically active and why ?


Give one chemical test as an evidence to show that [Co (NH3)5Cl]  are ionisation isomers. 


Answer the following in one or two sentences.

Predict whether the [Cr(en)2(H2O)2]3+ complex is chiral. Write the structure of its enantiomer.


Answer the following question.

Draw geometric isomers and enantiomers of the following complex.

[Pt(en)3]4⊕


Answer the following question.

Draw geometric isomers and enantiomers of the following complex.

[Pt(en)2ClBr]2⊕


The pair [Co(NH3)5(SO4)]Br and [Co(NH3)5Br]SO4 exhibits ____________ isomerism


Define the term Co-ordination isomer.


Draw structure of cis isomer of [Co(NH3)4Cl2]+


Which type of isomerism is exhibited by [Pt(NH3)2Cl2]?


Which one of the following complexes is not expected to exhibit isomerism?


Fac-mer isomerism is shown by


What are hydrate isomers? Explain with an example.


Which would exhibit coordination isomerism?


The compound(s) that exhibit(s) geometrical isomerism is (are):

(I) [Pt(en)Cl2]

(II) [Pt(en)2]Cl2

(III) [Pt(en)2Cl2]

(IV) [Pt(NH3)2Cl2]


Identify the CORRECT statement about the following complex of platinum.

[PtCl2(en)2]2+


Which of the following does NOT show optical isomerism?


Which of the following has zero dipole moment?


Geometrical isomerism is not shown by


\[\ce{CH3CH2COO- Na+ ->[NaOH, + ?][Heat] CH3CH3 + Na2CO3}\]

Consider the above reaction and identify the missing reagent/chemical.


Which of the following are isostructural pairs?

(A) \[\ce{SO^{2-}4}\] and \[\ce{CrO^{2-}4}\]

(B) SiCl4 and TiCl4

(C) NH3 and \[\ce{NO^-3}\]

(D) BCl3 and BrCl3


Which compound would exhibit optical isomers?


The number of geometrical isomers of \[\ce{[Co(NH3)3 (NO3)3]}\] are ______.


The one that is not expected to show isomerism is ______.


Indicate the types of isomerism exhibited by the following complexes and draw the structures for these isomers: [Pt(NH3)(H2O)Cl2]


Explain the geometrical isomerism of the octahedral complex of the type [M(AA)2B2]with a suitable example.


Draw the structure of trans isomers of Pt(NH3)2Cl2.


Three organic compounds A, B and C are non cyclic functional isomers of carbonyl compounds with molecular formula C4H8O. Isomers A and C give positive Tollen’s test while compound B does not give positive Tollen’s test but gives positive iodoform test. Compounds A and B on reduction with Zn amalgam and conc. HCl give the same product.

  1. Write the structures of the compounds A, B and C.
  2. Out of the compounds A, B and C, which one will be the least reactive towards addition of HCN.

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