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प्रश्न
Consider the figure and answer the following question.
If cell ‘A’ has ECell = 0.5V and cell ‘B’ has ECell = 1.1V then what will be the reactions at anode and cathode?
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उत्तर
Now cell ‘B’ acts as galvanic cell as it has higher emf and will push electrons into cell ‘A’.
The electrode reaction will be:
At anode: \[\ce{Zn -> Zn^{2+} + 2e^{-}}\]
At cathode: \[\ce{Cu^{2+} + 2e^{-} -> Cu}\]
APPEARS IN
संबंधित प्रश्न
Draw a neat and well labelled diagram of primary reference electrode.
Arrange the following reducing agents in the order of increasing strength under standard state conditions. Justify the answer
|
Element |
Al(s) |
Cu(s) |
Cl(aq) |
Ni(s) |
|
Eo |
-1.66V |
0.34V |
1.36V |
-0.26V |
Can copper sulphate solution be stored in an iron vessel? Explain.
The standard e.m.f of the following cell is 0.463 V
`Cu|Cu_(1m)^(++)`
What is the standard potential of Cu electrode?
(A) 1.137 V
(B) 0.337 V
(C) 0.463 V
(D) - 0.463 V
Calculate E°cell for the following reaction at 298 K:
2Al(s) + 3Cu+2(0.01M) → 2Al+3(0.01M) + 3Cu(s)
Given: Ecell = 1.98V
Calculate e.m.f of the following cell at 298 K:
2Cr(s) + 3Fe2+ (0.1M) → 2Cr3+ (0.01M) + 3 Fe(s)
Given: E°(Cr3+ | Cr) = – 0.74 VE° (Fe2+ | Fe) = – 0.44 V
Calculate emf of the following cell at 25 °C :
Fe|Fe2+(0.001 M)| |H+(0.01 M)|H2(g) (1 bar)|Pt (s)
E°(Fe2+| Fe)= −0.44 V E°(H+ | H2) = 0.00 V
Depict the galvanic cell in which the reaction \[\ce{Zn(s) + 2Ag+(aq) → Zn^{2+}(aq) + 2Ag(s)}\] takes place. Further show:
- Which of the electrode is negatively charged?
- The carriers of the current in the cell.
- Individual reaction at each electrode.
In the representation of the galvanic cell, the ions in the same phase are separated by a _______.
Calculate the emf of the following cell at 25°C :
Standard electrode potential is measured taking the concentrations of all the species involved in a half-cell is ____________.
Which cell will measure standard electrode potential of copper electrode?
Value of standard electrode potential for the oxidation of \[\ce{Cl-}\] ions is more positive than that of water, even then in the electrolysis of aqueous sodium chloride, why is \[\ce{Cl-}\] oxidised at anode instead of water?
Which reference electrode is used to measure the electrode potential of other electrodes?
The standard electrode potential of the two half cells are given below:
\[\ce{Ni^{2+} + 2e^{-} -> Ni, E_0 = - 0.25 Volt}\]
\[\ce{Zn^{2+} + 2e^{-} -> Zn, E_0 = - 0.77 Volt}\]
The voltage of cell formed by combining the two half cells would be?
A voltaic cell is made by connecting two half cells represented by half equations below:
\[\ce{Sn^{2+}_{ (aq)} + 2e^- -> Sn_{(s)}}\], E0 = − 0.14 V
\[\ce{Fe^{3+}_{ (aq)} + e^- -> Fe^{2+}_{ (aq)}}\], E0 = + 0.77 V
Which statement is correct about this voltaic cell?
