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Answer the following in one or two sentences. Consider the complexes [Cu(NHA3)A4][PtClA4] and [Pt(NHA3)A4] [CuClA4]. What type of isomerism these two complexes exhibit?

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प्रश्न

Answer the following in one or two sentences.

Consider the complexes \[\ce{[Cu(NH3)4][PtCl4] and [Pt(NH3)4] [CuCl4]}\]. What type of isomerism these two complexes exhibit?

एका वाक्यात उत्तर
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उत्तर

The complex \[\ce{[Cu(NH3)4][PtCl4] and [Pt(NH3)4] [CuCl4]}\] exhibit coordination isomerism.

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पाठ 9: Coordination Compounds - Exercises [पृष्ठ २०८]

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बालभारती Chemistry [English] Standard 12 Maharashtra State Board
पाठ 9 Coordination Compounds
Exercises | Q 2.6 | पृष्ठ २०८

संबंधित प्रश्‍न

Give one chemical test as an evidence to show that [Co (NH3)5Cl]  are ionisation isomers. 


Why dextro and laevo rotatory isomers of Butan-2-ol are difficult to separate by fractional distillation?


Choose the most correct option.

Which of the following complexes exist as cis and trans isomers?

1. [Cr(NH3)2Cl4]-

2. [Co(NH3)5Br]2⊕

3. [PtCl2Br2]2- (square planar)

4. [FeCl2(NCS)2]2- (tetrahedral)


Answer the following question.

Draw isomers of the following

Ru(NH3)4Cl2


Answer the following question.

Draw geometric isomers and enantiomers of the following complex.

[Pt(en)2ClBr]2⊕


Write the type of isomerism exhibited by [Co(NH3)5(NO2)]2+ and [Co(NH3)5ONO]2+ pair of complex ion.


Which type of isomerism is exhibited by [Pt(NH3)2Cl2]?


How many geometrical isomers are possible for \[\ce{[Pt(Py)(NH3)(Br)(Cl)]}\]?


Which one of the following pairs represents linkage isomers?


Fac-mer isomerism is shown by


The compound(s) that exhibit(s) geometrical isomerism is (are):

(I) [Pt(en)Cl2]

(II) [Pt(en)2]Cl2

(III) [Pt(en)2Cl2]

(IV) [Pt(NH3)2Cl2]


Consider the two complexes given below:

\[\ce{\underset{(I)}{[Co(NH3)5SO4]Br}}\] and \[\ce{\underset{(II)}{[Co(NH3)5Br]SO4}}\]

I and II are ____________ isomers.


____________ isomers are formed when the ligand has two different donor atoms.


The relationship between compound (i) and (ii) is

(i) (ii)

Geometrical isomerism is not shown by


Which of the following shows maximum number of isomers?


The compounds [PtCl2(NH3)4]Br2 and [PtBr2(NH3)4]Cl2 constitutes a pair of ______.


Give cis isomer of [Co(NH3)4Cl2].


What are structural isomers?


Match the pairs in column I (pairs of isomers) and column II (types of isomers)

Column I
(Pairs of isomers)
Column II
(Types of isomers)
(A) [Cr(H2O)5Cl]Cl2.H2O and [Cr(H2O)4Cl2]Cl.2H2O (i) Ionization isomers
(B) [Co(en)2(NO2)2]+ and [Co(en)2(ONO2)]+ (ii) Hydrate isomers
(C) [Co(NH3)6] [Cr(CN)6] and [Cr(NH3)6] [Co(CN)6] (iii) Linkage isomers
(D) [Pt(NH3)4Cl2] Br2 and [Pt(NH3)4Br2]Cl2 (iv) Coordination isomers

Draw the structure of cis isomers of Pt(NH3)2Cl2.


The co-ordination number of Co3+ ion in the complex [Co(NH3)4Cl2] is ______.


Name the type of isomerism exhibited by the following pair of compounds:

[Co(NH3)5(ONO)]Cl2 and [Co(NH3)5(NO2)]Cl2


Name the type of isomerism exhibited by the following pair of compound:

\[\ce{[Pt(NH3)4Cl2]Br2  and  [Pt(NH3)4 Br2]Cl2}\]


Give a chemical test to show that \[\ce{[Co(NH3)5Cl]SO4}\] and \[\ce{[Co(NH3)5SO4]CI}\] are ionisation isomers.


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