Advertisements
Advertisements
प्रश्न
What will happen during the electrolysis of aqueous solution of \[\ce{CuSO4}\] by using platinum electrodes?
(i) Copper will deposit at cathode.
(ii) Copper will deposit at anode.
(iii) Oxygen will be released at anode.
(iv) Copper will dissolve at anode.
Advertisements
उत्तर
(i) Copper will deposit at cathode.
(iii) Oxygen will be released at anode.
Explanation:
During electrolysis following reaction takes place at cathode:
\[\ce{Cu^{2+} + 2e^{-} -> Cu}\]
\[\ce{H^{-} + e^{-} -> 1/2 H_2}\]
Standard electrode potential of \[\ce{Cu^{2+}/Cu}\] is greater than \[\ce{H-/1/2 H2}\] therefore Cu will deposite at cathode.
APPEARS IN
संबंधित प्रश्न
96500 coulombs correspond to the charge on how many electrons?
Number of faradays of electricity required to liberate 12 g of hydrogen is:
Using the E° values of A and B, predict which is better for coating the surface of iron [E°(Fe+2/Fe) = -0.44V] to prevent corrosion and why?
Given: E° (A+2/A)=-2.37 V: E°(B+2/B)= -0.14V
Following reactions occur at cathode during the electrolysis of aqueous sodium chloride solution:
Na+(aq) + e− ⟶ Na (s) E0 = 2.71 V
H+(aq) + e− ⟶ `1/2` H2 (g) E0 = 0.00 V
On the basis of their standard reduction electrode potential (E0) values, which reaction is feasible at the cathode and why?
If a current of 0.5 ampere flows through a metallic wire for 2 hours, then how many electrons would flow through the wire?
A solution of Ni(NO3)2 is electrolysed between platinum electrodes using a current of 5 amperes for 20 minutes. What mass of Ni is deposited at the cathode?
On passing 1.5 F charge, the number of moles of aluminium deposited at cathode are _______ [Molar mass of Al = 27 gram mol–1]
(A) 1.0
(B) 13.5
(C) 0.50
(D) 0.75
Write any two uses of H2SO4
State second law of electrolysis
Explain Faraday’s second law of electrolysis
Solve the following question.
A steady current of 2 amperes was passed through two electrolytic cells X and Y connected in series containing electrolytes FeSO4 and ZnSO4 until 2.8 g of Fe deposited at the cathode of cell X. How long did the current flow? Calculate the mass of Zn deposited at the cathode of cell Y.
(Molar mass : Fe = 56 g mol–1, Zn = 65.3 g mol–1, 1F = 96500 C mol–1)
Electrolytic cell uses electrical energy to bring about ____________.
In the electrolysis of aqueous sodium chloride solution which of the half cell reaction will occur at anode?
What will happen during the electrolysis of aqueous solution of CuSO4 in the presence of Cu electrodes?
(i) Copper will deposit at cathode.
(ii) Copper will dissolve at anode.
(iii) Oxygen will be released at anode.
(iv) Copper will deposit at anode.
Aqueous copper sulphate solution and aqueous silver nitrate solution are electrolysed by 1 ampere current for 10 minutes in separate electrolytic cells. Will the mass of copper and silver deposited on the cathode be same or different? Explain your answer.
Assertion: Electrolysis of NaCl solution gives chlorine at anode instead of O2.
Reason: Formation of oxygen at anode requires overvoltage.
When during electrolysis of a solution of AgNO3, 9650 coulombs of charge pass through the electroplating bath, the mass of silver deposited on the cathode will be ______.
The quantity of electricity needed to separately electrolyse 1 M solution of ZnSO4, AlCl3, and AgNO3 completely is in the ratio of ______.
A current of 4 amp was passed for 2 hours through a solution of copper sulphate when 5.0 g of copper was deposited. The current efficiency is ______% (Cu = 63.5).
On passing electricity through nitrobenzene solution, it is converted into azobenzene. The mass of azobenzene is ______ mg, if the same quantity of electricity produces oxygen just sufficient to burn 96 mg of fullerene (C60)·
