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Draw optical isomers of [Co(en)3]3+. - Chemistry

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प्रश्न

Draw optical isomers of [Co(en)3]3+.

Write the structures of the optical isomers of [Co(en)3]3+.

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अध्याय 9: Coordination Compounds - Short Answer Questions (Type-II)

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एससीईआरटी महाराष्ट्र Chemistry [English] 12 Standard HSC
अध्याय 9 Coordination Compounds
Short Answer Questions (Type-II) | Q 6.2

संबंधित प्रश्न

Give one chemical test as an evidence to show that [Co (NH3)5Cl]  are ionisation isomers. 


Answer the following in one or two sentences.

Consider the complexes \[\ce{[Cu(NH3)4][PtCl4] and [Pt(NH3)4] [CuCl4]}\]. What type of isomerism these two complexes exhibit?


The pair [Co(NH3)5(SO4)]Br and [Co(NH3)5Br]SO4 exhibits ____________ isomerism


Draw structure of cis isomer of [Co(NH3)4Cl2]+


Which one of the following will give a pair of enantiomorphs?


Which one of the following pairs represents linkage isomers?


Which kind of isomerism is possible for a complex [Co(NH3)4Br2]Cl?


Draw all possible geometrical isomers of the complex \[\ce{[Co(en)2Cl2]^+}\] and identify the optically active isomer.


Explain optical isomerism in coordination compounds with an example.


The term anomers of glucose refer to ____________.


Identify the CORRECT statement about the following complex of platinum.

[PtCl2(en)2]2+


The number of geometrical isomers of [CrCl2(en)2]+ is ____________.


Which of the following does NOT show optical isomerism?


The complex ions [Co(H2O)5(ONO)]2+ and [Co(H2O)5NO2]2+ are ____________.


\[\ce{IUPAC}\] name of \[\ce{[Pt(NH3)2 Cl(NO2)]}\] is ______.


The relationship between compound (i) and (ii) is

(i) (ii)

Which of the following does not show optical isomerism?


Write the name of isomerism in the following complexes:

[Cu(NH3)4] [PtCl4] and [Pt(NH3)4] [ CuCl4]


Draw geometric isomers of the following complex.

Geometrical isomers of Pt(NH3)2Cl2


White precipitate of AgCl dissolves in aqueous ammonia solution due to formation of ______.


Give cis isomer of [Co(NH3)4Cl2].


Indicate the types of isomerism exhibited by the following complexes and draw the structures for these isomers: [Pt(NH3)(H2O)Cl2]


Write structures for geometrical isomers of diamminebromochloroplatinum (II).


What are structural isomers?


Match the pairs in column I (pairs of isomers) and column II (types of isomers)

Column I
(Pairs of isomers)
Column II
(Types of isomers)
(A) [Cr(H2O)5Cl]Cl2.H2O and [Cr(H2O)4Cl2]Cl.2H2O (i) Ionization isomers
(B) [Co(en)2(NO2)2]+ and [Co(en)2(ONO2)]+ (ii) Hydrate isomers
(C) [Co(NH3)6] [Cr(CN)6] and [Cr(NH3)6] [Co(CN)6] (iii) Linkage isomers
(D) [Pt(NH3)4Cl2] Br2 and [Pt(NH3)4Br2]Cl2 (iv) Coordination isomers

Draw the structure of cis isomers of Pt(NH3)2Cl2.


Give a chemical test to show that \[\ce{[Co(NH3)5Cl]SO4}\] and \[\ce{[Co(NH3)5SO4]CI}\] are ionisation isomers.


Three organic compounds A, B and C are non cyclic functional isomers of carbonyl compounds with molecular formula C4H8O. Isomers A and C give positive Tollen’s test while compound B does not give positive Tollen’s test but gives positive iodoform test. Compounds A and B on reduction with Zn amalgam and conc. HCl give the same product.

  1. Write the structures of the compounds A, B and C.
  2. Out of the compounds A, B and C, which one will be the least reactive towards addition of HCN.

Match List-I with List-II:

List-I
(Complex)
List-II
(Type of isomerism)
A. [Co(NH3)5(NO2)]Cl2 I. Solvate isomerism
B. [Co(NH3)5(SO4)]Br II. Linkage isomerism
C. [Co(NH3)6][Cr(CN)6] III. Ionisation isomerism
D. [Co(H2O)6]Cl3 IV. Coordination isomerism

Choose the correct answer from the options given below:


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