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Answer the following in one or two sentences. Predict whether the [Cr(en)2(H2O)2]3+ complex is chiral. Write the structure of its enantiomer.

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प्रश्न

Answer the following in one or two sentences.

Predict whether the [Cr(en)2(H2O)2]3+ complex is chiral. Write the structure of its enantiomer.

टीपा लिहा
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उत्तर

i. The complex [Cr(en)2(H2O)2]3+ is chiral.

ii. Structures of enantiomers:

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पाठ 9: Coordination Compounds - Exercises [पृष्ठ २०८]

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बालभारती Chemistry [English] Standard 12 Maharashtra State Board
पाठ 9 Coordination Compounds
Exercises | Q 2.2 | पृष्ठ २०८

संबंधित प्रश्‍न

 Out of    and  , which one is optically active and why ?


Answer in brief.

What are ionization isomers ? Give an example.


Define the term Hydrated isomers.


Which one of the following will give a pair of enantiomorphs?


Which kind of isomerism is possible for a complex [Co(NH3)4Br2]Cl?


Which one of the following complexes is not expected to exhibit isomerism?


What are hydrate isomers? Explain with an example.


The compound(s) that exhibit(s) geometrical isomerism is (are):

(I) [Pt(en)Cl2]

(II) [Pt(en)2]Cl2

(III) [Pt(en)2Cl2]

(IV) [Pt(NH3)2Cl2]


Which of the following is NOT a pair of structural isomers?


Identify the CORRECT statement about the following complex of platinum.

[PtCl2(en)2]2+


The number of geometrical isomers of [CrCl2(en)2]+ is ____________.


The formula of two complexes X and Y of chromium are given below:

\[\ce{\underset{(X)}{[Cr(H2O)6]Cl3}}\] and \[\ce{\underset{(Y)}{[Cr(H2O)5Cl]Cl2.H2O}}\]

X and Y are examples of ____________ isomers.


What type of isomerism is present between (I) [Cr(H2O)6]Cl3 and (II) [Cr(H2O)5Cl]Cl2.H2O?


The relationship between compound (i) and (ii) is

(i) (ii)

Which of the following does not show optical isomerism?


Complex [COCl2(en)2]+ can 


Which of the following compounds show optical isomerism?


Which of the following has an optical isomer?


Which of the following shows maximum number of isomers?


Write the name of isomerism in the following complexes:

[Cu(NH3)4] [PtCl4] and [Pt(NH3)4] [ CuCl4]


Which compound would exhibit optical isomers?


Which among the following solid is a non-polar solid?


Define Distereoisomers.


Explain the geometrical isomerism of the octahedral complex of the type [M(AA)2B2]with a suitable example.


Match the pairs in column I (pairs of isomers) and column II (types of isomers)

Column I
(Pairs of isomers)
Column II
(Types of isomers)
(A) [Cr(H2O)5Cl]Cl2.H2O and [Cr(H2O)4Cl2]Cl.2H2O (i) Ionization isomers
(B) [Co(en)2(NO2)2]+ and [Co(en)2(ONO2)]+ (ii) Hydrate isomers
(C) [Co(NH3)6] [Cr(CN)6] and [Cr(NH3)6] [Co(CN)6] (iii) Linkage isomers
(D) [Pt(NH3)4Cl2] Br2 and [Pt(NH3)4Br2]Cl2 (iv) Coordination isomers

Draw the geometrical isomers of the following complexes [Co(NH3)4Cl2]+


Name the type of isomerism exhibited by the following pair of compounds:

[Cr(H2O)5Cl]Cl2.H2O and [Cr(H2O)4Cl2]Cl.2H2O


Match List-I with List-II:

List-I
(Complex)
List-II
(Type of isomerism)
A. [Co(NH3)5(NO2)]Cl2 I. Solvate isomerism
B. [Co(NH3)5(SO4)]Br II. Linkage isomerism
C. [Co(NH3)6][Cr(CN)6] III. Ionisation isomerism
D. [Co(H2O)6]Cl3 IV. Coordination isomerism

Choose the correct answer from the options given below:


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