Advertisements
Advertisements
Question
What will happen during the electrolysis of aqueous solution of \[\ce{CuSO4}\] by using platinum electrodes?
(i) Copper will deposit at cathode.
(ii) Copper will deposit at anode.
(iii) Oxygen will be released at anode.
(iv) Copper will dissolve at anode.
Advertisements
Solution
(i) Copper will deposit at cathode.
(iii) Oxygen will be released at anode.
Explanation:
During electrolysis following reaction takes place at cathode:
\[\ce{Cu^{2+} + 2e^{-} -> Cu}\]
\[\ce{H^{-} + e^{-} -> 1/2 H_2}\]
Standard electrode potential of \[\ce{Cu^{2+}/Cu}\] is greater than \[\ce{H-/1/2 H2}\] therefore Cu will deposite at cathode.
APPEARS IN
RELATED QUESTIONS
On calculating the strength of current in amperes if a charge of 840C (coulomb) passes through an electrolyte in 7 minutes, it will be
- 1
- 2
- 3
- 4
96500 coulombs correspond to the charge on how many electrons?
Number of faradays of electricity required to liberate 12 g of hydrogen is:
Using the E° values of A and B, predict which is better for coating the surface of iron [E°(Fe+2/Fe) = -0.44V] to prevent corrosion and why?
Given: E° (A+2/A)=-2.37 V: E°(B+2/B)= -0.14V
If a current of 0.5 ampere flows through a metallic wire for 2 hours, then how many electrons would flow through the wire?
Consider the reaction: \[\ce{Cr2O^{2-}_7 + 14H^+ + 6e^- -> 2Cr^{3+} + 7H2O}\]
What is the quantity of electricity in coulombs needed to reduce 1 mol of \[\ce{Cr2O^{2-}_7}\]?
Three electrolytic cells A, B, C containing solutions of ZnSO4, AgNO3 and CuSO4, respectively, are connected in series. A steady current of 1.5 amperes was passed through them until 1.45 g of silver deposited at the cathode of cell B. How long did the current flow? What mass of copper and zinc were deposited?
Write any two uses of H2SO4
State second law of electrolysis
Explain Faraday’s second law of electrolysis
How many faradays of electricity are required to produce 13 gram of aluminium from aluminium chloride solution? (Given: Molar mass of Al = 27.0-gram mol–1)
Assertion: Electrolysis of NaCl solution gives chlorine at anode instead of O2.
Reason: Formation of oxygen at anode requires overvoltage.
Consider the figure and answer the following question.
Cell ‘A’ has ECell = 2V and Cell ‘B’ has ECell = 1.1V which of the two cells ‘A’ or ‘B’ will act as an electrolytic cell. Which electrode reactions will occur in this cell?
When during electrolysis of a solution of AgNO3, 9650 coulombs of charge pass through the electroplating bath, the mass of silver deposited on the cathode will be ______.
The quantity of electricity needed to separately electrolyse 1 M solution of ZnSO4, AlCl3, and AgNO3 completely is in the ratio of ______.
What is the quantity of electricity in Coulombs required to produce 4.8 g of Mg from molten MgCl2? How much Ca will be produced if the same amount of electricity was passed through molten CaCl2? (Atomic mass of Mg = 24 u, atomic mass of Ca = 40 u).
Through an aqueous solution of an unknown salt of metal M (M = 200 g/mol) a current of 1.93 A is passed for 50 min. If 4 g of metal is produced at cathode. The charge on metal ion in solution is ______.
A current of 4 amp was passed for 2 hours through a solution of copper sulphate when 5.0 g of copper was deposited. The current efficiency is ______% (Cu = 63.5).
On passing electricity through nitrobenzene solution, it is converted into azobenzene. The mass of azobenzene is ______ mg, if the same quantity of electricity produces oxygen just sufficient to burn 96 mg of fullerene (C60)·
