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HSC Science (General) १२ वीं कक्षा - Maharashtra State Board Important Questions for Chemistry

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Chemistry
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Identify the product ‘D’ in the following sequence of reactions:

\[\ce{H3C - CH2 - CH2 - Cl \underset{KOH}{\overset{Alc}{->}} 'B' \overset{HBr}{->} 'C' \underset{Elther}{\overset{Na}{->}}'D'}\]

Appears in 1 question paper
Chapter: [10.01] Haloalkanes
Concept: Hydrocarbons: Alkanes >> Reactions of Haloalkanes - Elimination Reactions

Identify ‘A’ and ‘B’ in the following reaction :

\[\ce{CH3 - CH = CH2 ->[HBr]'A' ->[alc.KOH]'B'}\]

Appears in 1 question paper
Chapter: [10.01] Haloalkanes
Concept: Hydrocarbons: Alkanes >> Reactions of Haloalkanes - Elimination Reactions

Discuss the mechanism of alkaline hydrolysis of bromomethane.

Appears in 1 question paper
Chapter: [10.01] Haloalkanes
Concept: Hydrocarbons: Alkanes >> Reactions of Haloalkanes - Nucleophilic Substitution Reactions

State and explain Markownikoff's rule with suitable example

Appears in 1 question paper
Chapter: [10.01] Haloalkanes
Concept: Hydrocarbons: Alkanes >> Reactions of Haloalkanes - Elimination Reactions

which of the following carbocations is least stable?

(A) 

(B)

(C)

(D)

 

 

Appears in 1 question paper
Chapter: [10.01] Haloalkanes
Concept: Introduction to Haloalkanes and Haloarenes >> Nature of C-X Bond

What is the action of bromine in alkaline medium on

i. CH3CH2NO2

ii. 

Appears in 1 question paper
Chapter: [10.01] Haloalkanes
Concept: Methods of Preparation of Haloalkanes and Haloarenes

The stability order for carbocation is _______.

(A) 2° > 3° > 1° 

(B) 3° > 2° > 1°

(C) 3° > 1° > 2°

(D) 1° > 3° > 2°

Appears in 1 question paper
Chapter: [10.01] Haloalkanes
Concept: Hydrocarbons: Alkanes >> Reactions of Haloalkanes - Nucleophilic Substitution Reactions

How are the following conversions carried out?

2-methylbutan-1-ol into 2 -methylbutanoic acid.

Appears in 1 question paper
Chapter: [10.01] Haloalkanes
Concept: Introduction to Haloalkanes and Haloarenes >> Nomenclature

But-1-ene on reaction with HCl in the presence of sodium peroxide yields _______.

Appears in 1 question paper
Chapter: [10.01] Haloalkanes
Concept: Introduction to Haloalkanes and Haloarenes >> Nomenclature

IUPAC name of is C6H5 − CH2 − C − CH2 − CH2 − CH2 − CH3 is _______

(A) 1-Phenylhexan-2-one

(B) 6-Phenylhexan-5-one

(C) 1-Benzylhexan-5-one

(D) Dodecan-5-one

Appears in 1 question paper
Chapter: [10.01] Haloalkanes
Concept: Introduction to Haloalkanes and Haloarenes >> Nomenclature

How is nitromethane prepared from the following?

alkyl halide

Appears in 1 question paper
Chapter: [10.01] Haloalkanes
Concept: Introduction to Haloalkanes and Haloarenes >> Nomenclature

How is nitromethane prepared from the following?

α-nitroalkene

Appears in 1 question paper
Chapter: [10.01] Haloalkanes
Concept: Introduction to Haloalkanes and Haloarenes >> Nomenclature

Draw a neat, labelled energy profile diagram for SN1 reaction mechanism.

Appears in 1 question paper
Chapter: [10.01] Haloalkanes
Concept: Hydrocarbons: Alkanes >> Reactions of Haloalkanes - Elimination Reactions

Identify 'A' in the following reaction -

(a) 2- Bromo-2 methylbutane

(b) 1 -Bromo-2,2-dimethylpropane

(c) 1 - Bromo - 3 -methylbutane

(d) 1 - Bromo- 2 -methylpropane

Appears in 1 question paper
Chapter: [10.01] Haloalkanes
Concept: Hydrocarbons: Alkanes >> Reactions of Haloalkanes - Nucleophilic Substitution Reactions

Complete and rewrite the balanced chemical equations

Appears in 1 question paper
Chapter: [10.01] Haloalkanes
Concept: Introduction to Haloalkanes and Haloarenes >> Nomenclature

What is the action of the following on ethyl bromide
alcoholic solution of potassium hydroxide.

Appears in 1 question paper
Chapter: [10.01] Haloalkanes
Concept: Hydrocarbons: Alkanes >> Reactions of Haloalkanes - Nucleophilic Substitution Reactions

What is the action of the following on ethyl bromide:
moist silver oxide

Appears in 1 question paper
Chapter: [10.01] Haloalkanes
Concept: Hydrocarbons: Alkanes >> Reactions of Haloalkanes - Nucleophilic Substitution Reactions

Write a short note on Sandmeyer’s reaction. 

Appears in 1 question paper
Chapter: [10.01] Haloalkanes
Concept: Methods of Preparation of Haloalkanes and Haloarenes

What are racemates?

Appears in 1 question paper
Chapter: [10.01] Haloalkanes
Concept: Hydrocarbons: Alkanes >> Reactions of Haloalkanes - Elimination Reactions

Observe the following compounds and answer the questions given below.


      (I)

\[\ce{\underset{\text{(II)}}{CH3 - CH2 - Br}}\]

  1. Identify the type of halides.
  2. Explain the nature of the C – Br bond in both of these halides.
  3. Which of these compounds will undergo aqueous alkaline hydrolysis readily? Write the reaction in support of your answer.
Appears in 1 question paper
Chapter: [10.01] Haloalkanes
Concept: Hydrocarbons: Alkanes >> Reactions of Haloalkanes - Elimination Reactions
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