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Which reference electrode is used to measure the electrode potential of other electrodes? - Chemistry

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प्रश्न

Which reference electrode is used to measure the electrode potential of other electrodes?

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उत्तर

Standard hydrogen electrode is the reference electrode whose electrode potential is taken to be zero. The electrode potential of other electrodes is measured with respect to it.

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अध्याय 3: Electrochemistry - Exercises [पृष्ठ ४०]

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एनसीईआरटी एक्झांप्लर Chemistry [English] Class 12
अध्याय 3 Electrochemistry
Exercises | Q III. 44. | पृष्ठ ४०

संबंधित प्रश्न

Draw a neat and well labelled diagram of primary reference electrode.


Arrange the following reducing agents in the order of increasing strength under standard state conditions. Justify the answer 

Element

Al(s)

Cu(s)

Cl(aq)

Ni(s)

 

Eo

-1.66V

0.34V

1.36V

-0.26V

 


Calculate Ecell and ΔG for the following at 28°C :

Mg(s) + Sn2+( 0.04M ) → Mg2+( 0.06M ) + Sn(s)

cell = 2.23V. Is the reaction spontaneous ?


Calculate emf of the following cell at 25°C:

\[\ce{Sn/Sn^2+ (0.001 M) || H+ (0.01 M) | H2_{(g)} (1 bar) | Pt_{(s)}}\]

Given: \[\ce{E^\circ(Sn^2+/sn) = -0.14 V, E^\circ H+/H2 = 0.00 V (log 10 = 1)}\]


Calculate e.m.f of the following cell at 298 K:

2Cr(s) + 3Fe2+ (0.1M) → 2Cr3+ (0.01M) + 3 Fe(s)

Given: E°(Cr3+ | Cr) = – 0.74 VE° (Fe2+ | Fe) = – 0.44 V


 
 

Calculate e.m.f. and ∆G for the following cell:

Mg (s) |Mg2+ (0.001M) || Cu2+ (0.0001M) | Cu (s)

`"Given :" E_((Mg^(2+)"/"Mg))^0=−2.37 V, E_((Cu^(2+)"/"Cu))^0=+0.34 V.`

 

 
 

Draw a neat and labelled diagram of the lead storage battery.


Calculate the emf of the following cell at 25°C :

\[{E^0}_\left( {Zn}^{2 +} /Zn \right) = - 0 . 76 V, {E^0}_\left( H^+ / H_2 \right) = 0 . 00 V\]

 


Galvanic or a voltaic cell converts the chemical energy liberated during a redox reaction to ____________.


Standard hydrogen electrode operated under standard conditions of 1 atm Hpressure, 298 K, and pH = 0 has a cell potential of ____________.


Which cell will measure standard electrode potential of copper electrode?


The difference between the electrode potentials of two electrodes when no current is drawn through the cell is called ______.


Using the data given below find out the strongest reducing agent.

`"E"_("Cr"_2"O"_7^(2-)//"Cr"^(3+))^⊖` = 1.33 V  `"E"_("Cl"_2//"Cl"^-) = 1.36` V

`"E"_("MnO"_4^-//"Mn"^(2+))` = 1.51 V  `"E"_("Cr"^(3+)//"Cr")` = - 0.74 V


Use the data given in below find out which of the following is the strongest oxidising agent.

`"E"_("Cr"_2"O"_7^(2-)//"Cr"^(3+))^⊖`= 1.33 V `"E"_("Cl"_2//"Cl"^-)^⊖` = 1.36 V

`"E"_("MnO"_4^-//"Mn"^(2+))^⊖` = 1.51 V `"E"_("Cr"^(3+)//"Cr")^⊖` = - 0.74 V


Assertion: Cu is less reactive than hydrogen.

Reason: `E_((Cu^(2+))/(Cu))^Θ` is negative.


Which is the correct order of second ionization potential of C, N, O and F in the following?


Standard electrode potential of three metals X, Y and Z are –1.2 V, +0.5 V and –3.0 V, respectively. The reducing power of these metals will be ______.


The emf of a galvanic cell, with electrode potential of Zn2+ = - 0.76 V and that of Cu2+ = 0.34 V, is ______.


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