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Draw optical isomers of [Co(en)3]3+.

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प्रश्न

Draw optical isomers of [Co(en)3]3+.

Write the structures of the optical isomers of [Co(en)3]3+.

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अध्याय 9: Coordination Compounds - Short Answer Questions (Type-II)

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संबंधित प्रश्न

Write the structural formula and IUPAC names of all possible isomers of the compound with molecular formula C3H8O.


List various types of isomerism possible for coordination compounds, giving an example of each.


 Out of    and  , which one is optically active and why ?


Choose the most correct option.

Which of the following complexes exist as cis and trans isomers?

1. [Cr(NH3)2Cl4]-

2. [Co(NH3)5Br]2⊕

3. [PtCl2Br2]2- (square planar)

4. [FeCl2(NCS)2]2- (tetrahedral)


Answer the following in one or two sentences.

Predict whether the [Cr(en)2(H2O)2]3+ complex is chiral. Write the structure of its enantiomer.


The pair [Co(NH3)5(SO4)]Br and [Co(NH3)5Br]SO4 exhibits ____________ isomerism


Define the term Hydrated isomers.


Draw the geometrical isomers of the following complexes [Pt(NH3)(H2O)Cl2].


How many geometrical isomers are possible for \[\ce{[Pt(Py)(NH3)(Br)(Cl)]}\]?


Fac-mer isomerism is shown by


Explain optical isomerism in coordination compounds with an example.


Which of the following is NOT a pair of structural isomers?


The complex ions [Co(H2O)5(ONO)]2+ and [Co(H2O)5NO2]2+ are ____________.


The formula of two complexes X and Y of chromium are given below:

\[\ce{\underset{(X)}{[Cr(H2O)6]Cl3}}\] and \[\ce{\underset{(Y)}{[Cr(H2O)5Cl]Cl2.H2O}}\]

X and Y are examples of ____________ isomers.


Assertion: Complexes of MX6 and MX5L type (X and L are unidentate) do not show geometrical isomerism.

Reason: Geometrical isomerism is not shown by complexes of coordination number 6.


Geometrical isomerism is not shown by


Which of the following compounds show optical isomerism?


Which of the following has an optical isomer?


\[\ce{CH3CH2COO- Na+ ->[NaOH, + ?][Heat] CH3CH3 + Na2CO3}\]

Consider the above reaction and identify the missing reagent/chemical.


Write the name of isomerism in the following complexes:

[Cu(NH3)4] [PtCl4] and [Pt(NH3)4] [ CuCl4]


The compounds [PtCl2(NH3)4]Br2 and [PtBr2(NH3)4]Cl2 constitutes a pair of ______.


Define Distereoisomers.


Draw the structure of cis isomers of Pt(NH3)2Cl2.


Name the type of isomerism exhibited by the following pair of compounds:

[Cr(H2O)5Cl]Cl2.H2O and [Cr(H2O)4Cl2]Cl.2H2O


Give a chemical test to show that \[\ce{[Co(NH3)5Cl]SO4}\] and \[\ce{[Co(NH3)5SO4]CI}\] are ionisation isomers.


Three organic compounds A, B and C are non cyclic functional isomers of carbonyl compounds with molecular formula C4H8O. Isomers A and C give positive Tollen’s test while compound B does not give positive Tollen’s test but gives positive iodoform test. Compounds A and B on reduction with Zn amalgam and conc. HCl give the same product.

  1. Write the structures of the compounds A, B and C.
  2. Out of the compounds A, B and C, which one will be the least reactive towards addition of HCN.

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