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What is the action of following on phenol at low temperature? dil. HNO3 conc. H2SO4 Br2/CS2

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प्रश्न

What is the action of following on phenol at low temperature?

  1. dil. HNO3
  2. conc. H2SO4
  3. Br2/CS2
संक्षेप में उत्तर
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उत्तर

  1. Dilute HNO3: Phenol reacts with dilute nitric acid at low temperature to give a mixture of ortho- and para-nitrophenol.
  2. Conc. H2SO4: At room temperature (298 K), phenol reacts with concentrated sulphuric acid to form o-phenolsulphonic acid.
  3. Br2 in CS2: When a reaction is carried out in a solvent of lower polarity like CS2 a mixture of ortho- and para-bromophenol is formed.
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अध्याय 11: Alcohols, Phenols and Ethers - Short Answer Questions (Type-II)

संबंधित प्रश्न

Write two points of difference between the properties of phenol and ethyl alcohol.


Answer in brief.

Give the reagents and conditions necessary to prepare phenol from Benzene sulfonic acid.


An ether (A), C5H12O, when heated with excess of hot HI produce two alkyl halides which on hydrolysis form compound (B) and (C), oxidation of (B) gave and acid (D), whereas oxidation of (C) gave a ketone (E). Deduce the structural formula of (A), (B), (C), (D), and (E).


When vapours of tert.butyl alcohol are passed over hot copper, it gives _____________


Reaction between hot conc. HI and anisole gives ______________


Arrange the following in decreasing order of acid strength.

CH3OH, CH3–CH2–OH, CH3–CH(OH)–CH3, (CH3)3–C–OH


Draw intramolecular hydrogen bonding structure in o-nitrophenol.


Write Kolbe’s reaction.


How will you bring about the following conversions?

acetone to 2-methylpropan-2-ol


Write the reactions for the preparation of carbolic acid from aniline.


Bromination of phenol, will NOT give:


Phenol is ____________.


Isobutylene on hydroboration followed by oxidation with hydrogen peroxide in presence of base yields ______.


Propane when treated with cold cone. H2SO4 forms a compound which on heating with water gives ______.


What is the product of the following reaction?

\[\ce{CH3 - CH2 - CH2 - OH ->[conc. H2SO4][\Delta]}\]


Sodium benzene sulphonate reacts with NaOH and then on acidic hydrolysis, it gives __________.


\[\ce{Isopropyl alcohol + acidic K2Cr2O7 -> X}\]

Identify product 'X' in the above reactions.


Identify the product B in following conversion.

\[\ce{Chlorobenzene + H2O ->[Cu, 673 K][Pressure] A ->[conc. H2SO4][373 K] B}\]


Which of the following alcohols is least soluble in water?


Identify 'Z' in the following series of reaction:

\[\ce{Butan - 2 - ol ->[PCl3] X ->[alco. KOH] Y ->[i) H2SO4][ii) H-OH/heat] Z}\]


Identify the compound having highest boiling point from the following?


Identify the role of PDC from the following.


Identify the product X in the following reaction.

\[\ce{Phenol ->[Na2Cr2O7][H2SO4] X}\]


Which of the following compounds has lowest boiling point?


What is the product formed when aniline is treated with \[\ce{NaNO2 + HCl}\] previous to hydrolysis?


What is the product obtained in Reimer - Tiemann reaction?


Arrange the following compounds in an increasing order of their solubility in water:


Write the chemical reaction when hot copper is treated with Vapours of 2° (secondary) alcohol.


What is the commercial method of preparation of phenol?


The structure of A in the given reaction is:


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