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Science (English Medium) कक्षा १२ - CBSE Question Bank Solutions for Chemistry

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Chemistry
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Value of standard electrode potential for the oxidation of \[\ce{Cl-}\] ions is more positive than that of water, even then in the electrolysis of aqueous sodium chloride, why is \[\ce{Cl-}\] oxidised at anode instead of water?

[2] Electrochemistry
Chapter: [2] Electrochemistry
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Which reference electrode is used to measure the electrode potential of other electrodes?

[2] Electrochemistry
Chapter: [2] Electrochemistry
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Assertion: Cu is less reactive than hydrogen.

Reason: `E_((Cu^(2+))/(Cu))^Θ` is negative.

[2] Electrochemistry
Chapter: [2] Electrochemistry
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Consider the figure and answer the following question.

If cell ‘A’ has ECell = 0.5V and cell ‘B’ has ECell = 1.1V then what will be the reactions at anode and cathode?

[2] Electrochemistry
Chapter: [2] Electrochemistry
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At high pressure the following reaction is zero order.

\[\ce{2NH3(g) ->[1130 K][Platinum catalyst] N2(g) + 3H2(g)}\]

Which of the following options are correct for this reaction?

(i) Rate of reaction = Rate constant.

(ii) Rate of the reaction depends on concentration of ammonia.

(iii) Rate of decomposition of ammonia will remain constant until ammonia disappears completely.

(iv) Further increase in pressure will change the rate of reaction.

[3] Chemical Kinetics
Chapter: [3] Chemical Kinetics
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Which of the following graphs is correct for a zero order reaction?

[3] Chemical Kinetics
Chapter: [3] Chemical Kinetics
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Write the rate equation for the reaction `2A + B -> C` if the order of the reaction is zero.

[3] Chemical Kinetics
Chapter: [3] Chemical Kinetics
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Derive an expression to calculate time required for completion of zero order reaction.

[3] Chemical Kinetics
Chapter: [3] Chemical Kinetics
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For a zero order reaction will the molecularity be equal to zero? Explain.

[3] Chemical Kinetics
Chapter: [3] Chemical Kinetics
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Arrange the following diagrams in correct sequence of steps involved in the mechanism of catalysis, in accordance with modern adsorption theory.


                    (a)


             (b)


           (c)


               (d)


               (e)

[5] Surface Chemistry
Chapter: [5] Surface Chemistry
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In qualitative analysis when \[\ce{H2S}\] is passed through an aqueous solution of salt acidified with dil. \[\ce{HCl}\], a black precipitate is obtained. On boiling the precipitate with dil. \[\ce{HNO3}\], it forms a solution of blue colour. Addition of excess of aqueous solution of ammonia to this solution gives ______.

[7] P - Block Elements
Chapter: [7] P - Block Elements
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A brown ring is formed in the ring test for \[\ce{NO3^{-}}\] ion. It is due to the formation of ______.

[7] P - Block Elements
Chapter: [7] P - Block Elements
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In the preparation of HNO3, we get NO gas by catalytic oxidation of ammonia. The moles of NO produced by the oxidation of two moles of NH3 will be ______.

[7] P - Block Elements
Chapter: [7] P - Block Elements
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\[\ce{PCl5}\] reacts with finely divided silver on heating and a white silver salt is obtained, which dissolves on adding excess aqueous \[\ce{NH3}\] solution. Write the reactions involved to explain what happens.

[7] P - Block Elements
Chapter: [7] P - Block Elements
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The electronic configuration of \[\ce{Cu(II)}\] is 3d9 whereas that of \[\ce{Cu(I)}\] is 3d10. Which of the following is correct?

[4] d-block and f-block Elements
Chapter: [4] d-block and f-block Elements
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Which of the following complexes formed by \[\ce{Cu^2+}\] ions is most stable?

[5] Coordination Compounds
Chapter: [5] Coordination Compounds
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When 0.1 mol \[\ce{CoCl3 (NH3)5}\] is treated with excess of \[\ce{AgNO3}\], 0.2 mol of \[\ce{AgCl}\] are obtained. The conductivity of solution will correspond to ______.

[5] Coordination Compounds
Chapter: [5] Coordination Compounds
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When 1 mol \[\ce{CrCl3.6H2O}\] is treated with excess of \[\ce{AgNO3}\], 3 mol of \[\ce{AgCl}\] are obtained. The formula of the complex is ______.

[5] Coordination Compounds
Chapter: [5] Coordination Compounds
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The correct \[\ce{IUPAC}\] name of \[\ce{[Pt(NH3)2Cl2]}\] is ______.

[5] Coordination Compounds
Chapter: [5] Coordination Compounds
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The stabilisation of coordination compounds due to chelation is called the chelate effect. Which of the following is the most stable complex species?

[5] Coordination Compounds
Chapter: [5] Coordination Compounds
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