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Explain the fact that in alkyl aryl ethers, the alkoxy group is ring activating and ortho/para directing towards electrophilic aromatic substitution. - Chemistry

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प्रश्न

Explain the fact that in alkyl aryl ethers, the alkoxy group is ring activating and ortho/para directing towards electrophilic aromatic substitution.

दीर्घउत्तर
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उत्तर

  1. Resonance structures of alkyl aryl ethers are as follows:
  2. The +R effect of −OR the group results in increased electron density at the para- and two ortho positions.
    Hence, the alkoxy group in aromatic ether is a ring activating and ortho/para-directing group towards electrophilic aromatic substitution.
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अध्याय 11: Alcohols, Phenols and Ethers - Long Answer Questions

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एससीईआरटी महाराष्ट्र Chemistry [English] 12 Standard HSC
अध्याय 11 Alcohols, Phenols and Ethers
Long Answer Questions | Q 2.2

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