मराठी
महाराष्ट्र राज्य शिक्षण मंडळएचएससी विज्ञान (सामान्य) इयत्ता १२ वी

Explain the fact that in alkyl aryl ethers, the alkoxy group is ring activating and ortho/para directing towards electrophilic aromatic substitution.

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प्रश्न

Explain the fact that in alkyl aryl ethers, the alkoxy group is ring activating and ortho/para directing towards electrophilic aromatic substitution.

दीर्घउत्तर
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उत्तर

  1. Resonance structures of alkyl aryl ethers are as follows:
  2. The +R effect of −OR the group results in increased electron density at the para- and two ortho positions.
    Hence, the alkoxy group in aromatic ether is a ring activating and ortho/para-directing group towards electrophilic aromatic substitution.
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Ethers
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पाठ 11: Alcohols, Phenols and Ethers - Long Answer Questions

संबंधित प्रश्‍न

Anisole on heating with concentrated HI gives ______.


Write the preparation of ethanol from methyl magnesium iodide.


Write the reaction between ethanol and acetic anhydride.


How will you prepare diethyl ether by dehydration of alcohol?


What are the limitations to prepare ether by this method?


What is the action of following on diethyl ether?

dil. H2SO4


What is the action of following on diethyl ether?

PCl5


In the following reaction:

\[\ce{Ether ->[Hot HI] A + B + H2O}\],

If A and B are identical, the ether is ____________.


Which of the following compounds does not contain \[\begin{array}{cc}\backslash\phantom{......}\\\ce{C = O}\\
/\phantom{......}\\\end{array}\] group?


For the preparation of mixed ethers by Williamson synthesis, which of the following combination will give the best yield?


Action of hydrogen iodide on anisole gives ______.


Which of the following statements is INCORRECT for ethers?


A mixed ether on hydrolysis gives ____________.


To prepare ethanol from methyl magnesium bromide, the other reagent required is ____________.


What are the products of the following reaction?

\[\ce{(CH3)3C - O - CH3 + HI ->[cold] ?}\]


Which of the following compounds does NOT contain \[\begin{array}{cc}\backslash\phantom{.......}\\\ce{C = O}\\
/\phantom{.......}\\\end{array}\] group?


Ether is obtained from ethyl alcohol in presence of H2SO4 at _______.


The major product of the reaction between tert-butyl chloride and sodium ethoxide is ______.


Isopropyl methyl ether when treated with cold hydrogen iodide gives ______.


Formation of diethyl ether from ethanol is based oh a ______.


Ethers when dissolved in cold concentrated sulphuric acid forms ______.


Explain Williamson's synthesis.


In Williamson synthesis, if a tertiary alkyl halide is used, then ______.


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