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प्रश्न
What is the action of following on phenol at low temperature?
- dil. HNO3
- conc. H2SO4
- Br2/CS2
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उत्तर
- Dilute HNO3: Phenol reacts with dilute nitric acid at low temperature to give a mixture of ortho- and para-nitrophenol.

- Conc. H2SO4: At room temperature (298 K), phenol reacts with concentrated sulphuric acid to form o-phenolsulphonic acid.

- Br2 in CS2: When a reaction is carried out in a solvent of lower polarity like CS2 a mixture of ortho- and para-bromophenol is formed.

संबंधित प्रश्न
Choose the correct option.
Which is the most resistant alcohol towards oxidation reaction among the following?
Answer in one sentence/ word.
Write the IUPAC name of alcohol having molecular formula C4H10O which is resistant towards oxidation.
Answer in brief.
Explain why phenol is more acidic than ethyl alcohol.
Answer in brief.
Give a simple chemical test to distinguish between ethanol and ethyl bromide.
An ether (A), C5H12O, when heated with excess of hot HI produce two alkyl halides which on hydrolysis form compound (B) and (C), oxidation of (B) gave and acid (D), whereas oxidation of (C) gave a ketone (E). Deduce the structural formula of (A), (B), (C), (D), and (E).
Reaction between hot conc. HI and anisole gives ______________
The reagents used to convert phenol to 2,4,6-tribromophenol is _____________
Draw intramolecular hydrogen bonding structure in o-nitrophenol.
Name the reagents used to convert phenol into
- picric acid
- p-benzoquinone
An organic compound gives hydrogen on reaction with sodium metal. It forms an aldehyde with molecular formula C2H4O on oxidation with pyridinium chlorochromate. Give the chemical equations in support of these observations.
Number of oxygen atoms present in salicylaldehyde are ______.
Isobutylene on hydroboration followed by oxidation with hydrogen peroxide in presence of base yields ______.
\[\ce{CH3 - CH = CH2 ->[HBr][Peroxide] A}\]
Identify A.
Carbolic acid is oxidised by acidified sodium dichromate to give ______.
In Dow process, chlorobenzene is converted into phenol by ____________.
The most resistant alcohol towards oxidation reaction is:
Identify the product B in following conversion.
\[\ce{Chlorobenzene + H2O ->[Cu, 673 K][Pressure] A ->[conc. H2SO4][373 K] B}\]
Which following reagent is used to obtain alkene from alcohol?
The number of σ bonds in carbolic acid is ______.
Which of the following alcohols is NOT prepared by reduction of carbonyl compounds?
Identify the product obtained when phenol is treated with bromine water?
The acid, which contains both -OH and -COOR groups is ______.

Product (B) in this reaction is:
The order of reactivity of hydrogen halides with ether is as follows.
Explain the reaction of 1° and 2° alcohol with oxidising agent chromic anhydride (CrO3).
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Convert the following :
cumene to phenol.
