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प्रश्न
Explain the fact that in alkyl aryl ethers, the alkoxy group is ring activating and ortho/para directing towards electrophilic aromatic substitution.
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उत्तर
- Resonance structures of alkyl aryl ethers are as follows:
- The +R effect of −OR the group results in increased electron density at the para- and two ortho positions.
Hence, the alkoxy group in aromatic ether is a ring activating and ortho/para-directing group towards electrophilic aromatic substitution.
संबंधित प्रश्न
Anisole on heating with concentrated HI gives ______.
Choose the correct option.
Ethers react with cold and concentrated H2SO4 to form ________.
What is the action of atmospheric oxygen on ethers?
Write the preparation of ethanol from methyl magnesium iodide.
Write the reaction between ethanol and acetic anhydride.
How will you prepare diethyl ether by dehydration of alcohol?
What are the limitations to prepare ether by this method?
What is the action of following on diethyl ether?
dil. H2SO4
For the preparation of mixed ethers by Williamson synthesis, which of the following combination will give the best yield?
____________ on heating with excess of conc. HI gives two moles of ethyl iodide.
Which of the following statements is INCORRECT for ethers?
In ethers, two C-O sigma bonds are formed by ____________ overlap.
\[\ce{(CH3)2CH - O - CH3 ->[Cold HI] X + Y}\]
\[\ce{X ->[K2Cr2O7][dil. H2SO4] Z}\]
\[\ce{Y ->[NaOH(aq)][\Delta] CH3OH}\]
Identify X, Y and Z.
When methoxy benzene reacts with HI at room temperature the products formed are ______.
Which of the following compounds does NOT contain \[\begin{array}{cc}\backslash\phantom{.......}\\\ce{C = O}\\
/\phantom{.......}\\\end{array}\] group?
Ether is obtained from ethyl alcohol in presence of H2SO4 at _______.
The major product of the reaction between tert-butyl chloride and sodium ethoxide is ______.
The compound which is not formed when a mixture of n-butyl bromide and ethyl bromide treated with sodium metal in the presence of dry ether is ______.
Isopropyl methyl ether when treated with cold hydrogen iodide gives ______.
Formation of diethyl ether from ethanol is based oh a ______.
Explain Williamson's synthesis.
Write preparation of diethyl ether.
