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प्रश्न
Choose the most correct option.
Which of the following complexes exist as cis and trans isomers?
1. [Cr(NH3)2Cl4]-
2. [Co(NH3)5Br]2⊕
3. [PtCl2Br2]2- (square planar)
4. [FeCl2(NCS)2]2- (tetrahedral)
पर्याय
1 and 3
2 and 3
1 and 3
4 only
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उत्तर
1 and 3
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संबंधित प्रश्न
Draw optical isomers of [Co(en)3]3+.
Which one of the following will give a pair of enantiomorphs?
Which type of isomerism is exhibited by [Pt(NH3)2Cl2]?
Which kind of isomerism is possible for a complex [Co(NH3)4Br2]Cl?
Which one of the following complexes is not expected to exhibit isomerism?
The compound(s) that exhibit(s) geometrical isomerism is (are):
(I) [Pt(en)Cl2]
(II) [Pt(en)2]Cl2
(III) [Pt(en)2Cl2]
(IV) [Pt(NH3)2Cl2]
The formula of two complexes X and Y of chromium are given below:
\[\ce{\underset{(X)}{[Cr(H2O)6]Cl3}}\] and \[\ce{\underset{(Y)}{[Cr(H2O)5Cl]Cl2.H2O}}\]
X and Y are examples of ____________ isomers.
Which of the following has zero dipole moment?
What is the number of moles of silver chloride precipitated when excess of aqueous silver nitrate is treated with [Co(NH3)4Cl2]Cl?
Complex [COCl2(en)2]+ can
Which of the following has an optical isomer?
Which of the following shows maximum number of isomers?
\[\ce{CH3CH2COO- Na+ ->[NaOH, + ?][Heat] CH3CH3 + Na2CO3}\]
Consider the above reaction and identify the missing reagent/chemical.
Draw geometric isomers of the following complex.
Geometrical isomers of Pt(NH3)2Cl2
Which of the following are isostructural pairs?
(A) \[\ce{SO^{2-}4}\] and \[\ce{CrO^{2-}4}\]
(B) SiCl4 and TiCl4
(C) NH3 and \[\ce{NO^-3}\]
(D) BCl3 and BrCl3
Which compound would exhibit optical isomers?
White precipitate of AgCl dissolves in aqueous ammonia solution due to formation of ______.
The one that is not expected to show isomerism is ______.
Give cis isomer of [Co(NH3)4Cl2]⊕.
Explain the geometrical isomerism of the octahedral complex of the type [M(AA)2B2]n± with a suitable example.
Match the pairs in column I (pairs of isomers) and column II (types of isomers)
| Column I (Pairs of isomers) |
Column II (Types of isomers) |
| (A) [Cr(H2O)5Cl]Cl2.H2O and [Cr(H2O)4Cl2]Cl.2H2O | (i) Ionization isomers |
| (B) [Co(en)2(NO2)2]+ and [Co(en)2(ONO2)]+ | (ii) Hydrate isomers |
| (C) [Co(NH3)6] [Cr(CN)6] and [Cr(NH3)6] [Co(CN)6] | (iii) Linkage isomers |
| (D) [Pt(NH3)4Cl2] Br2 and [Pt(NH3)4Br2]Cl2 | (iv) Coordination isomers |
Draw the geometrical isomers of the following complexes [Co(NH3)4Cl2]+
Draw the structure of cis isomers of Pt(NH3)2Cl2.
The co-ordination number of Co3+ ion in the complex [Co(NH3)4Cl2]⊕ is ______.
Name the type of isomerism exhibited by the following pair of compounds:
[Cr(H2O)5Cl]Cl2.H2O and [Cr(H2O)4Cl2]Cl.2H2O
Three organic compounds A, B and C are non cyclic functional isomers of carbonyl compounds with molecular formula C4H8O. Isomers A and C give positive Tollen’s test while compound B does not give positive Tollen’s test but gives positive iodoform test. Compounds A and B on reduction with Zn amalgam and conc. HCl give the same product.
- Write the structures of the compounds A, B and C.
- Out of the compounds A, B and C, which one will be the least reactive towards addition of HCN.
